4.8 Article

Discrete geometry optimization for reducing flow non-uniformity, asymmetry, and parasitic minor loss pressure drops in Z-type configurations of fuel cells

期刊

JOURNAL OF POWER SOURCES
卷 269, 期 -, 页码 274-283

出版社

ELSEVIER
DOI: 10.1016/j.jpowsour.2014.06.136

关键词

PEM fuel cell; Z-type configuration; Flow field; Flow distribution; Geometry optimization

资金

  1. University Cancer Research Fund (University of North Carolina at Chapel Hill)

向作者/读者索取更多资源

Parallel channel configurations, such as Z-type, used to distribute reagents in planar fuel cells provide lower overall pressure drop as compared to other channel designs. However, due to their inherent characteristics, flow maldistribution in parallel configurations is commonly observed and leads to starvation of reagents in middle channels. In addition, the Reynolds number dependent minor losses at branching tee junctions may cause asymmetric flow non-uniformity and reagent imbalance between the cathode and anode. Herein, we present a universal and simple optimization method to simultaneously reduce flow maldistribution, asymmetry, and parasitic pressure in Z-type parallel configurations of fuel cells or fuel cell stacks that has improved scalability relative to previous methods. A discrete model's governing equations were reduced to yield geometric ratios between headers. Increasing header widths to satisfy these ratios reduced flow maldistribution without modifying parallel channel geometry as validated by computation fluid dynamics (CFD) simulations. Furthermore, decreased Reynolds numbers throughout the headers reduced minor pressure drops and flow distribution asymmetry. We offer several methods to reduce the optimized geometry's footprint, including an adaptation of the discontinuous design. (C)2014 Elsevier B.V. All rights reserved.

作者

我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。

评论

主要评分

4.8
评分不足

次要评分

新颖性
-
重要性
-
科学严谨性
-
评价这篇论文

推荐

Article Chemistry, Multidisciplinary

Enzymatic cleavage of uracil-containing single-stranded DNA linkers for the efficient release of affinity-selected circulating tumor cells

Soumya V. Nair, Malgorzata A. Witek, Joshua M. Jackson, Maria A. M. Lindell, Sally A. Hunsucker, Travis Sapp, E. Perry, Mateusz L. Hupert, Victoria Bae-Jump, Paola A. Gehrig, Weiya Z. Wysham, Paul M. Armistead, Peter Voorhees, Steven A. Soper

CHEMICAL COMMUNICATIONS (2015)

Article Chemistry, Analytical

Microfluidics for the detection of minimal residual disease in acute myeloid leukemia patients using circulating leukemic cells selected from blood

Joshua M. Jackson, James B. Taylor, Malgorzata A. Witek, Sally A. Hunsucker, Jennifer P. Waugh, Yuri Fedoriw, Thomas C. Shea, Steven A. Soper, Paul M. Armistead

ANALYST (2016)

Article Chemistry, Analytical

Interrogating Surface Functional Group Heterogeneity of Activated Thermoplastics Using Super-Resolution Fluorescence Microscopy

Colleen E. ONeil, Joshua M. Jackson, Sang-Hee Shim, Steven A. Soper

ANALYTICAL CHEMISTRY (2016)

Review Oncology

Molecular Profiling of Liquid Biopsy Samples for Precision Medicine

Camila D. M. Campos, Joshua M. Jackson, Malgorzata A. Witek, Steven A. Soper

CANCER JOURNAL (2018)

Article Chemistry, Analytical

Solid-phase extraction and purification of membrane proteins using a UV-modified PMMA microfluidic bioaffinity μSPE device

Katrina N. Battle, Joshua M. Jackson, Malgorzata A. Witek, Mateusz L. Hupert, Sally A. Hunsucker, Paul M. Armistead, Steven A. Soper

ANALYST (2014)

Article Biochemical Research Methods

UV activation of polymeric high aspect ratio microstructures: ramifications in antibody surface loading for circulating tumor cell selection

Joshua M. Jackson, Malgorzata A. Witek, Mateusz L. Hupert, Charles Brady, Swathi Pullagurla, Joyce Kamande, Rachel D. Aufforth, Christopher J. Tignanelli, Robert J. Torphy, Jen Jen Yeh, Steven A. Soper

LAB ON A CHIP (2014)

Article Engineering, Electrical & Electronic

Arrays of high-aspect ratio microchannels for high-throughput isolation of circulating tumor cells (CTCs)

Mateusz L. Hupert, Joshua M. Jackson, Hong Wang, Malgorzata A. Witek, Joyce Kamande, Matthew I. Milowsky, Young E. Whang, Steven A. Soper

MICROSYSTEM TECHNOLOGIES-MICRO-AND NANOSYSTEMS-INFORMATION STORAGE AND PROCESSING SYSTEMS (2014)

