4.8 Article

PrNi0.6Co0.4O3-Ce0.8Sm0.2O1.9 composite cathodes for intermediate temperature solid oxide fuel cells

期刊

JOURNAL OF POWER SOURCES
卷 199, 期 -, 页码 150-154

出版社

ELSEVIER
DOI: 10.1016/j.jpowsour.2011.10.025

关键词

Solid oxide fuel cell; Cathode; Perovskite; Area specific resistance; Thermal expansion

资金

  1. Anhui Key Laboratory of Information Materials and Devices
  2. National Natural Science Foundation of China [11074001]

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Cobalt-containing perovskite, PrNi0.6Co0.4O3 (PNC) has been investigated as a possible candidate for cathode material for intermediate temperature solid oxide fuel cells. It is found that the maximum and minimum electrical conductivity of PNC are 1580 S cm(-1) at 50 degrees C and 1031 S cm(-1) at 1000 degrees C, respectively. The thermal expansion coefficient (TEC) of the PNC is 14.21 x 10(-6) K-1 at 700 degrees C. The TEC of the PNC-50 wt.% Ce0.8Sm02O1.9 (PNC-50SDC) composite cathode is 13.49 x 10(-6) K-1 at 700 degrees C, which is much more matching with the other components within the cell. The cathodic polarization of the single-phase PNC and composite cathodes with SDC shows that a weight ratio between PNC and SDC of 50:50 yields the lowest area specific resistance of 0.097 Omega cm(2) at 600 degrees C and 0.031 Omega cm2 at 700 degrees C. The maximum power density of the PNC-50SDC cathode in an anode-supported SOFC is 1.09W cm(-2) at 700 degrees C. (C) 2011 Elsevier B.V. All rights reserved.

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