4.8 Article

In situ microscopic studies on the structural and chemical behaviors of lithium-ion battery materials

期刊

JOURNAL OF POWER SOURCES
卷 270, 期 -, 页码 475-486

出版社

ELSEVIER
DOI: 10.1016/j.jpowsour.2014.07.123

关键词

Microscopic techniques; Silicon; Lithium-ion battery; State-of-charge; Structural evolution

资金

  1. Hong Kong University of Science and Technology

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The direct observation of the microstructural evolution and state-of-charge (SOC) distribution in active materials is crucial to understand the lithiation/delithiation mechanisms during electrochemical cycling of lithium-ion batteries (LIBs). Owing to their high spatial resolutions and capability to map chemical states by combining other spectroscopic techniques, microscopic techniques including X-ray fluorescence (XRF) microscopy, Raman microscopy, transmission X-ray microscopy (D(M), scanning electron microscopy (SEM), and transmission electron microscopy (TEM) play significant roles in real time monitoring the dynamic changes in the LIB electrodes and materials. This paper reviews the recent progress of using in situ microscopic techniques to study LIB materials, including Si-, Sn-, Ge-, C- and metal oxides-based anode materials, and layered oxysulfide, metal fluorides, LiCoO2, LiNi0.8Co0.15Al0.05O2, LiMn2O4, LiFePO4 cathode materials. (C) 2014 Elsevier B.V. All rights reserved.

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