4.8 Article

Mass spectroscopy for the anode gas layer in a semi-passive DMFC using porous carbon plate Part I: Relationship between the gas composition and the current density

期刊

JOURNAL OF POWER SOURCES
卷 194, 期 2, 页码 610-617

出版社

ELSEVIER SCIENCE BV
DOI: 10.1016/j.jpowsour.2009.07.027

关键词

Passive DMFC; Anode gas layer; Porous carbon plate; Mass spectrometry; Partial pressure of methanol

资金

  1. JSPS KAKENHI [1936057]
  2. Nippon Sheet Glass Foundation

向作者/读者索取更多资源

In situ mass spectroscopy with a capillary probe was conducted for the anode gas layer of a semi-passive direct methanol fuel cell (DMFC) employing a porous carbon plate (PCP) in order to evaluate the gas composition in contact with the anode. Different types of PCPs were used for the DMFC, and then the relationship between the gas composition in the gas layer and the current density was investigated. The profiles of the CO2 gas pressure, methanol and water vapor pressures were discussed on the basis of the current density and the resistance for the methanol and CO2 transport through the PCP. The current density linearly and identically increased with the increase in the partial pressure of methanol, P-CH3OH, in the gas layer up to 7.5 kPa irrespective of the type of the PCP suggesting that the current was a function of P-CH3OH and it was rate limited by the methanol transport to the anode. The calculated liquid methanol concentration equivalent to the measured gas mixture in the gas layer was about 5-7 M in the optimum conditions. This confirmed that the actual methanol activity on the anode of the DMFC with the PCP was controlled by the PCP and was similar to that of the usual liquid feed DMFC even when a very high concentration of methanol was in the reservoir. (C) 2009 Elsevier B.V. All rights reserved.

作者

我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。

评论

主要评分

4.8
评分不足

次要评分

新颖性
-
重要性
-
科学严谨性
-
评价这篇论文

推荐

Article Biochemistry & Molecular Biology

Biotic Cathode of Graphite Fibre Brush for Improved Application in Microbial Fuel Cells

Siti Farah Nadiah Rusli, Siti Mariam Daud, Mimi Hani Abu Bakar, Kee Shyuan Loh, Mohd Shahbudin Masdar

Summary: The study investigates the effect of electrode combination between non-chemical modified stainless steel and graphite fibre brush in a microbial fuel cell system. The results show that the combination of graphite fibre brush as both anode and cathode generates the highest power density and lowest internal resistance, indicating the best performance among the tested electrode combinations.

MOLECULES (2022)

Article Thermodynamics

Dehumidification behavior of an aluminophosphate zeolite coated crossflow heat exchanger driven with direct hot water heating and evaporative cooling

Seng Sunhor, Yugo Osaka, Takuya Tsujiguchi, Akio Kodama, Dendi Adi Saputra

Summary: In this study, the influence of cooling air velocity, regeneration hot water temperature, and adsorption/regeneration cycle time on a heat exchanger coated with aluminophosphate zeolite for desiccant dehumidification was experimentally investigated. The results showed that the minimum humidity of the adsorption outlet air decreased with an increase in the cooling air velocity and adsorption/desorption time. However, the maximum time-averaged amount of dehumidification appeared at an appropriate cycle time, and increasing the cooling air velocity had a positive impact on both the momentary observed minimum humidity and time-averaged amount of dehumidification. The temperature of the hot water also contributed to the increase in the time-averaged amount of dehumidification.

APPLIED THERMAL ENGINEERING (2022)

Article Biochemistry & Molecular Biology

Core Shell Nanostructure: Impregnated Activated Carbon as Adsorbent for Hydrogen Sulfide Adsorption

Nurul Noramelya Zulkefli, Rajeevelosana Seladorai, Mohd Shahbudin Masdar, Nabilah Mohd Sofian, Wan Nor Roslam Wan Isahak

Summary: This study focuses on the synthesis, characterization, and performance evaluation of core shell nanostructure adsorbent for hydrogen sulfide (H2S) capture. Different preparation techniques were used to modify commercial coconut shell activated carbon (CAC) and the performance of the synthesized adsorbents was analyzed. The results showed that a specific combination of adsorbents exhibited better adsorption capacity, but degradation was also observed.

