期刊
JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY
卷 49, 期 15, 页码 3328-3337出版社
WILEY
DOI: 10.1002/pola.24769
关键词
amphiphilic; graft copolymers; RAFT; SET-LRP; stimuli-responsive
资金
- National Natural Science Foundation of China [20974117, 20904065, 50873029, 51073042]
- Shanghai Scientific and Technological Innovation Project [08431902300, 10431903000]
- Shanghai Nano-Technology Program [0952nm05800]
A series of well-defined amphiphilic graft copolymers bearing hydrophobic poly(tert-butyl acrylate) backbone and hydrophilic poly[poly(ethylene glycol) methyl ether methacrylate)] (PPEGMEMA) side chains were synthesized by sequential reversible addition fragmentation chain transfer (RAFT) polymerization and single-electron-transfer living radical polymerization (SET-LRP) without any polymeric functional group transformation. A new Br-containing acrylate monomer, tert-butyl 2-((2-bromoisobutanoyloxy)methyl)acrylate (tBBIBMA), was first prepared, which can be homopolymerized by RAFT to give a well-defined PtBBIBMA homopolymer with a narrow molecular weight distribution (M-w/M-n 1.15). This homopolymer with pendant Br initiation group in every repeating unit initiated SET-LRP of PEGMEMA at 45 degrees C using CuBr/dHbpy as catalytic system to afford well-defined PtBBIBMA-g-PPEGMEMA graft copolymers via the grafting-from strategy. The self-assembly behavior of the obtained graft copolymers in aqueous media was investigated by fluorescence spectroscopy and TEM. These copolymers were found to be stimuli-responsive to both temperature and ions. Finally, poly(acrylic acid)-g-PPEGMEMA double hydrophilic graft copolymers were obtained by selective acidic hydrolysis of hydrophobic PtBA backbone while PPEGMEMA side chains kept inert. (C) 2011 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 49: 3328-3337, 2011
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