期刊
JOURNAL OF PORPHYRINS AND PHTHALOCYANINES
卷 13, 期 10, 页码 1034-1039出版社
WORLD SCI PUBL CO INC
DOI: 10.1142/S1088424609001303
关键词
phthalocyanines; fullerenes; electron donor-acceptor conjugates; electron donor-acceptor hybrids; charge transfer
资金
- SFB 583
- DFG [GU 517/4-1]
- FCI
- Office of Basic Energy Sciences of the US Department of Energy
- COST [D-35/0015/05]
- Ministerio de Ciencia y Tecnologia [CTQ2008-00418/BQU, ESF-MEC MAT2006-28180-E]
- Comunidad de Madrid MADRISOLAR [S-0505/PPQ/0225]
Fullerenes and phthalocyanines are ideally suited for devising integrated, multi-component model systems to transmit and process solar energy. Implementation of C-60 as a three-dimensional electron acceptor bears great promises on account of its small reorganization energy in electron transfer reactions and has exerted a noteworthy impact on the improvement of light-induced charge separation. This mini-review describes how the specific composition of phthalocyanines chromophores associated with C-60 yielding artificial light-harvesting antenna and reaction center mimics - have been elegantly utilized to tune the electronic couplings between donor and acceptor sites. Specifically, the effects that these parameters have on the rate, yield and lifetime of the energetic charge-separated states are considered.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据