期刊
JOURNAL OF POWER SOURCES
卷 218, 期 -, 页码 254-260出版社
ELSEVIER
DOI: 10.1016/j.jpowsour.2012.07.004
关键词
Surface exchange coefficient; Electrical conductivity relaxation; Lanthanum Strontium Cobaltite Ferrite; Doped ceria; Solid oxide fuel cells
资金
- Ministry of Science and Technology of China [2012CB215403]
- US National Science Foundation [CBET 0967166]
- Div Of Chem, Bioeng, Env, & Transp Sys
- Directorate For Engineering [0967166] Funding Source: National Science Foundation
Chemical oxygen surface exchange coefficient (K-ex) Of La0.6Sr0.4Co0.8Fe0.2O3 - (delta) (LSCF) coated with samaria-doped ceria (SDC) particles has been investigated using the electrical conductivity relaxation method. It has been found that adding doped ceria to LSCF results in an increase of a factor of 10 in surface exchange rate, suggesting that oxygen incorporation at the LSCF/SDC/gas boundary sites is facile. Furthermore, K-ex of the SDC coated LSCF increases with the conductivity of SDC rather than the composition of the SDC, inferring that SDC supplies additional free oxygen vacancies for the surface exchange reaction. These results demonstrate that introducing doped ceria to La-1 - xSrxCo1 _ yFeyO3 - can substantially enhance the oxygen surface incorporation process for applications such as solid oxide fuel cell cathodes as well as oxygen separation membranes. (C) 2012 Elsevier B.V. All rights reserved.
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