4.8 Article

Fabrication and characterization of anode-supported micro-tubular solid oxide fuel cell based on BaZr0.1Ce0.7Y0.1Yb0.1O3-δ electrolyte

期刊

JOURNAL OF POWER SOURCES
卷 196, 期 2, 页码 688-691

出版社

ELSEVIER SCIENCE BV
DOI: 10.1016/j.jpowsour.2010.07.058

关键词

Solid oxide fuel cell; Micro-tubular; Proton conductor; Phase inversion

资金

  1. Department of Energy [09-510]

向作者/读者索取更多资源

Anode-supported micro-tubular solid oxide fuel cells (SOFCs) based on a proton and oxide ion mixed conductor electrolyte, BaZr0.1Ce0.7Y0.1Yb0.1O3-delta (BZCYYb), have been fabricated using phase inversion and dip-coating techniques with a co-firing process. The single cell is composed of NiO-BZCYYb anode, BZCYYb electrolyte and La0.6Sr0.4Co0.2Fe0.8O3-delta (LSCF)-BZCYYb cathode. Maximum power densities of 0.08, 0.15, and 0.26 W cm(-2) have been obtained at 500,550 and 600 degrees C, respectively, using H-2 as fuel and ambient air as oxidant. (C) 2010 Elsevier B.V. All rights reserved.

作者

我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。

评论

主要评分

4.8
评分不足

次要评分

新颖性
-
重要性
-
科学严谨性
-
评价这篇论文

推荐

Review Chemistry, Physical

A review on cathode processes and materials for electro-reduction of carbon dioxide in solid oxide electrolysis cells

Yunan Jiang, Fanglin Chen, Changrong Xia

Summary: The excessive emission of CO2 poses a threat to the environment and human livelihood, driving the development of solid oxide electrolysis cells (SOECs) as a promising technology for CO2 reduction and renewable energy storage. Efforts are focused on enhancing the catalytic activity and durability of SOEC cathode materials to facilitate efficient CO2 electro-reduction.

JOURNAL OF POWER SOURCES (2021)

Article Electrochemistry

A practical approach for identifying various polarization behaviors of redox-stable electrodes in symmetrical solid oxide fuel cells

Jihao Zhang, Libin Lei, Hangyue Li, Fanglin Chen, Minfang Han

Summary: In this study, a systematic and practical approach was utilized to investigate the elementary reaction processes and rate-limiting steps of redox-stable electrodes in symmetrical solid oxide fuel cells, with the application of electrochemical impedance spectroscopy technology. The results showed that the rate-limiting steps of the cathode are associated with the formation of adsorbed oxygen ions and the combination of oxygen ions and oxygen vacancies, while the rate-limiting steps of the anode are attributed to the processes of hydrogen dissociated adsorption and steam desorption.

ELECTROCHIMICA ACTA (2021)

Review Chemistry, Physical

A review on anode on-cell catalyst reforming layer for direct methane solid oxide fuel cells

Peng Qiu, Shichen Sun, Xin Yang, Fanglin Chen, Chunyan Xiong, Lichao Jia, Jian Li

Summary: This study emphasizes the importance of promoting the commercialization of solid oxide fuel cells through direct utilization of methane. It identifies carbon deposition on nickel-based anodes as a key issue limiting long-term stability, and suggests on-cell catalytic reforming layer as one of the most promising designs.

INTERNATIONAL JOURNAL OF HYDROGEN ENERGY (2021)

Article Energy & Fuels

Effects and Attenuation Mechanism Analysis of a Fluoroethylene Carbonate Additive on SiOx/Graphite Anode-Based Pouch Cells

Mi Zhou, Chao Jin, Zhang Cao, Ximin Wang, Yinnan Yuan, Lihua Jin, Honghe Zheng

Summary: This study investigates the issues of SiOx/graphite composite anodes, and finds that the additive fluoroethylene carbonate (FEC) can accelerate degradation at high temperatures by generating more gas and hydrofluoric acid, leading to cathodic corrosion and loss of active lithium.

ENERGY & FUELS (2022)

Review Chemistry, Physical

Progress report on the catalyst layers for hydrocarbon-fueled SOFCs

Panpan Zhang, Zhibin Yang, Yiqian Jin, Changlei Liu, Ze Lei, Fanglin Chen, Suping Peng

Summary: Solid oxide fuel cell (SOFC) is an energy conversion device that can directly convert the chemical energy of carbonaceous fuels into electricity. Addressing carbon deposition in traditional nickel-based anodes is crucial for improving SOFC performance. Although alternative anode materials have shown progress, nickel-based anodes remain the most promising for commercializing SOFC due to their superior catalytic activity for carbonaceous fuels.