MOLECULES (2022)

Article Chemistry, Physical

Effect of Bimetallic-Activated Carbon Impregnation on Adsorption-Desorption Performance for Hydrogen Sulfide (H2S) Capture

Nurul Noramelya Zulkefli, Loshinni S. Mathuray Veeran, Adam Mohd Izhan Noor Azam, Mohd Shahbudin Masdar, Wan Nor Roslam Wan Isahak

Summary: This study investigates the impregnation of bi-metallic adsorbents on commercial coconut activated carbon and their potential for biogas purification. The modified adsorbents were characterized and tested for H2S capture. The results showed that ZnAc2/TiO2/CAC_DCM exhibited increased adsorption capacity, while ZnAc2/ZnO/CAC_DCM had the lowest degradation percentage.

MATERIALS (2022)

Article Energy & Fuels

Integrated Energy System Powered a Building in Sharjah Emirates in the United Arab Emirates

Tareq Salameh, Abdul Ghani Olabi, Mohammad Ali Abdelkareem, Mohd Shahbudin Masdar, Siti Kartom Kamarudin, Enas Taha Sayed

Summary: A study was conducted on a green hydrogen system for powering an office building in the Sharjah emirate, United Arab Emirates. A hybrid green hydrogen energy system was compared to a standard hybrid system, and both systems met the power requirements of the office building. The cost of energy was similar for both systems, but the operational and replacement costs were higher for the basic system compared to the green hydrogen system. The green hydrogen system also had a significantly lower carbon footprint compared to the basic system, reducing carbon dioxide emissions by a ratio of 4.6.

ENERGIES (2023)

Article Biochemistry & Molecular Biology

Performance and Characterization of Bi-Metal Compound on Activated Carbon for Hydrogen Sulfide Removal in Biogas

Nurul Noramelya Zulkefli, Adam Mohd Izhan Noor Azam, Mohd Shahbudin Masdar, Nurul Akidah Baharuddin, Wan Nor Roslam Wan Isahak, Nabilah Mohd Sofian

Summary: This study reports on the synthesis of bi-metal compound (BMC) adsorbents based on commercial coconut activated carbon (CAC) that were surface-modified to enhance their adsorption capacity for hydrogen sulfide (H2S). The results showed that the modified solution uniformly covered the adsorbent surface, and the synthesized adsorbents had a higher H2S loading capacity. Therefore, these novel adsorbents hold potential for applications in H2S capture.

MOLECULES (2022)

Article Chemistry, Physical

Adsorption-Desorption Behavior of Hydrogen Sulfide Capture on a Modified Activated Carbon Surface

Nurul Noramelya Zulkefli, Adam Mohd Izhan Noor Azam, Mohd Shahbudin Masdar, Wan Nor Roslam Wan Isahak

Summary: Metal-based adsorbents with varying active phase loadings were synthesized for H2S capture. The adsorption performance was evaluated and modified adsorbents showed the highest adsorption capacity. The behavioral model for H2S adsorption-desorption was validated effectively and the adsorbents' capability at the highest number of adsorption-desorption cycles was demonstrated.

MATERIALS (2023)

Article Polymer Science

Parametric Study and Electrocatalyst of Polymer Electrolyte Membrane (PEM) Electrolysis Performance

Adam Mohd Izhan Noor Azam, Ng Khai Li, Nurul Noramelya Zulkefli, Mohd Shahbudin Masdar, Edy Herianto Majlan, Nurul Akidah Baharuddin, Azran Mohd Zainoodin, Rozan Mohamad Yunus, Noor Shahirah Shamsul, Teuku Husaini, Siti Nur Amira Shaffee

Summary: The effects of operating parameters and electrode types on hydrogen gas production through electrolysis were investigated in a PEM electrolyzer. Various parameters including power supply, feed water flow rate, water temperature, and anode electrocatalyst type were varied. The best performance was observed with a flow rate of 2 mL/min and a temperature of 70 degrees C, using a membrane electrode assembly with a 3.0 mg/cm2 IrRuOx catalyst at the anode side. Optimal energy consumption was achieved at a current density of around 200 mA/cm2, with voltaic and energy efficiencies of 85% and 67.5% respectively. These findings highlight the importance of optimizing operating parameters to enhance the performance and reduce the costs of PEM electrolyzers.