Article Chemistry, Analytical

Time-Delayed Integration-Spectral Flow Cytometer (TDI-SFC) for Low-Abundance-Cell Immunophenotyping

Wenting Hu, Steven A. Soper, J. Matt Jackson

ANALYTICAL CHEMISTRY (2019)

Article Biology

Affinity enrichment of extracellular vesicles from plasma reveals mRNA changes associated with acute ischemic stroke

Harshani Wijerathne, Malgorzata A. Witek, Joshua M. Jackson, Virginia Brown, Mateusz L. Hupert, Kristina Herrera, Cameron Kramer, Abigail E. Davidow, Yan Li, Alison E. Baird, Michael C. Murphy, Steven A. Soper

COMMUNICATIONS BIOLOGY (2020)

Article Chemistry, Analytical

In-plane Extended Nano-coulter Counter (XnCC) for the Label-free Electrical Detection of Biological Particles

Zheng Zhao, Swarnagowri Vaidyanathan, Payel Bhanja, Sachindra Gamage, Subhrajit Saha, Collin McKinney, Junseo Choi, Sunggook Park, Thilanga Pahattuge, Harshani Wijerathne, Joshua M. Jackson, Mateusz L. Huppert, Malgorzata A. Witek, Steven A. Soper

Summary: We present an in-plane extended nanopore Coulter counter (XnCC) chip fabricated using imprinting in a thermoplastic material. The sensor was made using photolithography and focused ion beam milling to create the microfluidic network and in-plane pore sensor, respectively, in Si. UV resin stamps were then generated and used for thermal imprinting to produce the final device in the desired plastic material (cyclic olefin polymer, COP). As a demonstration, we used this in-plane extended nanopore sensor to count SARS-CoV-2 viral particles (VPs) affinity-selected from saliva and extracellular vesicles (EVs) affinity-selected from plasma samples obtained from mouse models exposed to different ionizing radiation doses.

ELECTROANALYSIS (2022)

Article Chemistry, Analytical

Assessing Breast Cancer Molecular Subtypes Using Extracellular Vesicles? mRNA

Mengjia Hu, Virginia Brown, Joshua M. Jackson, Harshani Wijerathne, Harsh Pathak, Devin C. Koestler, Emily Nissen, Mateusz L. Hupert, Rolf Muller, Andrew K. Godwin, Malgorzata A. Witek, Steven A. Soper

Summary: Extracellular vesicles (EVs) have the potential to be used as a minimally invasive liquid biopsy marker for precision medicine, as they carry RNA cargo associated with the cell-of-origin. Researchers have developed an EV microfluidic affinity purification (EV-MAP) chip, made from plastic for high-scale production, which can isolate EV subpopulations. They demonstrated the utility of this chip in molecular subtyping breast cancer patients, isolating two subpopulations of EVs that better recapitulate the tumor microenvironment. The EV-MAP provided high recovery and specificity based on exosomal mRNA and PCR results, and the EV subpopulations showed potential for prognostication using the PAM50 test.

ANALYTICAL CHEMISTRY (2023)

Article Biochemical Research Methods

Microfluidic-based solid phase extraction of cell free DNA

Camila D. M. Campos, Sachindra S. T. Gamage, Joshua M. Jackson, Malgorzata A. Witek, Daniel S. Park, Michael C. Murphy, Andrew K. Godwin, Steven A. Soper

LAB ON A CHIP (2018)

Review Chemistry, Multidisciplinary

Materials and microfluidics: enabling the efficient isolation and analysis of circulating tumour cells

Joshua M. Jackson, Malgorzata A. Witek, Joyce W. Kamande, Steven A. Soper

CHEMICAL SOCIETY REVIEWS (2017)

Meeting Abstract Hematology

Rapid Assessment of Minimal Residual Acute Myeloid Leukemia from Peripheral Blood Using a Microfluidic Chip

Joshua M. Jackson, James Taylor, Malgorzata Witek, Sally A. Hunsucker, Jennifer Paulsen Waugh, Yuri D. Fedoriw, Thomas C. Shea, Steven A. Soper, Paul M. Armistead

Article Chemistry, Physical

Development of a tubular direct carbon solid oxide fuel cell stack based on lanthanum gallate electrolyte

Tianyu Chen, Zhibin Lu, Guangjin Zeng, Yongmin Xie, Jie Xiao, Zhifeng Xu

Summary: The study introduces a high-performance LSGM electrolyte-supported tubular DC-SOFC stack for portable applications, which shows great potential in developing into high-performing, efficient, and environmentally friendly portable power sources for distributed applications.

