期刊
JOURNAL OF POWER SOURCES
卷 237, 期 -, 页码 149-155出版社
ELSEVIER SCIENCE BV
DOI: 10.1016/j.jpowsour.2013.03.035
关键词
Lithium ion batteries; Lithium iron phosphate; Nickel and manganese co-doping; High-temperature solid-state route; Electrochemical performance
资金
- National Natural Science Foundation of China [20871101]
- Natural Science of Hunan Province [09BG005]
- Xiangtan City [09BG005]
- Industrial Project of Colleges and Universities of Hunan Province [10CY005]
- Project of Condition Research of Hunan Province [2010TC2004]
- Colleges and Universities in Hunan Province plans to graduate research and innovation [CX2011B268]
The pristine LiFePO4/C and Ni and Mn co-doping LiFe(1-x-y)Ni(x)Nn(y)PO(4)/C (x = 0.01-0.04; y = 0.04-0.01) composites are synthesized for the first time by a simple high-temperature solid-state route. The structure, morphology and electrochemical performance of the samples are characterized by X-ray diffraction (XRD), Fourier transform infrared (FTIR) spectra, scanning electron microscope (SEM), charge/discharge tests and electrochemical impedance spectroscopy (EIS). The results indicate that the Ni and Mn co-doping does not destroy the olivine structure of LiFePO4, but it can stabilize the crystal structure, lengthen the Li-O bond, decrease charge transfer resistance, enhance Li ion diffusion velocity, and thus improve its cycling and high-rate capability of the LiFePO4/C. Especially, the LiFe0.95Ni0.02Mn0.03PO4/C shows the best cycling stability and rate capability among all the doped samples. The first discharge capacity of LiFe0.95Ni0.02Mn0.03PO4/C is 145.4 mAh g(-1) with the capacity retention ratio of 98.6% till 100 cycles at 1C. Even at a high rate of 10C, it still reveals a high discharge capacity of 115.2 mAh g(-1). (C) 2013 Elsevier B.V. All rights reserved.
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