POLYMERS (2023)

Article Chemistry, Physical

Structural transformation doubly triggered by hydrothermal temperature and reaction time in 3D mixed transition metal oxide: Great enhancement of pore size distribution and specific surface area

Nor Fatina Raduwan, Norazuwana Shaari, Siti Kartom Kamarudin, Mohd Shabudin Masdar, Rozan Mohamad Yunus

Summary: The 3D nanostructured binary metal oxides, such as hierarchical tremella-like NiCo2O4, shows great potential in energy-related applications due to their excellent electrochemical performance and stability. The crystal structure, morphology, particles size, surface area, and pore size distribution of NiCo2O4 powders synthesized through hydrothermal and annealing processes were investigated. The results indicated that the temperature and reaction time in the hydrothermal process greatly influenced the quality and morphological structures of NiCo2O4 powders, which in turn affected the electrochemical performance of fuel cells.

INTERNATIONAL JOURNAL OF HYDROGEN ENERGY (2023)

Article Polymer Science

Investigation of Performance of Anion Exchange Membrane (AEM) Electrolysis with Different Operating Conditions

Adam Mohd Izhan Noor Azam, Thuushren Ragunathan, Nurul Noramelya Zulkefli, Mohd Shahbudin Masdar, Edy Herianto Majlan, Rozan Mohamad Yunus, Noor Shahirah Shamsul, Teuku Husaini, Siti Nur Amira Shaffee

Summary: This work evaluates the performance of anion exchange membrane (AEM) electrolysis and conducts a parametric study to understand the effects of different operating parameters on AEM efficiency. Variations in potassium hydroxide (KOH) electrolyte concentration (0.5-2.0 M), electrolyte flow rate (1-9 mL/min), and operating temperature (30-60 degrees C) were investigated. The highest hydrogen production was achieved with a 2.0 M electrolyte concentration, 60 degrees C operating temperature, and 9 mL/min electrolyte flow at 2.38 V applied voltage. The hydrogen production reached 61.13 mL/min with an energy consumption of 48.25 kW.h/kg and an energy efficiency of 69.64%.

POLYMERS (2023)

Article Engineering, Chemical

Zeolite-coated fin-coil heat exchanger for CO2 recovery from simulated dry flue gas via low-temperature-heat-driven TSA

Heak Vannak, Yugo Osaka, Takuya Tsujiguchi, Akio Kodama

Summary: This study investigates the performance of adsorbent-coated heat exchangers for CO2 capture from dry flue gas. The results show that the coated adsorbent achieved similar CO2 concentration and higher CO2 recovery compared to packed adsorbent, thanks to enhanced heat transfer. The effects of different parameters, such as coating thickness and contact area, on the performance of adsorbent-coated heat exchangers were also evaluated.

SEPARATION AND PURIFICATION TECHNOLOGY (2023)

Article Environmental Sciences

Adaptive Neuro-Fuzzy Inference System Modeling and Optimization of Microbial Fuel Cells for Wastewater Treatment

Mohammad Ali Abdelkareem, Samah Ibrahim Alshathri, Mohd Shahbudin Masdar, Abdul Ghani Olabi

Summary: This research aims to improve the power density and Cr(VI) removal efficiency of microbial fuel cells (MFCs) using ANFIS modeling and artificial ecosystem optimization (AEO). The experimental results show that integrating ANFIS and AEO can significantly enhance the power density and Cr(VI) removal efficiency.
Article Thermodynamics

Performance variation of a desiccant wheel dehumidifier equipped with a sensible heat exchanger due to experimental fluctuations in regenerative heat input

Dendi Adi Saputra, Yugo Osaka, Takuya Tsujiguchi, Akio Kodama

Summary: This study investigates the impact of different control strategies on the performance of a single desiccant wheel dehumidifier with a heat recovery in real-world applications. A method to minimize the performance fluctuation as an effect of dynamic system performance response is proposed. The results showed that implementing a rotational control speed in the optimum operation mode effectively prevents the decline in system performance.

