4.8 Article

Compatibility of La26O27(BO3)8 electrolyte with standard cathode materials for use in proton conducting solid oxide fuel cells

期刊

JOURNAL OF POWER SOURCES
卷 196, 期 18, 页码 7435-7441

出版社

ELSEVIER
DOI: 10.1016/j.jpowsour.2011.04.041

关键词

La26O27(BO3)(8); Solid oxide fuel cells; Proton conductivity; Compatibility; AC impedance

资金

  1. FP7 Project EFFIPRO Efficient and robust fuel cell with novel ceramic proton conducting electrolyte [227560]

向作者/读者索取更多资源

The chemical and mechanical compatibility of proton conducting La26O27(BO3)(8) (LBO) electrolyte with standard cathode materials La0.7Sr0.3MnO3 (LSM), La0.75Sr0.25Cr0.5Mn0.5O3 (LSCM). La2NiO4 and Ba0.5Sr0.5Co0.8Fe0.2O3 (BSCF) was investigated. The results show that LSM, LSCM and La2NiO4 cathodes are chemically and mechanically stable with the LBO electrolyte, and BSCF reacts with LBO after heat-treatment of their mechanical ground mixtures at T = 1150 degrees C. Symmetrical cell tests based on LBO demonstrated that the values of the cathode ASR (area specific resistance) are much lower in the case of the LSM and La2NiO4 cathodes than in the case of the LSCM cathode (in humidified air at 700 degrees C: ASR(LSM) = 15 Omega cm(2); ASR(LSCM) = 60 Omega cm(2); ASR(La2NiO4) = 1 Omega cm(2)). The large value obtained for LSCM cathode may be related to the low level of its oxygen ion conductivity. Finally, a composite cathode (CER-CER) approach was used in order to optimize the polarization resistance of the LSM cathode. Several CER-CER cathodes with different cathode/electrolyte weight ratios were prepared. The lowest value of ASR for LSM-based composite cathode was obtained by adding 50 wt.% of LBO to LSM cathode (ASR(LSM/LBO) = 3.4 Omega cm(2) in humidified air at 700 degrees C). Crown Copyright (C) 2011 Published by Elsevier B.V. All rights reserved.

作者

我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。

评论

主要评分

4.8
评分不足

次要评分

新颖性
-
重要性
-
科学严谨性
-
评价这篇论文

推荐

Article Chemistry, Physical

An overview and prospective on Al and Al-ion battery technologies

Giuseppe Antonio Elia, Kostiantyn V. Kravchyk, Maksym V. Kovalenko, Joaquin Chacon, Alex Holland, Richard G. A. Wills

Summary: Aluminum batteries have high charge storage capacity and low redox potential, with a variety of electrolyte chemistry options available, classified into aqueous and non-aqueous types.

JOURNAL OF POWER SOURCES (2021)

Article Chemistry, Physical

Break-Even Analysis of All-Solid-State Batteries with Li-Garnet Solid Electrolytes

Kostiantyn V. Kravchyk, Faruk Okur, Maksym V. Kovalenko

ACS ENERGY LETTERS (2021)

Article Multidisciplinary Sciences

Design of metastable oxychalcogenide phases by topochemical (de)intercalation of sulfur in La2O2S2

Shunsuke Sasaki, Maria Teresa Caldes, Catherine Guillot-Deudon, Isabelle Braems, Gwladys Steciuk, Lukas Palatinus, Eric Gautron, Gilles Frapper, Etienne Janod, Benoit Corraze, Stephane Jobic, Laurent Cario

Summary: Researchers have successfully demonstrated the topochemical deintercalation/reintercalation of sulfur in a layered oxychalcogenide, leading to the design of novel metastable phases. By reacting La2O2S2 with monovalent metals, they produced sulfur-deintercalated metastable phases La2O2S1.5 and oA-La2O2S, with lamellar structures predicted through an evolutionary structure-prediction algorithm. This study opens up new possibilities for the unexplored topochemistry of mobile chalcogen anions.

NATURE COMMUNICATIONS (2021)

Article Chemistry, Physical

Building a Better Li-Garnet Solid Electrolyte/Metallic Li Interface with Antimony

Romain Dubey, Jordi Sastre, Claudia Cancellieri, Faruk Okur, Alexander Forster, Lea Pompizii, Agnieszka Priebe, Yaroslav E. Romanyuk, Lars P. H. Jeurgens, Maksym Kovalenko, Kostiantyn Kravchyk

Summary: The study finds that using Sb as an interface layer helps to improve the wettability of Li on LLZO, reducing the interfacial resistance. Experimental results show that both Li/Sb-coated LLZO/Li cells and LLZO/V2O5 full cells exhibit good electrochemical performance without external pressure.

