4.8 Article

Synthesis and performance of Sr1.5LaxMnO4 as cathode materials for intermediate temperature solid oxide fuel cell

期刊

JOURNAL OF POWER SOURCES
卷 196, 期 14, 页码 5835-5839

出版社

ELSEVIER SCIENCE BV
DOI: 10.1016/j.jpowsour.2011.03.016

关键词

Intermediate temperature solid oxide fuel cell (IT-SOFC); Cathode materials; Sr1.5LaxMnO4; Electrode reaction

资金

  1. National Natural Science Foundation of China [51072048]
  2. Research Project of New Century Excellent Talents in University [NCET-06-0349]
  3. Heilongjiang Educational Department [GZ09A204, 1152G027, 11531274, 11531285]

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A-site non-stoichiometric materials Sr1.5LaxMnO4 (x = 0.35, 0.40, 0.45) are prepared via solid state reaction. The structure of these materials is determined to be tetragonal. Both the lattice volume and the thermal expansion coefficient reduce with the decrease of lanthanum content. On the contrary, the conductivity increases and the maximum value of 13.9 S cm(-1) is found for Sr1.5La0.35MnO4 at 750 degrees C in air. AC impedance spectroscopy and DC polarization measurements are used to study the electrode performance. The optimum composition of Sr0.5La0.35MnO4 results in 0.25 Omega cm(2) area specific resistance (ASR) at 750 degrees C in air. The oxygen partial pressure measurement indicates that the charge transfer process is the rate-limiting step of the electrode reactions. (C) 2011 Elsevier B.V. All rights reserved.

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