CASE STUDIES IN THERMAL ENGINEERING (2023)

Review Biochemistry & Molecular Biology

Perovskite Membranes: Advancements and Challenges in Gas Separation, Production, and Capture

Abdul Hai Alami, Adnan Alashkar, Mohammad Ali Abdelkareem, Hegazy Rezk, Mohd Shahbudin Masdar, Abdul Ghani Olabi

Summary: Perovskite membranes are highly selective and permeable in gas separation and production. They are composed of perovskite oxides with a tailored crystalline structure. These membranes have applications in oxygen enrichment, carbon capture, and hydrogen production for various industrial purposes.

MEMBRANES (2023)

Article Chemistry, Analytical

Air-Purge Regenerative Direct Air Capture Using an Externally Heated and Cooled Temperature-Swing Adsorber Packed with Solid Amine

Heak Vannak, Yugo Osaka, Takuya Tsujiguchi, Akio Kodama

Summary: CO2 capture from air via temperature swing adsorption (TSA) and the use of low-volatility polyamine-loaded silica in double-pipe heat exchangers can achieve rough enrichment of CO2. A double-step adsorption process can simultaneously increase CO2 adsorption and recovery. This method can produce a product gas with a CO2 concentration 100 times higher than the raw gas, with a recovery ratio of 60%. Therefore, the reflux step significantly enhances CO2 capture via adsorption from elevated-CO2-concentration recirculating gas.

SEPARATIONS (2023)

Article Chemistry, Physical

Development of a tubular direct carbon solid oxide fuel cell stack based on lanthanum gallate electrolyte

Tianyu Chen, Zhibin Lu, Guangjin Zeng, Yongmin Xie, Jie Xiao, Zhifeng Xu

Summary: The study introduces a high-performance LSGM electrolyte-supported tubular DC-SOFC stack for portable applications, which shows great potential in developing into high-performing, efficient, and environmentally friendly portable power sources for distributed applications.

JOURNAL OF POWER SOURCES (2024)

Article Chemistry, Physical

Construction of ultrastable and high-rate performance zinc anode with three-dimensional porous structure and Schottky contact

Wenbin Tong, Yili Chen, Shijie Gong, Shaokun Zhu, Jie Tian, Jiaqian Qin, Wenyong Chen, Shuanghong Chen

Summary: In this study, a three-dimensional porous NiO interface layer with enhanced anode dynamics is fabricated, forming a Schottky contact with the zinc substrate, allowing rapid and uniform zinc plating both inside and below the interface layer. The resulting NiO@Zn exhibits exceptional stability and high capacity retention.

JOURNAL OF POWER SOURCES (2024)

Article Chemistry, Physical

Flexible low-temperature zinc ion supercapacitor based on gel electrolyte with α-MnO2@rGO electrode

Yafeng Bai, Kaidi Li, Liying Wang, Yang Gao, Xuesong Li, Xijia Yang, Wei Lu

Summary: In this study, a flexible zinc ion supercapacitor with gel electrolytes, porous alpha-MnO2@reduced graphene oxide cathode, and activated carbon/carbon cloth anode was developed. The device exhibits excellent electrochemical performance and stability, even at low temperatures, with a high cycle retention rate after 5000 cycles.

JOURNAL OF POWER SOURCES (2024)

Article Chemistry, Physical

Examining the effects of silicon based additives on the long-term cycling capabilities of cylindrical cells

Anmol Jnawali, Matt D. R. Kok, Francesco Iacoviello, Daniel J. L. Brett, Paul R. Shearing

Summary: This article presents the results of a systematic study on the electrochemical performance and mechanical changes in two types of commercial batteries with different anode chemistry. The study reveals that the swelling of anode layers in batteries with silicon-based components causes deformations in the jelly roll structure, but the presence of a small percentage of silicon does not significantly impact the cycling performance of the cells within the relevant state-of-health range for electric vehicles (EVs). The research suggests that there is room for improving the cell capacities by increasing the silicon loading in composite anodes to meet the increasing demands on EVs.

