期刊
JOURNAL OF POLYMER SCIENCE PART B-POLYMER PHYSICS
卷 48, 期 6, 页码 706-711出版社
WILEY-BLACKWELL
DOI: 10.1002/polb.21940
关键词
blends; crystallization; morphology; spherulites
资金
- Ministry of Education, Science, Sports and Culture, Japan
- Japan Society for the Promotion of Science [19550211]
- Grants-in-Aid for Scientific Research [19550211] Funding Source: KAKEN
Miscible blends of three crystalline polymers, namely poly(butylene succinate) (PBS), poly(ethylene succinate) (PES), and poly(oxyethylene) (POE), exhibited interpenetrating spherulites, where a spherulite of one component grows inside the spherulites of other components. PBS and PES were immiscible above the melting points, T(m), of these substances, while ternary blends with POE showed miscibility, which depended on the molecular weight of POE. PBS and PES exhibited the same spherulitic growth process as in a miscible binary blend when they were crystallized from a homogeneous ternary melt. Spherulites of PBS, which is the highest T(m) component, filled the whole volume first when a miscible ternary blend was quenched below T(m) of POE, the lowest-T(m) component. Then, the blends showed either two types of crystallization processes. One was successive nucleation and growth of PES and POE spherulites, that is, PES nucleated and developed spherulites inside the PBS spherulites and then POE spherulites grew inside the interlocked spherulites of PBS and PES. The other was simultaneous growth and the formation of interpenetrating spherulites of PES and POE inside the PBS spherulites. (C) 2010 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 48: 706-711, 2010
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