INTERNATIONAL JOURNAL OF HYDROGEN ENERGY (2021)

Article Electrochemistry

Effects of Nitriles additives on performances of SiOx/Graphite||NCM811 pouch cell at elevated temperature

Mi Zhou, Yarong Wang, Chao Jin, Yinnan Yuan, Honghe Zheng

Summary: This research reports the use of two kinds of nitriles additives to optimize the performance of SiOx/Gr||NCM811 pouch cell at high temperature. The results show enhanced charge/discharge capacity and rate capability, as well as reduced polarization resistance.

INTERNATIONAL JOURNAL OF ELECTROCHEMICAL SCIENCE (2022)

Article Chemistry, Physical

Performance and DRT analysis of infiltrated functional cathode based on the anode supported SOFCs with long-term stability

Ziwei Zheng, Junmeng Jing, Ze Lei, Zhongxu Wang, Zhibin Yang, Chao Jin, Suping Peng

Summary: The relationship between morphology and kinetics of oxygen reduction reaction (ORR) in cathode functional layer (CFL) is studied. A highly efficient and robust CFL is prepared by infiltrating method, which shows significantly enhanced ORR activity. This study provides insights for improving the performance of solid oxide fuel cells.

INTERNATIONAL JOURNAL OF HYDROGEN ENERGY (2022)

Article Chemistry, Physical

Enhanced ionic conductivity and interface compatibility of PVDF-LLZTO composite solid electrolytes by interfacial maleic acid modification

Lin Peng, Zhengyi Lu, Lin Zhong, Jiejie Jian, Yi Rong, Ruizhi Yang, Yadong Xu, Chao Jin

Summary: This study introduces maleic acid (MA) into PVDF-LLZTO-based composite polymer-ceramic electrolytes to improve conductivity and optimize interface contact. The core-shell structure formed with LLZTO as the core and MA nano-film as the shell enhances conductivity, provides extra channels for Li+ transmission, and improves compatibility with Li metal anode.

JOURNAL OF COLLOID AND INTERFACE SCIENCE (2022)

Article Materials Science, Ceramics

Atmospheric plasma spraying to fabricate metal-supported solid oxide fuel cells with open-channel porous metal support

Jie Lin, Haixia Li, Wanhua Wang, Peng Qiu, Greg Tao, Kevin Huang, Fanglin Chen

Summary: Metal-supported solid oxide fuel cells (MS-SOFCs) were successfully fabricated using phase-inversion tape-casting and atmospheric plasma spraying techniques. The amount of binder in the slurries and the plasma power of the plasma spraying process significantly influenced the microstructure of the metal support, electrolyte, and cathode. The MS-SOFCs achieved high cell power density and low resistances under optimized conditions.

JOURNAL OF THE AMERICAN CERAMIC SOCIETY (2023)

Editorial Material Electrochemistry

Perspective-Solid Oxide Cell Technology for Space Exploration

Robert D. Green, S. Elango Elangovan, Fanglin Chen

Summary: In order to achieve long-term manned space exploration, critical needs for life support, such as oxygen and water, as well as electrical power for on-board operation, and the generation of propellants for ascent vehicles are essential. Low temperature electrochemical devices have been developed and used for on-board oxygen and power generation in previous manned space programs. High temperature solid oxide cell technology has unique advantages for future space missions. This perspective highlights the recent advances in solid oxide cell technology that make it feasible for adoption in aerospace applications and outlines the projected needs for future research and development to better support space exploration.

JOURNAL OF THE ELECTROCHEMICAL SOCIETY (2022)

Article Chemistry, Multidisciplinary

Boosting and Robust Multifunction Cathode Layer for Solid Oxide Fuel Cells

Ziwei Zheng, Junmeng Jing, Haorui Yu, Zhibin Yang, Chao Jin, Fanglin Chen, Suping Peng

Summary: Designing an efficient cathode and accelerating the sluggish oxygen reduction reaction process are crucial for enhancing electrochemical outputs in solid oxide fuel cells (SOFCs). A novel multifunction layer cathode, combining a Gd0.2Ce0.8O2-delta (GDC) interlayer with a La0.6Sr0.4Co0.2Fe0.8O3-delta (LSCF) cathode functional layer, is reported in this study. By precisely controlling the concentration of the infiltration precursor solution, discrete and filmy LSCF coatings on the GDC scaffold can be prepared, with the film-like coating exhibiting lower initial polarization impedance and better stability. The as-obtained SOFCs exhibit enhanced peak power density and long-term operation stability.