JOURNAL OF POWER SOURCES (2024)

Article Chemistry, Physical

Construction of ultrastable and high-rate performance zinc anode with three-dimensional porous structure and Schottky contact

Wenbin Tong, Yili Chen, Shijie Gong, Shaokun Zhu, Jie Tian, Jiaqian Qin, Wenyong Chen, Shuanghong Chen

Summary: In this study, a three-dimensional porous NiO interface layer with enhanced anode dynamics is fabricated, forming a Schottky contact with the zinc substrate, allowing rapid and uniform zinc plating both inside and below the interface layer. The resulting NiO@Zn exhibits exceptional stability and high capacity retention.

JOURNAL OF POWER SOURCES (2024)

Article Chemistry, Physical

Flexible low-temperature zinc ion supercapacitor based on gel electrolyte with α-MnO2@rGO electrode

Yafeng Bai, Kaidi Li, Liying Wang, Yang Gao, Xuesong Li, Xijia Yang, Wei Lu

Summary: In this study, a flexible zinc ion supercapacitor with gel electrolytes, porous alpha-MnO2@reduced graphene oxide cathode, and activated carbon/carbon cloth anode was developed. The device exhibits excellent electrochemical performance and stability, even at low temperatures, with a high cycle retention rate after 5000 cycles.

JOURNAL OF POWER SOURCES (2024)

Article Chemistry, Physical

Examining the effects of silicon based additives on the long-term cycling capabilities of cylindrical cells

Anmol Jnawali, Matt D. R. Kok, Francesco Iacoviello, Daniel J. L. Brett, Paul R. Shearing

Summary: This article presents the results of a systematic study on the electrochemical performance and mechanical changes in two types of commercial batteries with different anode chemistry. The study reveals that the swelling of anode layers in batteries with silicon-based components causes deformations in the jelly roll structure, but the presence of a small percentage of silicon does not significantly impact the cycling performance of the cells within the relevant state-of-health range for electric vehicles (EVs). The research suggests that there is room for improving the cell capacities by increasing the silicon loading in composite anodes to meet the increasing demands on EVs.

JOURNAL OF POWER SOURCES (2024)

Article Chemistry, Physical

Lithium disilicate as an alternative silicate battery material. A theoretical study

Yohandys A. Zulueta, My Phuong Pham-Ho, Minh Tho Nguyen

Summary: Advanced atomistic simulations were used to study ion transport in the Na- and K-doped lithium disilicate Li2Si2O5. The results showed that Na and K doping significantly enhanced Li ion diffusion and conduction in the material.

JOURNAL OF POWER SOURCES (2024)

Article Chemistry, Physical

Novel BaO-decorated carbon-tolerant Ni-YSZ anode fabricated by an efficient phase inversion-impregnation approach

Zongying Han, Hui Dong, Yanru Yang, Hao Yu, Zhibin Yang

Summary: An efficient phase inversion-impregnation approach is developed to fabricate BaO-decorated Ni8 mol% YSZ anode-supported tubular solid oxide fuel cells (SOFCs) with anti-coking properties. BaO nanoislands are successfully introduced inside the Ni-YSZ anode, leading to higher peak power densities and improved stability in methane fuel. Density functional theory calculations suggest that the loading of BaO nanoislands facilitates carbon elimination by capturing and dissociating H2O molecules to generate OH.

JOURNAL OF POWER SOURCES (2024)

Article Chemistry, Physical

Safe and stable Li-CO2 battery with metal-organic framework derived cathode composite and solid electrolyte

Suresh Mamidi, Dan Na, Baeksang Yoon, Henu Sharma, Anil D. Pathak, Kisor Kumar Sahu, Dae Young Lee, Cheul-Ro Lee, Inseok Seo

Summary: Li-CO2 batteries, which utilize CO2 and have a high energy density, are hindered in practical applications due to slow kinetics and safety hazards. This study introduces a stable and highly conductive ceramic-based solid electrolyte and a metal-organic framework catalyst to improve the safety and performance of Li-CO2 batteries. The optimized Li-CO2 cell shows outstanding specific capacity and cycle life, and the post-cycling analysis reveals the degradation mechanism of the electrodes. First-principles calculations based on density functional theory are also performed to understand the interactions between the catalyst and the host electrode. This research demonstrates the potential of MOF cathode catalyst for stable operation in Li-CO2 batteries.

JOURNAL OF POWER SOURCES (2024)

Article Chemistry, Physical

Synergistic effect of platinum single atoms and nanoclusters for preferential oxidation of carbon monoxide in hydrogen-rich stream

Ganghua Xiang, Zhihuan Qiu, Huilong Fei, Zhigang Liu, Shuangfeng Yin, Yuen Wu

Summary: In this study, a CeFeOx-supported Pt single atoms and subnanometric clusters catalyst was developed, which exhibits enhanced catalytic activity and stability for the preferential oxidation of CO in H2-rich stream through synergistic effect.

