期刊
JOURNAL OF POWER SOURCES
卷 260, 期 -, 页码 1-5出版社
ELSEVIER
DOI: 10.1016/j.jpowsour.2014.03.001
关键词
Fuel cells; Oxygen reduction reaction; Methanol oxidation; Proton conduction; Mass transfer
资金
- National Natural Science Foundation of China [21373091, 21376257]
The electrocatalytic performances of carbon nanotubes supported platinum (Pt/CNTs) with different Pt loadings for oxygen reduction reaction (ORR) and methanol oxidation (MOR) are studied contrastively. Pt/CNTs showed an opposite change rule along different Pt loadings for ORR and MOR, which is discussed based on the charge transportation and mass transfer. The results show that at low Pt loading, proton conduction is the key factor, which determines the MOR activity; at high Pt loading, mass transfer is crucial, which decides the ORR activity of Pt/CNT catalysts. The viewpoint proposed in this paper can guide the design and preparation of Pt based catalysts for the commercialization of direct methanol fuel cells. (C) 2014 Elsevier B.V. All rights reserved.
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