ACS SUSTAINABLE CHEMISTRY & ENGINEERING (2022)

Article Electrochemistry

Construction of rice husk-derived SiOx nanoparticles encapsulated with graphene aerogel hybrid for high-performance lithium ion batteries

Mengfei Sun, Zhengzheng Xu, Kun Liu, Hongxun Yang, Tongyi Yang, Chao Jin, Zi Wang, Yanchun Jin, Lizhuang Chen

Summary: A SiOx/graphene aerogel (SGA) hybrid with improved electrical and ion conductivity, volume variations alleviation, and excellent electrochemical properties was developed.

ELECTROCHIMICA ACTA (2022)

Article Chemistry, Multidisciplinary

A Novel Self-Assembled Cobalt-Free Perovskite Composite Cathode with Triple-Conduction for Intermediate Proton-Conducting Solid Oxide Fuel Cells

Hua Tong, Min Fu, Yang Yang, Fanglin Chen, Zetian Tao

Summary: A novel triple-conducting and cobalt-free iron-based perovskite cathode is reported for proton-conducting solid oxide fuel cells (H-SOFCs). By modifying the composition and microstructure, this cathode material exhibits excellent cell performance at 700 degrees C.

ADVANCED FUNCTIONAL MATERIALS (2022)

Article Nanoscience & Nanotechnology

Unlocking the Potential of A-Site Ca-Doped LaCo0.2Fe0.8O3-d: A Redox-Stable Cathode Material Enabling High Current Density in Direct CO2 Electrolysis

Haixia Li, Wanhua Wang, Lucun Wang, Min Wang, Ka-Young Park, Taehee Lee, Andreas Heyden, Dong Ding, Fanglin Chen

Summary: This study investigates the use of A-site Cadoped La1-xCaxCo0.2Fe0.8O3-delta oxides as cathode materials for efficient CO2 electrolysis in an intermediate-temperature SOEC. The results show that this cathode material exhibits outstanding electrocatalytic performance and stability, making it a promising candidate for the conversion of CO2 into valuable chemicals.

ACS APPLIED MATERIALS & INTERFACES (2023)

Article Chemistry, Physical

High-performance Ruddlesden-Popper perovskite oxide with in situ exsolved nanoparticles for direct CO2 electrolysis

Ka-Young Park, Taehee Lee, Wanhua Wang, Haixia Li, Fanglin Chen

Summary: Carbon dioxide is a principal greenhouse gas responsible for global warming and extreme climate changes. Electrochemically converting CO2 into CO is a promising approach for industrial decarbonization. Solid oxide electrolysis cells (SOECs) have the potential for high-temperature CO2 electrolysis with high-energy efficiency, fast electrode kinetics, and competitive cost, but developing highly active and robust CO2 electrodes for SOECs remains a challenge.

JOURNAL OF MATERIALS CHEMISTRY A (2023)

Article Chemistry, Physical

Development of a tubular direct carbon solid oxide fuel cell stack based on lanthanum gallate electrolyte

Tianyu Chen, Zhibin Lu, Guangjin Zeng, Yongmin Xie, Jie Xiao, Zhifeng Xu

Summary: The study introduces a high-performance LSGM electrolyte-supported tubular DC-SOFC stack for portable applications, which shows great potential in developing into high-performing, efficient, and environmentally friendly portable power sources for distributed applications.

JOURNAL OF POWER SOURCES (2024)

Article Chemistry, Physical

Construction of ultrastable and high-rate performance zinc anode with three-dimensional porous structure and Schottky contact

Wenbin Tong, Yili Chen, Shijie Gong, Shaokun Zhu, Jie Tian, Jiaqian Qin, Wenyong Chen, Shuanghong Chen

Summary: In this study, a three-dimensional porous NiO interface layer with enhanced anode dynamics is fabricated, forming a Schottky contact with the zinc substrate, allowing rapid and uniform zinc plating both inside and below the interface layer. The resulting NiO@Zn exhibits exceptional stability and high capacity retention.

