期刊
JOURNAL OF POWER SOURCES
卷 195, 期 19, 页码 6443-6449出版社
ELSEVIER SCIENCE BV
DOI: 10.1016/j.jpowsour.2010.03.062
关键词
Proton exchange membrane; Post-sulfonation; Carboxyl group; Cross-linking
资金
- China High-Tech Development 863 Program [2007AA03Z218]
A novel poly(ether ether ketone) (PEEK) containing pendant carboxyl groups has been synthesized by a nucleophilic polycondensation reaction. Sulfonated polymers (SPEEKs) with different ion exchange capacity are then obtained by post-sulfonation process. The structures of PEEK and SPEEKs are characterized by both FT-IR and H-1 NMR. The properties of SPEEKs as candidates for proton exchange membranes are studied. The cross-linking reaction is performed at 140 degrees C using poly(vinyl alcohol) (PVA) as the cross-linker. In comparison with the non-cross-linked membranes, some properties of the cross-linked membranes are significantly improved, such as water uptake, methanol resistance, mechanical and oxidative stabilities, while the proton conductivity decreases. The effect of PVA content on proton conductivity, water uptake, swelling ratio, and methanol permeability is also investigated. Among all the membranes, SPEEK-C-8 shows the highest selectivity of 50.5 x 10(4) S s cm(-3), which indicates that it is a suitable candidate for applications in direct methanol fuel cells. (C) 2010 Elsevier B.V. All rights reserved.
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