ADVANCED ENERGY MATERIALS (2021)

Article Materials Science, Multidisciplinary

Perspective on design and technical challenges of Li-garnet solid-state batteries

Kostiantyn Kravchyk, Maksym Kovalenko

Summary: Solid-state Li-ion batteries based on LLZO electrolyte have made rapid advances, providing safe, non-flammable, and temperature-tolerant energy storage with improved energy densities and cycle life compared to liquid-electrolyte-based batteries. However, there are limitations in the fabrication of solid-state cathodes, LLZO electrolytes, and Li metal anode layers, as well as challenges in achieving energy densities matching conventional Li-ion systems.

SCIENCE AND TECHNOLOGY OF ADVANCED MATERIALS (2022)

Article Multidisciplinary Sciences

On the feasibility of all-solid-state batteries with LLZO as a single electrolyte

Kostiantyn Kravchyk, Dogan Tarik Karabay, Maksym Kovalenko

Summary: Replacing liquid-state electrolytes with solid-state counterparts in Li-ion batteries is a major research objective. Among the different solid-state electrolytes, garnet-type Li-ion electrolytes based on LLZO are considered promising candidates, but they still face challenges due to high density and lower ion conductivity compared to liquid electrolytes.

SCIENTIFIC REPORTS (2022)

Article Chemistry, Multidisciplinary

Thermal synthesis of conversion-type bismuth fluoride cathodes for high-energy-density Li-ion batteries

Julian F. Baumgartner, Frank Krumeich, Michael Worle, Kostiantyn Kravchyk, Maksym Kovalenko

Summary: Bismuth fluoride (BiF3) is synthesized through the thermal decomposition of bismuth trifluoroacetate, and its potential as a cathode material for lithium ion batteries is explored. BiF3 demonstrates high theoretical capacity, low volume change, and high oxidative stability, making it a promising candidate for enhancing the energy density of Li-ion batteries. The use of ionic liquid electrolytes also improves the cyclic stability of BiF3.

COMMUNICATIONS CHEMISTRY (2022)

Article Energy & Fuels

Formation of Cu(In,Ga)S2 chalcopyrite thin films following a 3-stage co-evaporation process

A. Thomere, N. Barreau, N. Stephant, C. Guillot-Deudon, E. Gautron, M. T. Caldes, A. Lafond

Summary: This study investigates the origin of the bi-layered structure of CuIn1-xGaxS2 (CIGS) films deposited following a 3-stage process. Interrupting the growth at key steps and characterizing the differences using various techniques, a model attributing composition plateaus to the formation of Cu-poor crystalline phases is proposed.

SOLAR ENERGY MATERIALS AND SOLAR CELLS (2022)

Article Materials Science, Multidisciplinary

Silicon oxycarbide-tin nanocomposite derived from a UV crosslinked single source preceramic precursor as high-performance anode materials for Li-ion batteries

Dominik Knozowski, Pradeep Vallachira Warriam Sasikumar, Romain Dubey, Marcel Aebli, Kostiantyn Kravchyk, Grzegorz Trykowski, Maksym Kovalenko, Thomas Graule, Monika Wilamowska-Zawlocka, Gurdial Blugan

Summary: In this work, a nanocomposite based on silicon oxycarbide and tin nanoparticles was synthesized using UV light. The SiOC ceramic matrix with a conductive free carbon phase showed excellent electrochemical stability and lithium-ion storage capacity. The SiOC/Sn nanocomposite exhibited high reversible capacity and stability as an anode for Li-ion batteries.

APPLIED MATERIALS TODAY (2022)

Review Chemistry, Multidisciplinary

Advances and challenges of aluminum-sulfur batteries

Matthias Klimpel, Maksym V. Kovalenko, Kostiantyn V. Kravchyk

Summary: This paper provides an overview of research pursuits in aluminum-sulfur (Al-S) batteries, focusing on the fundamental problem of polysulfide dissolution. The authors examine experimental and computational approaches to improve the chemical interactions between sulfur host materials and polysulfides, and suggest promising future research directions.

COMMUNICATIONS CHEMISTRY (2022)

Article Materials Science, Multidisciplinary

Crystal structures, frustrated magnetism, and chemical pressure in Sr-doped Ba3NiSb2O9 perovskites

Melanie Viaud, Catherine Guillot-Deudon, Eric Gautron, Maria Teresa Caldes, Guido Berlanda, Philippe Deniard, Philippe Boullay, Florence Porcher, Carole La, Celine Darie, A. Zorko, A. Ozarowski, Fabrice Bert, Philippe Mendels, Christophe Payen

Summary: The effects of chemical pressure on the structural and magnetic properties of Ba3NiSb2O9 were studied by substituting Sr2+ ions for Ba2+ions. It was found that the structure of the compound changes with increasing Sr content, leading to the stabilization of different phases with distinct magnetic interactions.