JOURNAL OF POWER SOURCES (2024)

Article Chemistry, Physical

Flexible low-temperature zinc ion supercapacitor based on gel electrolyte with α-MnO2@rGO electrode

Yafeng Bai, Kaidi Li, Liying Wang, Yang Gao, Xuesong Li, Xijia Yang, Wei Lu

Summary: In this study, a flexible zinc ion supercapacitor with gel electrolytes, porous alpha-MnO2@reduced graphene oxide cathode, and activated carbon/carbon cloth anode was developed. The device exhibits excellent electrochemical performance and stability, even at low temperatures, with a high cycle retention rate after 5000 cycles.

JOURNAL OF POWER SOURCES (2024)

Article Chemistry, Physical

Examining the effects of silicon based additives on the long-term cycling capabilities of cylindrical cells

Anmol Jnawali, Matt D. R. Kok, Francesco Iacoviello, Daniel J. L. Brett, Paul R. Shearing

Summary: This article presents the results of a systematic study on the electrochemical performance and mechanical changes in two types of commercial batteries with different anode chemistry. The study reveals that the swelling of anode layers in batteries with silicon-based components causes deformations in the jelly roll structure, but the presence of a small percentage of silicon does not significantly impact the cycling performance of the cells within the relevant state-of-health range for electric vehicles (EVs). The research suggests that there is room for improving the cell capacities by increasing the silicon loading in composite anodes to meet the increasing demands on EVs.

JOURNAL OF POWER SOURCES (2024)

Article Chemistry, Physical

Lithium disilicate as an alternative silicate battery material. A theoretical study

Yohandys A. Zulueta, My Phuong Pham-Ho, Minh Tho Nguyen

Summary: Advanced atomistic simulations were used to study ion transport in the Na- and K-doped lithium disilicate Li2Si2O5. The results showed that Na and K doping significantly enhanced Li ion diffusion and conduction in the material.

JOURNAL OF POWER SOURCES (2024)

Article Chemistry, Physical

Novel BaO-decorated carbon-tolerant Ni-YSZ anode fabricated by an efficient phase inversion-impregnation approach

Zongying Han, Hui Dong, Yanru Yang, Hao Yu, Zhibin Yang

Summary: An efficient phase inversion-impregnation approach is developed to fabricate BaO-decorated Ni8 mol% YSZ anode-supported tubular solid oxide fuel cells (SOFCs) with anti-coking properties. BaO nanoislands are successfully introduced inside the Ni-YSZ anode, leading to higher peak power densities and improved stability in methane fuel. Density functional theory calculations suggest that the loading of BaO nanoislands facilitates carbon elimination by capturing and dissociating H2O molecules to generate OH.

JOURNAL OF POWER SOURCES (2024)

Article Chemistry, Physical

Safe and stable Li-CO2 battery with metal-organic framework derived cathode composite and solid electrolyte

Suresh Mamidi, Dan Na, Baeksang Yoon, Henu Sharma, Anil D. Pathak, Kisor Kumar Sahu, Dae Young Lee, Cheul-Ro Lee, Inseok Seo

Summary: Li-CO2 batteries, which utilize CO2 and have a high energy density, are hindered in practical applications due to slow kinetics and safety hazards. This study introduces a stable and highly conductive ceramic-based solid electrolyte and a metal-organic framework catalyst to improve the safety and performance of Li-CO2 batteries. The optimized Li-CO2 cell shows outstanding specific capacity and cycle life, and the post-cycling analysis reveals the degradation mechanism of the electrodes. First-principles calculations based on density functional theory are also performed to understand the interactions between the catalyst and the host electrode. This research demonstrates the potential of MOF cathode catalyst for stable operation in Li-CO2 batteries.

JOURNAL OF POWER SOURCES (2024)

Article Chemistry, Physical

Synergistic effect of platinum single atoms and nanoclusters for preferential oxidation of carbon monoxide in hydrogen-rich stream

Ganghua Xiang, Zhihuan Qiu, Huilong Fei, Zhigang Liu, Shuangfeng Yin, Yuen Wu

Summary: In this study, a CeFeOx-supported Pt single atoms and subnanometric clusters catalyst was developed, which exhibits enhanced catalytic activity and stability for the preferential oxidation of CO in H2-rich stream through synergistic effect.