JOURNAL OF POWER SOURCES (2024)

Article Chemistry, Physical

Lithium disilicate as an alternative silicate battery material. A theoretical study

Yohandys A. Zulueta, My Phuong Pham-Ho, Minh Tho Nguyen

Summary: Advanced atomistic simulations were used to study ion transport in the Na- and K-doped lithium disilicate Li2Si2O5. The results showed that Na and K doping significantly enhanced Li ion diffusion and conduction in the material.

JOURNAL OF POWER SOURCES (2024)

Article Chemistry, Physical

Novel BaO-decorated carbon-tolerant Ni-YSZ anode fabricated by an efficient phase inversion-impregnation approach

Zongying Han, Hui Dong, Yanru Yang, Hao Yu, Zhibin Yang

Summary: An efficient phase inversion-impregnation approach is developed to fabricate BaO-decorated Ni8 mol% YSZ anode-supported tubular solid oxide fuel cells (SOFCs) with anti-coking properties. BaO nanoislands are successfully introduced inside the Ni-YSZ anode, leading to higher peak power densities and improved stability in methane fuel. Density functional theory calculations suggest that the loading of BaO nanoislands facilitates carbon elimination by capturing and dissociating H2O molecules to generate OH.

JOURNAL OF POWER SOURCES (2024)

Article Chemistry, Physical

Safe and stable Li-CO2 battery with metal-organic framework derived cathode composite and solid electrolyte

Suresh Mamidi, Dan Na, Baeksang Yoon, Henu Sharma, Anil D. Pathak, Kisor Kumar Sahu, Dae Young Lee, Cheul-Ro Lee, Inseok Seo

Summary: Li-CO2 batteries, which utilize CO2 and have a high energy density, are hindered in practical applications due to slow kinetics and safety hazards. This study introduces a stable and highly conductive ceramic-based solid electrolyte and a metal-organic framework catalyst to improve the safety and performance of Li-CO2 batteries. The optimized Li-CO2 cell shows outstanding specific capacity and cycle life, and the post-cycling analysis reveals the degradation mechanism of the electrodes. First-principles calculations based on density functional theory are also performed to understand the interactions between the catalyst and the host electrode. This research demonstrates the potential of MOF cathode catalyst for stable operation in Li-CO2 batteries.

JOURNAL OF POWER SOURCES (2024)

Article Chemistry, Physical

Synergistic effect of platinum single atoms and nanoclusters for preferential oxidation of carbon monoxide in hydrogen-rich stream

Ganghua Xiang, Zhihuan Qiu, Huilong Fei, Zhigang Liu, Shuangfeng Yin, Yuen Wu

Summary: In this study, a CeFeOx-supported Pt single atoms and subnanometric clusters catalyst was developed, which exhibits enhanced catalytic activity and stability for the preferential oxidation of CO in H2-rich stream through synergistic effect.

JOURNAL OF POWER SOURCES (2024)

Article Chemistry, Physical

Towards understanding the functional mechanism and synergistic effects of LiMn2O4-LiNi0.5Mn0.3Co0.2O2 blended positive electrodes for Lithium-ion batteries

Dimitrios Chatzogiannakis, Marcus Fehse, Maria Angeles Cabanero, Natalia Romano, Ashley Black, Damien Saurel, M. Rosa Palacin, Montse Casas-Cabanas

Summary: By coupling electrochemical testing to operando synchrotron based X-ray absorption and powder diffraction experiments, blended positive electrodes consisting of LiMn2O4 spinel (LMO) and layered LiNi0.5Mn0.3Co0.2O2 (NMC) were studied to understand their redox mechanism. It was found that blending NMC with LMO can enhance energy density at high rates, with the blend containing 25% LMO showing the best performance. Testing with a special electrochemical setup revealed that the effective current load on each blend component can vary significantly from the nominal rate and also changes with SoC. Operando studies allowed monitoring of the oxidation state evolution and changes in crystal structure, in line with the expected behavior of individual components considering their electrochemical current loads.

