4.8 Article

Carbon-tolerant solid oxide fuel cells using NiTiO3 as an anode internal reforming layer

期刊

JOURNAL OF POWER SOURCES
卷 255, 期 -, 页码 404-409

出版社

ELSEVIER SCIENCE BV
DOI: 10.1016/j.jpowsour.2014.01.014

关键词

Internal reforming layer; Carbon tolerant; Solid oxide fuel cells; Hydrocarbon fuels

资金

  1. Natural Science Foundation of China [51072193]
  2. National Basic Research Program of China (973 Program) [2012CB922001]
  3. Fundamental Research Funds for the Central Universities

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In this work, adding a NiTiO3 (NTO) reforming layer is firstly adopted as a low cost method to improve the carbon tolerance in solid oxide fuel cells. XRD patterns suggest that NTO has a good chemical compatibility with the YSZ electrolyte, and NTO can be totally reduced to Ni and TiO2 when exposing to the H-2 atmosphere. Maximum power densities for the cells with the NTO layers at 700 degrees C are 270 mWcm(-2) with wet H-2 fuel, and 236 mWcm(-2) with wet methane fuel, respectively. Improved discharging stability for the cells with NTO layers has also been observed. The current density remains unchanged for the cells with NTO layers during a 26 h test, while it drops to zero within 1 h for the cells without NTO. Above electro-performance and long term stability tests suggest that fabricating a NTO reforming layer on the anode surface is an efficient and inexpensive method to realize highly carbon tolerant SOFCs. (C) 2014 Elsevier B.V. All rights reserved.

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