PHYSICAL REVIEW MATERIALS (2022)

Article Electrochemistry

Charge Storage Mechanism of LixWO3 Hexagonal Tungsten Bronze in Aqueous Electrolytes

Julio Cesar Espinosa-Angeles, Eric Quarez, Louis-Beni Mvele Eye'a, Camille Douard, Antonella Iadecola, Hui Shao, Pierre-Louis Taberna, Patrice Simon, Olivier Crosnier, Thierry Brousse

Summary: The electrochemical behavior of LixWO3 was studied in this work. The material was synthesized under hydrothermal conditions and exhibited nanorod-like particles with growth along the c-axis. A specific capacity of 71 C.g(-1) was obtained at a rate of 2 mV.s(-1) in a 5 M LiNO3 aqueous electrolyte, with a charge/discharge cycle time of 10 minutes. The charge storage mechanism was investigated using electrochemical quartz crystal microbalance (EQCM) and synchrotron operando X-ray absorption spectroscopy (XAS), revealing a desolvation process upon Li+ intercalation and reversible reduction/oxidation of tungsten cations during charge/discharge cycling.

BATTERIES-BASEL (2023)

Article Chemistry, Inorganic & Nuclear

Influence of Polymorphism on the Electrochemical Behavior of Dilithium (2,3-Dilithium-oxy)-terephthalate vs. Li

Lou Bernard, Alia Jouhara, Eric Quarez, Yanis Levieux-Souid, Sophie Le Caer, Pierre Tran-Van, Steven Renault, Philippe Poizot

Summary: Organic electrode materials offer opportunities for cost-effective and environmentally friendly rechargeable batteries. However, the electrochemical performance of organic materials also relies on crystal packing. Therefore, further efforts in crystal chemistry are needed to make organic materials more efficient.

INORGANICS (2022)

Article Electrochemistry

AlCl3-Saturated Ionic Liquid Anolyte with an Excess of AlCl3 for Al-Graphite Dual-Ion Batteries

Shutao Wang, Maksym V. Kovalenko, Kostiantyn V. Kravchyk

Summary: Al-graphite dual-ion batteries are a promising concept for large-scale stationary electricity storage due to their safety, low cost, long cycling life, and high energy efficiency. However, the deployment of these batteries is currently limited by their low cell-level energy density. By utilizing an AlCl3-saturated IL anolyte, researchers were able to improve the energy density of the battery significantly.

BATTERIES & SUPERCAPS (2021)

Article Electrochemistry

Laser Patterning of High-Mass-Loading Graphite Anodes for High-Performance Li-Ion Batteries

Romain Dubey, Marcel-David Zwahlen, Yevhen Shynkarenko, Sergii Yakunin, Axel Fuerst, Maksym V. Kovalenko, Kostiantyn V. Kravchyk

Summary: The rate capability and volumetric capacity of graphite electrodes can be significantly improved by laser patterning to create vertically aligned channels for rapid Li-ion transport. Laser patterned graphite electrodes exhibited enhanced performance compared to non-patterned electrodes, showing an increase in volumetric capacity.

BATTERIES & SUPERCAPS (2021)

Article Chemistry, Physical

Development of a tubular direct carbon solid oxide fuel cell stack based on lanthanum gallate electrolyte

Tianyu Chen, Zhibin Lu, Guangjin Zeng, Yongmin Xie, Jie Xiao, Zhifeng Xu

Summary: The study introduces a high-performance LSGM electrolyte-supported tubular DC-SOFC stack for portable applications, which shows great potential in developing into high-performing, efficient, and environmentally friendly portable power sources for distributed applications.

JOURNAL OF POWER SOURCES (2024)

Article Chemistry, Physical

Construction of ultrastable and high-rate performance zinc anode with three-dimensional porous structure and Schottky contact

Wenbin Tong, Yili Chen, Shijie Gong, Shaokun Zhu, Jie Tian, Jiaqian Qin, Wenyong Chen, Shuanghong Chen

Summary: In this study, a three-dimensional porous NiO interface layer with enhanced anode dynamics is fabricated, forming a Schottky contact with the zinc substrate, allowing rapid and uniform zinc plating both inside and below the interface layer. The resulting NiO@Zn exhibits exceptional stability and high capacity retention.