JOURNAL OF POWER SOURCES (2024)

Article Chemistry, Physical

We may be underestimating the power capabilities of lithium-ion capacitors

Chiara Cementon, Daniel Dewar, Thrinathreddy Ramireddy, Michael Brennan, Alexey M. Glushenkov

Summary: This Perspective discusses the specific power and power density of lithium-ion capacitors, highlighting the fact that their power characteristics are often underestimated. Through analysis, it is found that lithium-ion capacitors can usually achieve power densities superior to electrochemical supercapacitors, making them excellent alternatives to supercapacitors.

JOURNAL OF POWER SOURCES (2024)

Article Chemistry, Physical

Highly concentrated solvation structure for reversible high-voltage lithium-ion battery at low temperature

Weihao Wang, Hao Yu, Li Ma, Youquan Zhang, Yuejiao Chen, Libao Chen, Guichao Kuang, Liangjun Zhou, Weifeng Wei

Summary: This study achieved an improved electrolyte with excellent low-temperature and high-voltage performance by regulating the Li+ solvation structure and highly concentrating it. The electrolyte exhibited outstanding oxidation potential and high ionic conductivity under low temperature and high voltage conditions, providing a promising approach for the practical application of high-voltage LIBs.

JOURNAL OF POWER SOURCES (2024)

Article Chemistry, Physical

Evaluation of mitigation of capacity decay in vanadium redox flow batteries for cation- and anion-exchange membrane by validated mathematical modelling

Martin Bures, Dan Gotz, Jiri Charvat, Milos Svoboda, Jaromir Pocedic, Juraj Kosek, Alexandr Zubov, Petr Mazur

Summary: Vanadium redox flow battery is a promising energy storage solution with long-term durability, non-flammability, and high overall efficiency. Researchers have developed a mathematical model to simulate the charge-discharge cycling of the battery, and found that hydraulic connection of electrolyte tanks is the most effective strategy to reduce capacity losses, achieving a 69% reduction.

JOURNAL OF POWER SOURCES (2024)

Article Chemistry, Physical

Operando analysis of the positive active mass of lead batteries by neutron diffraction

M. Rodriguez-Gomez, J. Campo, A. Orera, F. de La Fuente, J. Valenciano, H. Fricke, D. S. Hussey, Y. Chen, D. Yu, K. An, A. Larrea

Summary: In this study, we analysed the operando performance of industrial lead cells using neutron diffraction experiments. The experiments revealed the evolution of different phases in the positive electrode, showed significant inhomogeneity of phase distribution inside the electrode, and estimated the energy efficiency of the cells.

JOURNAL OF POWER SOURCES (2024)

Article Chemistry, Physical

Double Conductive Ni-pads for a kW-class micro-tubular solid oxide fuel cell stack

Jiawei Liu, Chenpeng Wang, Yue Yao, Hao Ye, Yinglong Liu, Yingli Liu, Xiaoru Xu, Zhicong Chen, Huazheng Yang, Gang Wu, Libin Lei, Chao Wang, Bo Liang

Summary: The study focuses on utilizing double conductive Ni-pads as anode collectors in micro-tubular solid oxide fuel cells. The simulation results show excellent performance and stability of DCNPs, and also highlight the potential applications in various fields.

JOURNAL OF POWER SOURCES (2024)

Article Chemistry, Physical

Ion transport regulation of polyimide separator for safe and durable Li-metal battery

Yang Wang, Kangjie Zhou, Lang Cui, Jiabing Mei, Shengnan Li, Le Li, Wei Fan, Longsheng Zhang, Tianxi Liu

Summary: This study presents a polyimide sandwiched separator (s-PIF) for improving the cycling stability of Li-metal batteries. The s-PIF separator exhibits superior mechanical property, electrolyte adsorption/retention and ion conductivity, and enables dendrite-free Li plating/stripping process.

JOURNAL OF POWER SOURCES (2024)