期刊
JOURNAL OF POWER SOURCES
卷 186, 期 1, 页码 211-215出版社
ELSEVIER
DOI: 10.1016/j.jpowsour.2008.09.075
关键词
Polymer gel electrolyte; Nonflammability; Triethyl phosphate; Lithium ion battery; Cycleability
资金
- New Energy and Industrial Technology Development Organization (NEDO) of Japan
Nonflammable polymeric gel electrolyte has been prepared by immobilizing 1 M LiBF4/EC+DEC+TEP (55:25:20, v/v/v, EC: ethylene carbonate, DEC: diethyl carbonate and TEP: triethyl phosphate) solution in poly(vinylidene fluoride-co-hexafluoro propylene) (PVdF-HFP) where TEP acts as a fire-retardant solvent in the gel electrolyte. The polymeric gel electrolyte has a high value of ionic conductivity of 1.76 mS cm(-1) at 28 degrees C. Thermal safety calorimetry (TSC) experiments show good thermal stability of the gel electrolyte. Cyclic voltammetry and charge/discharge cycling tests were performed on LiMn2O4/gel electrolyte and graphite/gel electrolyte half cells. The gel electrolyte works well for graphite/LiMn2O4 cell although some improvement in the cycleability of the graphite electrode is still needed. (C) 2008 Elsevier B.V. All rights reserved.
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