Article
Polymer Science
Yongan Niu, Zenghui Shi, Yingjin Pei, Xinyu Lu, Jianming Feng, Xin Zhang
Summary: In this study, blend polyimide films containing ODA/TPA units were prepared by blending different materials, and complementary advantages of excellent mechanical, thermal, optical, and electrochemical properties were successfully achieved.
JOURNAL OF APPLIED POLYMER SCIENCE
(2022)
Article
Engineering, Chemical
Wei Xie, Yang Jiao, Zhili Cai, Hongyan Liu, Lili Gong, Wei Lai, Linglong Shan, Shuangjiang Luo
Summary: This study developed benzimidazole functionalized polyimides and ionic polyimides with high CO2/CH4 selectivity for natural gas sweetening, demonstrating improved gas separation properties by tightening microporous structures and restricting polymer chain mobility. High performance was observed under high-pressure mixed-gas conditions.
SEPARATION AND PURIFICATION TECHNOLOGY
(2022)
Article
Polymer Science
Shiqing Lai, Yufei Shi, Weilian Wu, Bowen Wei, Chanjuan Liu, Li Zhou, Xiaohua Huang
Summary: A novel fluorinated diamine monomer BASA was designed and synthesized, and a series of polyimides were obtained through high-temperature polycondensation. The polymers exhibited good thermal stability, excellent solubility, optical properties, hydrophobicity, and promising gas transport properties. These polymers could be applied in optics and gas separation.
Article
Chemistry, Physical
Anastasiia E. Soldatova, Regina N. Shamsutdinova, Tatiana Plisko, Katsiaryna S. Burts, Anna Yu Tsegelskaya, Dmitry A. Khanin, Kristina Z. Monakhova, Tikhon S. Kurkin, Alexandr Bildyukevich, Alexander A. Kuznetsov
Summary: A series of aromatic polyimides were synthesized using the one-pot high-temperature catalytic polycondensation method in molten benzoic acid. The properties of these polyimides and the influence of the synthesis method on the crystalline phase formation were investigated. The performance of polyimide PI-DA in membrane separation was compared with the commercially available polyetherimide Ultem 1000(TM).
Article
Polymer Science
Xin-Xin Zhi, Gang-Lan Jiang, Yan Zhang, Yan-Jiang Jia, Lin Wu, Yuan-Cheng An, Jin-Gang Liu, Yan-gai Liu
Summary: By using methyl-substituted benzanilide containing organo-soluble polyimide resins, two colorless and transparent polyimide films with enhanced high-temperature dimensional stability were prepared. The films showed good solution-processability and high optical transparency.
JOURNAL OF APPLIED POLYMER SCIENCE
(2022)
Article
Chemistry, Physical
Sander Smeets, Quan Liu, Jochen Vanderspikken, Tyler James Quill, Sam Gielen, Laurence Lutsen, Koen Vandewal, Wouter Maes
Summary: Traditional synthesis methods and catalysts have limitations for the commercial application of organic solar cells. By using flow chemistry and defect-free synthesis, we have successfully synthesized high-efficiency organic photovoltaic materials with tailorable molar mass.
CHEMISTRY OF MATERIALS
(2023)
Article
Polymer Science
Yunfei Guo, Sebastian Spicher, Anna Cristadoro, Peter Deglmann, Rint P. Sijbesma, Zeljko Tomovic
Summary: Poly(urethane imide)s (PUIs) with improved thermal properties and flame retardancy can be directly synthesized by the reaction of isocyanates with anhydrides to give aromatic imides. Experimental studies and quantum chemical calculations have investigated the mechanism of this reaction in the presence of water. The computational study has provided insights into the underlying mechanism and guided the development of a solvent-free synthetic method for industrial-scale production of PUIs.
