期刊
JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY
卷 47, 期 1, 页码 121-136出版社
WILEY
DOI: 10.1002/pola.23129
关键词
amine; elastomers; films; fluoropolymers; grafting; ionomers; NMR; poly(VDF-co-HFP) copolymer; proton exchange membrane; radical polymerization; telomerization
资金
- European Commission
- CNRS
The synthesis of a novel aromatic sulfonic acid bearing an amino function H,H2NC2H4-S-C2H4-C6H4-SO3Na (1) from the radical addition of mercaptoethylamine hydrochloride onto styrene sodium sulfonate, and its subsequent grafting onto poly(vinylidene fluoride-co-hexafluoropropylene), poly(VDF-co-HFP), copolymer are presented. First, the radical telomerization, carried out under radical conditions and in water, led to various products [monoadduct (1), multiadducts, and polymers], the amounts of which depend on the experimental conditions and [mercaptan](0)/[monomer](0) initial molar ratio (R-0). Am R-0 >= 1 led to the monoadduct (1) only and achieved in similar to 85% yield. The zwitterionic isomer was obtained mainly and its chemical modification was possible to get an original aromatic sodium sulfonate containing an amino end group. A kinetic study of the telomerization was presented for R-0 < 1. Thermogravimetric analysis of the telomer showed that this compound was stable up to 200 degrees C. Second, the grafting of (1) onto poly(VDF-co-HFP) copolymer was also investigated. Such a grafting proceeded as expected by a classic mechanism of grafting of amines. Molar percentages of grafted telomer were assessed by H-1 NMR spectroscopy and by elemental analysis. Ion exchange capacity (IEC) values of the membranes were deduced from the mol % grafted telomer. Scanning electron microscopy pictures showed a good homogeneity in the cross-section of membranes, and energy dispersive X-ray evidenced that all SO3Na groups of the grafted amine were changed into SO3H after treatment with concentrated HCl. Method involving an impedance analyzer, working at increasing high frequencies was used to assess the protonic conductivities, a. These values were lower than that of Nafion117 (R), but a increased with the IEC to 0.4 mS/cm at room temperature and 95% relative humidity. Water and methanol uptakes were also assessed, and it was shown that a increased when water uptakes increased. Membranes started to decompose from 170 degrees C under air. 0 2008 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 47: 121-136, 2009
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