JOURNAL OF POWER SOURCES (2024)

Article Chemistry, Physical

Towards understanding the functional mechanism and synergistic effects of LiMn2O4-LiNi0.5Mn0.3Co0.2O2 blended positive electrodes for Lithium-ion batteries

Dimitrios Chatzogiannakis, Marcus Fehse, Maria Angeles Cabanero, Natalia Romano, Ashley Black, Damien Saurel, M. Rosa Palacin, Montse Casas-Cabanas

Summary: By coupling electrochemical testing to operando synchrotron based X-ray absorption and powder diffraction experiments, blended positive electrodes consisting of LiMn2O4 spinel (LMO) and layered LiNi0.5Mn0.3Co0.2O2 (NMC) were studied to understand their redox mechanism. It was found that blending NMC with LMO can enhance energy density at high rates, with the blend containing 25% LMO showing the best performance. Testing with a special electrochemical setup revealed that the effective current load on each blend component can vary significantly from the nominal rate and also changes with SoC. Operando studies allowed monitoring of the oxidation state evolution and changes in crystal structure, in line with the expected behavior of individual components considering their electrochemical current loads.

JOURNAL OF POWER SOURCES (2024)

Article Chemistry, Physical

We may be underestimating the power capabilities of lithium-ion capacitors

Chiara Cementon, Daniel Dewar, Thrinathreddy Ramireddy, Michael Brennan, Alexey M. Glushenkov

Summary: This Perspective discusses the specific power and power density of lithium-ion capacitors, highlighting the fact that their power characteristics are often underestimated. Through analysis, it is found that lithium-ion capacitors can usually achieve power densities superior to electrochemical supercapacitors, making them excellent alternatives to supercapacitors.

JOURNAL OF POWER SOURCES (2024)

Article Chemistry, Physical

Highly concentrated solvation structure for reversible high-voltage lithium-ion battery at low temperature

Weihao Wang, Hao Yu, Li Ma, Youquan Zhang, Yuejiao Chen, Libao Chen, Guichao Kuang, Liangjun Zhou, Weifeng Wei

Summary: This study achieved an improved electrolyte with excellent low-temperature and high-voltage performance by regulating the Li+ solvation structure and highly concentrating it. The electrolyte exhibited outstanding oxidation potential and high ionic conductivity under low temperature and high voltage conditions, providing a promising approach for the practical application of high-voltage LIBs.

JOURNAL OF POWER SOURCES (2024)

Article Chemistry, Physical

Evaluation of mitigation of capacity decay in vanadium redox flow batteries for cation- and anion-exchange membrane by validated mathematical modelling

Martin Bures, Dan Gotz, Jiri Charvat, Milos Svoboda, Jaromir Pocedic, Juraj Kosek, Alexandr Zubov, Petr Mazur

Summary: Vanadium redox flow battery is a promising energy storage solution with long-term durability, non-flammability, and high overall efficiency. Researchers have developed a mathematical model to simulate the charge-discharge cycling of the battery, and found that hydraulic connection of electrolyte tanks is the most effective strategy to reduce capacity losses, achieving a 69% reduction.

JOURNAL OF POWER SOURCES (2024)

Article Chemistry, Physical

Operando analysis of the positive active mass of lead batteries by neutron diffraction

M. Rodriguez-Gomez, J. Campo, A. Orera, F. de La Fuente, J. Valenciano, H. Fricke, D. S. Hussey, Y. Chen, D. Yu, K. An, A. Larrea

Summary: In this study, we analysed the operando performance of industrial lead cells using neutron diffraction experiments. The experiments revealed the evolution of different phases in the positive electrode, showed significant inhomogeneity of phase distribution inside the electrode, and estimated the energy efficiency of the cells.

JOURNAL OF POWER SOURCES (2024)

Article Chemistry, Physical

Double Conductive Ni-pads for a kW-class micro-tubular solid oxide fuel cell stack

Jiawei Liu, Chenpeng Wang, Yue Yao, Hao Ye, Yinglong Liu, Yingli Liu, Xiaoru Xu, Zhicong Chen, Huazheng Yang, Gang Wu, Libin Lei, Chao Wang, Bo Liang

Summary: The study focuses on utilizing double conductive Ni-pads as anode collectors in micro-tubular solid oxide fuel cells. The simulation results show excellent performance and stability of DCNPs, and also highlight the potential applications in various fields.

JOURNAL OF POWER SOURCES (2024)

Article Chemistry, Physical

Ion transport regulation of polyimide separator for safe and durable Li-metal battery

Yang Wang, Kangjie Zhou, Lang Cui, Jiabing Mei, Shengnan Li, Le Li, Wei Fan, Longsheng Zhang, Tianxi Liu

Summary: This study presents a polyimide sandwiched separator (s-PIF) for improving the cycling stability of Li-metal batteries. The s-PIF separator exhibits superior mechanical property, electrolyte adsorption/retention and ion conductivity, and enables dendrite-free Li plating/stripping process.

JOURNAL OF POWER SOURCES (2024)