期刊
JOURNAL OF POWER SOURCES
卷 195, 期 22, 页码 7644-7648出版社
ELSEVIER
DOI: 10.1016/j.jpowsour.2010.05.053
关键词
Lithium battery; X-ray spectroscopy; Depth profile; Manganese oxide; Valence state
资金
- Office of Basic Energy Sciences, Chemical Sciences Division of the U.S. Department of Energy [DE-AC03-76SF00098]
- U.S. Department of Energy, Office of Science, Office of Basic Energy Sciences [DE-AC02-06CH11357]
- Office of Science/BES, of the U.S. DoE [DE-AC02-05CH11231]
- European Commission [CT-2006-042095]
A 50-mu m thick lithium manganese oxide (parent material LiMn2O4) battery electrode (positive electrode; cathode) was charged, slightly discharged and then sliced with a scotch tape test-type method. A selected number of slices was then subject to synchrotron soft X-ray emission spectroscopy near the Mn L-alpha,L-beta emission lines in order to determine changes in the oxidation state of the manganese as a function of sampling depth. The emission spectra showed a minute yet noticeable and systematic chemical shift of up to 0.25 eV between the layer near the current collector and the layer near the electrolyte separator. The average manganese oxidation state near the separator was smaller than the average oxidation state in the interior of the electrode, or near the current collector. Since the data provide an oxidation state depth profile of the cathode, a Li+ depth profile can be inferred. This method provides information on the spatial chemical inhomogeneity of electrodes prior to and after electrochemical cycling, and thus can aid in degradation studies. (C) 2010 Elsevier B.V. All rights reserved.
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