Mesoporous nano-Co3O4: A potential negative electrode material for alkaline secondary battery

A potential negative electrode material (mesoporous nano-Co3O4) is synthesized via a simple thermal decomposition of precursor Co(OH)(2) hexagonal nanosheets in the air. The structure and morphology of the samples are characterized by X-ray diffraction (XRD), scanning electron microscopy (SEM) and transmission electron microscopy (TEM). It is found that the nano-Co3O4 is present in mesoporous hexagonal nanoparticles. The average size of holes is about 5-15 nm. The electrochemical performances of mesoporous nano-Co3O4 as the active starting negative electrode material for alkaline secondary battery are investigated by galvanostatic charge-discharge and cyclic voltammetry (CV) technique. The results demonstrate that the prepared mesoporous nano-Co3O4 electrode displays excellent electrochemical performance. The discharge capacity of the mesoporous nano-Co3O4 electrode can reach 436.5 mAh g(-1) and retain about 351.5 mAh g(-1) after 100 cycles at discharge current of 100 mA g(-1). A properly electrochemical reaction mechanism of mesoporous nano-Co3O4 electrode is also constructed in detail. (C) 2011 Elsevier B.V. All rights reserved.