JOURNAL OF POWER SOURCES (2024)

Article Chemistry, Physical

Towards understanding the functional mechanism and synergistic effects of LiMn2O4-LiNi0.5Mn0.3Co0.2O2 blended positive electrodes for Lithium-ion batteries

Dimitrios Chatzogiannakis, Marcus Fehse, Maria Angeles Cabanero, Natalia Romano, Ashley Black, Damien Saurel, M. Rosa Palacin, Montse Casas-Cabanas

Summary: By coupling electrochemical testing to operando synchrotron based X-ray absorption and powder diffraction experiments, blended positive electrodes consisting of LiMn2O4 spinel (LMO) and layered LiNi0.5Mn0.3Co0.2O2 (NMC) were studied to understand their redox mechanism. It was found that blending NMC with LMO can enhance energy density at high rates, with the blend containing 25% LMO showing the best performance. Testing with a special electrochemical setup revealed that the effective current load on each blend component can vary significantly from the nominal rate and also changes with SoC. Operando studies allowed monitoring of the oxidation state evolution and changes in crystal structure, in line with the expected behavior of individual components considering their electrochemical current loads.

JOURNAL OF POWER SOURCES (2024)

Article Chemistry, Physical

We may be underestimating the power capabilities of lithium-ion capacitors

Chiara Cementon, Daniel Dewar, Thrinathreddy Ramireddy, Michael Brennan, Alexey M. Glushenkov

Summary: This Perspective discusses the specific power and power density of lithium-ion capacitors, highlighting the fact that their power characteristics are often underestimated. Through analysis, it is found that lithium-ion capacitors can usually achieve power densities superior to electrochemical supercapacitors, making them excellent alternatives to supercapacitors.

JOURNAL OF POWER SOURCES (2024)

Article Chemistry, Physical

Highly concentrated solvation structure for reversible high-voltage lithium-ion battery at low temperature

Weihao Wang, Hao Yu, Li Ma, Youquan Zhang, Yuejiao Chen, Libao Chen, Guichao Kuang, Liangjun Zhou, Weifeng Wei

Summary: This study achieved an improved electrolyte with excellent low-temperature and high-voltage performance by regulating the Li+ solvation structure and highly concentrating it. The electrolyte exhibited outstanding oxidation potential and high ionic conductivity under low temperature and high voltage conditions, providing a promising approach for the practical application of high-voltage LIBs.

JOURNAL OF POWER SOURCES (2024)

Article Chemistry, Physical

Evaluation of mitigation of capacity decay in vanadium redox flow batteries for cation- and anion-exchange membrane by validated mathematical modelling

Martin Bures, Dan Gotz, Jiri Charvat, Milos Svoboda, Jaromir Pocedic, Juraj Kosek, Alexandr Zubov, Petr Mazur

Summary: Vanadium redox flow battery is a promising energy storage solution with long-term durability, non-flammability, and high overall efficiency. Researchers have developed a mathematical model to simulate the charge-discharge cycling of the battery, and found that hydraulic connection of electrolyte tanks is the most effective strategy to reduce capacity losses, achieving a 69% reduction.

JOURNAL OF POWER SOURCES (2024)

Article Chemistry, Physical

Operando analysis of the positive active mass of lead batteries by neutron diffraction

M. Rodriguez-Gomez, J. Campo, A. Orera, F. de La Fuente, J. Valenciano, H. Fricke, D. S. Hussey, Y. Chen, D. Yu, K. An, A. Larrea

Summary: In this study, we analysed the operando performance of industrial lead cells using neutron diffraction experiments. The experiments revealed the evolution of different phases in the positive electrode, showed significant inhomogeneity of phase distribution inside the electrode, and estimated the energy efficiency of the cells.

JOURNAL OF POWER SOURCES (2024)

Article Chemistry, Physical

Double Conductive Ni-pads for a kW-class micro-tubular solid oxide fuel cell stack

Jiawei Liu, Chenpeng Wang, Yue Yao, Hao Ye, Yinglong Liu, Yingli Liu, Xiaoru Xu, Zhicong Chen, Huazheng Yang, Gang Wu, Libin Lei, Chao Wang, Bo Liang

Summary: The study focuses on utilizing double conductive Ni-pads as anode collectors in micro-tubular solid oxide fuel cells. The simulation results show excellent performance and stability of DCNPs, and also highlight the potential applications in various fields.

JOURNAL OF POWER SOURCES (2024)

Article Chemistry, Physical

Ion transport regulation of polyimide separator for safe and durable Li-metal battery

Yang Wang, Kangjie Zhou, Lang Cui, Jiabing Mei, Shengnan Li, Le Li, Wei Fan, Longsheng Zhang, Tianxi Liu

Summary: This study presents a polyimide sandwiched separator (s-PIF) for improving the cycling stability of Li-metal batteries. The s-PIF separator exhibits superior mechanical property, electrolyte adsorption/retention and ion conductivity, and enables dendrite-free Li plating/stripping process.

JOURNAL OF POWER SOURCES (2024)