JOURNAL OF POWER SOURCES (2024)

Article Chemistry, Physical

Flexible low-temperature zinc ion supercapacitor based on gel electrolyte with α-MnO2@rGO electrode

Yafeng Bai, Kaidi Li, Liying Wang, Yang Gao, Xuesong Li, Xijia Yang, Wei Lu

Summary: In this study, a flexible zinc ion supercapacitor with gel electrolytes, porous alpha-MnO2@reduced graphene oxide cathode, and activated carbon/carbon cloth anode was developed. The device exhibits excellent electrochemical performance and stability, even at low temperatures, with a high cycle retention rate after 5000 cycles.

JOURNAL OF POWER SOURCES (2024)

Article Chemistry, Physical

Examining the effects of silicon based additives on the long-term cycling capabilities of cylindrical cells

Anmol Jnawali, Matt D. R. Kok, Francesco Iacoviello, Daniel J. L. Brett, Paul R. Shearing

Summary: This article presents the results of a systematic study on the electrochemical performance and mechanical changes in two types of commercial batteries with different anode chemistry. The study reveals that the swelling of anode layers in batteries with silicon-based components causes deformations in the jelly roll structure, but the presence of a small percentage of silicon does not significantly impact the cycling performance of the cells within the relevant state-of-health range for electric vehicles (EVs). The research suggests that there is room for improving the cell capacities by increasing the silicon loading in composite anodes to meet the increasing demands on EVs.

JOURNAL OF POWER SOURCES (2024)

Article Chemistry, Physical

Lithium disilicate as an alternative silicate battery material. A theoretical study

Yohandys A. Zulueta, My Phuong Pham-Ho, Minh Tho Nguyen

Summary: Advanced atomistic simulations were used to study ion transport in the Na- and K-doped lithium disilicate Li2Si2O5. The results showed that Na and K doping significantly enhanced Li ion diffusion and conduction in the material.

JOURNAL OF POWER SOURCES (2024)

Article Chemistry, Physical

Novel BaO-decorated carbon-tolerant Ni-YSZ anode fabricated by an efficient phase inversion-impregnation approach

Zongying Han, Hui Dong, Yanru Yang, Hao Yu, Zhibin Yang

Summary: An efficient phase inversion-impregnation approach is developed to fabricate BaO-decorated Ni8 mol% YSZ anode-supported tubular solid oxide fuel cells (SOFCs) with anti-coking properties. BaO nanoislands are successfully introduced inside the Ni-YSZ anode, leading to higher peak power densities and improved stability in methane fuel. Density functional theory calculations suggest that the loading of BaO nanoislands facilitates carbon elimination by capturing and dissociating H2O molecules to generate OH.

JOURNAL OF POWER SOURCES (2024)

Article Chemistry, Physical

Safe and stable Li-CO2 battery with metal-organic framework derived cathode composite and solid electrolyte

Suresh Mamidi, Dan Na, Baeksang Yoon, Henu Sharma, Anil D. Pathak, Kisor Kumar Sahu, Dae Young Lee, Cheul-Ro Lee, Inseok Seo

Summary: Li-CO2 batteries, which utilize CO2 and have a high energy density, are hindered in practical applications due to slow kinetics and safety hazards. This study introduces a stable and highly conductive ceramic-based solid electrolyte and a metal-organic framework catalyst to improve the safety and performance of Li-CO2 batteries. The optimized Li-CO2 cell shows outstanding specific capacity and cycle life, and the post-cycling analysis reveals the degradation mechanism of the electrodes. First-principles calculations based on density functional theory are also performed to understand the interactions between the catalyst and the host electrode. This research demonstrates the potential of MOF cathode catalyst for stable operation in Li-CO2 batteries.

JOURNAL OF POWER SOURCES (2024)

Article Chemistry, Physical

Synergistic effect of platinum single atoms and nanoclusters for preferential oxidation of carbon monoxide in hydrogen-rich stream

Ganghua Xiang, Zhihuan Qiu, Huilong Fei, Zhigang Liu, Shuangfeng Yin, Yuen Wu

Summary: In this study, a CeFeOx-supported Pt single atoms and subnanometric clusters catalyst was developed, which exhibits enhanced catalytic activity and stability for the preferential oxidation of CO in H2-rich stream through synergistic effect.

