期刊
JOURNAL OF PORPHYRINS AND PHTHALOCYANINES
卷 15, 期 7-8, 页码 678-685出版社
WORLD SCI PUBL CO INC
DOI: 10.1142/S1088424611003616
关键词
porphyrin; cyanine dye; two-photon absorption
资金
- Ministry of Education, Culture, Sports, Science and Technology, Japan (Monbu Kagakusho) [18750118]
- Grants-in-Aid for Scientific Research [18750118, 22750124] Funding Source: KAKEN
New porphyrin-(cyanine dye) composites, in which two porphyrins are bridged by a cyanine dye through triple bonds, were synthesized. In the UV-vis absorption spectra of the composites, the Soret band and Q-band were red-shifted to 436 and 575-640 nm, respectively. The absorption originating from the cyanine dye portion was also red-shifted from 710 nm to 764 nm, suggesting the expansion of pi-conjugation over the porphyrin and cyanine dye parts. Fluorescence studies suggested that energy transfer from the porphyrin portion to the cyanine dye moiety occurred. The fluorescence intensity decreased with increasing dielectric constants of solvents, suggesting intramolecular photoinduced electron transfer from the porphyrin to the cyanine dye parts. The effective two-photon absorption (2PA) cross-section values were measured using a nanosecond open aperture Z-scan method. The maximum effective 2PA cross-section and two-photon excited fluorescence cross-section values were 33,000 GM and 4,800 GM, respectively, at 860 nm in toluene/pyridine (95:5).
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