JOURNAL OF POWER SOURCES (2024)

Article Chemistry, Physical

Towards understanding the functional mechanism and synergistic effects of LiMn2O4-LiNi0.5Mn0.3Co0.2O2 blended positive electrodes for Lithium-ion batteries

Dimitrios Chatzogiannakis, Marcus Fehse, Maria Angeles Cabanero, Natalia Romano, Ashley Black, Damien Saurel, M. Rosa Palacin, Montse Casas-Cabanas

Summary: By coupling electrochemical testing to operando synchrotron based X-ray absorption and powder diffraction experiments, blended positive electrodes consisting of LiMn2O4 spinel (LMO) and layered LiNi0.5Mn0.3Co0.2O2 (NMC) were studied to understand their redox mechanism. It was found that blending NMC with LMO can enhance energy density at high rates, with the blend containing 25% LMO showing the best performance. Testing with a special electrochemical setup revealed that the effective current load on each blend component can vary significantly from the nominal rate and also changes with SoC. Operando studies allowed monitoring of the oxidation state evolution and changes in crystal structure, in line with the expected behavior of individual components considering their electrochemical current loads.

JOURNAL OF POWER SOURCES (2024)

Article Chemistry, Physical

We may be underestimating the power capabilities of lithium-ion capacitors

Chiara Cementon, Daniel Dewar, Thrinathreddy Ramireddy, Michael Brennan, Alexey M. Glushenkov

Summary: This Perspective discusses the specific power and power density of lithium-ion capacitors, highlighting the fact that their power characteristics are often underestimated. Through analysis, it is found that lithium-ion capacitors can usually achieve power densities superior to electrochemical supercapacitors, making them excellent alternatives to supercapacitors.

JOURNAL OF POWER SOURCES (2024)

Article Chemistry, Physical

Highly concentrated solvation structure for reversible high-voltage lithium-ion battery at low temperature

Weihao Wang, Hao Yu, Li Ma, Youquan Zhang, Yuejiao Chen, Libao Chen, Guichao Kuang, Liangjun Zhou, Weifeng Wei

Summary: This study achieved an improved electrolyte with excellent low-temperature and high-voltage performance by regulating the Li+ solvation structure and highly concentrating it. The electrolyte exhibited outstanding oxidation potential and high ionic conductivity under low temperature and high voltage conditions, providing a promising approach for the practical application of high-voltage LIBs.

JOURNAL OF POWER SOURCES (2024)

Article Chemistry, Physical

Evaluation of mitigation of capacity decay in vanadium redox flow batteries for cation- and anion-exchange membrane by validated mathematical modelling

Martin Bures, Dan Gotz, Jiri Charvat, Milos Svoboda, Jaromir Pocedic, Juraj Kosek, Alexandr Zubov, Petr Mazur

Summary: Vanadium redox flow battery is a promising energy storage solution with long-term durability, non-flammability, and high overall efficiency. Researchers have developed a mathematical model to simulate the charge-discharge cycling of the battery, and found that hydraulic connection of electrolyte tanks is the most effective strategy to reduce capacity losses, achieving a 69% reduction.

JOURNAL OF POWER SOURCES (2024)

Article Chemistry, Physical

Operando analysis of the positive active mass of lead batteries by neutron diffraction

M. Rodriguez-Gomez, J. Campo, A. Orera, F. de La Fuente, J. Valenciano, H. Fricke, D. S. Hussey, Y. Chen, D. Yu, K. An, A. Larrea

Summary: In this study, we analysed the operando performance of industrial lead cells using neutron diffraction experiments. The experiments revealed the evolution of different phases in the positive electrode, showed significant inhomogeneity of phase distribution inside the electrode, and estimated the energy efficiency of the cells.

JOURNAL OF POWER SOURCES (2024)

Article Chemistry, Physical

Double Conductive Ni-pads for a kW-class micro-tubular solid oxide fuel cell stack

Jiawei Liu, Chenpeng Wang, Yue Yao, Hao Ye, Yinglong Liu, Yingli Liu, Xiaoru Xu, Zhicong Chen, Huazheng Yang, Gang Wu, Libin Lei, Chao Wang, Bo Liang

Summary: The study focuses on utilizing double conductive Ni-pads as anode collectors in micro-tubular solid oxide fuel cells. The simulation results show excellent performance and stability of DCNPs, and also highlight the potential applications in various fields.

JOURNAL OF POWER SOURCES (2024)

Article Chemistry, Physical

Ion transport regulation of polyimide separator for safe and durable Li-metal battery

Yang Wang, Kangjie Zhou, Lang Cui, Jiabing Mei, Shengnan Li, Le Li, Wei Fan, Longsheng Zhang, Tianxi Liu

Summary: This study presents a polyimide sandwiched separator (s-PIF) for improving the cycling stability of Li-metal batteries. The s-PIF separator exhibits superior mechanical property, electrolyte adsorption/retention and ion conductivity, and enables dendrite-free Li plating/stripping process.

JOURNAL OF POWER SOURCES (2024)