Article
Polymer Science
Saskia J. Boardman, Adam S. Hayward, Neil J. Lant, Renae D. Fossum, Paul D. Thornton
Summary: This study focuses on dye transfer inhibitors added to detergents to prevent color transfer during laundry. The results show that these inhibitors can effectively block the deposition of indigo dye on various types of fibers even at low concentrations, offering promising potential for inclusion in laundry detergent formulations.
JOURNAL OF APPLIED POLYMER SCIENCE
(2021)
Article
Polymer Science
Wentao Xu, Huaqiang Zhuang, Wenjie Chen, Wei Liu, Xiaoyang Pan
Summary: By using PAA-catalyzed in-situ COF synthesis method to apply COF-PAA modifier on PVDF membranes, the water flux, rejection rate, and antifouling properties can be improved, with a reduced leaching rate of PAA. The tight bonding of COF to PAA on the membrane surface contributes to enhanced stability and antifouling properties.
JOURNAL OF APPLIED POLYMER SCIENCE
(2022)
Article
Polymer Science
David Meis, Silvio Neumann, Sergey Shishatskiy, Ulrike Meis, Volkan Filiz
Summary: Through molecular modeling and experimental analysis, the structure-property relationship and mechanism of thermally stimulated solid-state reactions of polybenzoxazoles were investigated. The resulting materials exhibited low conversion temperatures, high conversion rates, and excellent hydrogen and propylene separation performance, making them suitable for efficient gas separation.
Article
Materials Science, Composites
Sheida Esmaielzadeh, Hashem Ahmadizadegan
Summary: Novel polyimide/clay nanocomposites were prepared by incorporating organically modified clay into the polyimide matrix. The nanocomposites exhibited good dispersion of clay in the matrix and intercalation between the clay and polyimide macromolecules. The mechanical properties of the nanocomposites were improved, and the gas permeation increased with the increase in organoclay loading.
JOURNAL OF THERMOPLASTIC COMPOSITE MATERIALS
(2023)
Article
Polymer Science
Hashem Ahmadizadegan, Sheida Esmaielzadeh
Summary: Nanocomposite gas transport and thermally stable membranes based on fluorinated polyimide/clay were prepared and characterized using various techniques such as X-ray diffraction, thermal gravimetric analysis, differential scanning calorimetry, scanning electron microscopy, and pure gas permeation testing. The addition of organically modified clay to polyimide improved the thermal stability and mechanical properties of the hybrid films. The layered silicate clay was successfully exfoliated in the polymer matrix, and the gas permeation behavior of the hybrid membrane was influenced by the presence of clay particles. The addition of clay decreased the gas permeation flux but increased the selectivity of the membrane.
Article
Materials Science, Multidisciplinary
Xueshuang Jiang, Yubo Long, Kaijin Chen, Qiaoxi Yu, Long Jiang, Zhenguo Chi, Siwei Liu, Jiarui Xu, Yi Zhang
Summary: Two new bioderived diamines, OAC and OOD, with cis-fused cyclopentane ring structures were synthesized from natural citric acid. Two series of bio-based polyimides, PI(B/F/HAC) and PI(B/F/HOD), were successfully developed by the polymerization of OAC and OOD with three commercial dianhydrides. The resulting polyimides exhibited light color or colorless and transparent properties, as well as interesting optical activities, due to the introduction of optically asymmetric active carbon atoms. In addition, the polyimides showed excellent dimensional stability, mechanical properties, and biodegradability, making them potential solutions to environmental problems caused by polyimides.
JOURNAL OF MATERIALS CHEMISTRY C
(2023)
Article
Engineering, Chemical
Jessica Olvera-Mancilla, Carla Aguilar-Lugo, Lioudmila Fomina, Francisco Manuel Sanchez-Arevalo, Maria Ortencia Gonzalez-Diaz, Rita Sulub-Sulub, Manuel Aguilar-Vega, Larissa Alexandrova
Summary: This study reports the preparation and characterization of a carbon molecular sieve membrane derived from a processable high molecular weight fluorinated polybenzimidazole. The membrane exhibits excellent separation performance for several gas pairs, with significantly improved permeability and selectivity compared to the original polymer. The structure of the membrane was analyzed, revealing the formation of specific molecular units that contribute to its higher permeability values.
INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH
(2022)
Article
Polymer Science
Xiaohua Tong, Shuli Wang, Jiangnan Dai, Shuai Wang, Ke Zhang, Xiaogang Zhao, Daming Wang, Chunhai Chen
Summary: In this study, a series of aromatic polyimides based on Cardo structure were synthesized using different building blocks and commercially available dianhydride. The resulting polyimides exhibited excellent thermal stability and good mechanical properties. Single gas permeation tests revealed that one of the polyimides showed higher permeability without sacrificing selectivity, while another polyimide showed significantly improved CO2 permeability and CO2/CH4 selectivity. These findings provide guidance for the molecular structure design of gas separation membranes.
Article
Nanoscience & Nanotechnology
Changsheng Shan, Kaifeng Wu, Hung-Ju Yen, Claudia Narvaez Villarrubia, Tom Nakotte, Xiangjie Bo, Ming Zhou, Gang Wu, Hsing-Lin Wang
ACS APPLIED MATERIALS & INTERFACES
(2018)
Article
Biochemical Research Methods
Antonietta M. Lillo, Ciana L. Lopez, Trideep Rajale, Hung-Ju Yen, Harsha D. Magurudeniya, M. Lisa Phipps, Eva Rose M. Balog, Timothy C. Sanchez, Srinivas Iyer, Hsing-Lin Wang, Ryszard Michalczyk, Reginaldo C. Rocha, Jennifer S. Martinez
BIOCONJUGATE CHEMISTRY
(2018)
Review
Polymer Science
Hung-Ju Yen, Guey-Sheng Liou
PROGRESS IN POLYMER SCIENCE
(2019)
Article
Nanoscience & Nanotechnology
Kristin B. Labasan, Hong-Jhen Lin, Febri Baskoro, Jazer Jose H. Togonon, Hui Qi Wong, Cha-Wen Chang, Susan D. Arco, Hung-Ju Yen
Summary: Recent studies have investigated aromatic polyimide (PI) derivatives as redox-active electrode materials for Li-ion batteries due to their high thermal stability, excellent solvent resistance, and good electrical properties. Two PI derivatives, TPA-NTCPI and TPA-PMPI, synthesized from a newly developed DiCN-TPA monomer, show promising electrochemical performance with stable specific capacities up to 1000 cycles for the cathode and high specific capacities up to 1600 mAh g(-1) for the anode after 100 cycles. These results suggest that TPA-NTCPI and TPA-PMPI could be potential organic electrode materials for next generation Li-ion batteries.
ACS APPLIED MATERIALS & INTERFACES
(2021)
Article
Energy & Fuels
Febri Baskoro, Hui Qi Wong, Kristin B. Labasan, Chen-Wei Cho, Chun-Wei Pao, Po-Yu Yang, Chien-Cheng Chang, Chih- Chen, Chu-Chen Chueh, Wanyi Nie, Hsinhan Tsai, Hung-Ju Yen
Summary: Metal-organic frameworks (MOFs) are considered as one of the most promising alternative anode materials for lithium-ion batteries. Lead-based MOFs exhibit high efficiency and reversible lithium storage, with excellent electrochemical performance and storage capacity. The DFT simulation reveals efficient absorption of Li atoms by Pb sites in MOFs, supporting high storage capacity and competitive electrochemical performance compared to other reported MOF anode electrodes.
Article
Energy & Fuels
Febri Baskoro, Chin-May Ngue, Kristin B. Labasan, Hui Qi Wong, Man-Kit Leung, Hung-Ju Yen
Summary: A zinc-based MOF with a special dual-ligand system was successfully fabricated and utilized as an anode material for lithium-ion batteries, delivering efficient lithium storage capacity with excellent stability over long-term charge-discharge cycles. The study highlights the potential of dual-ligand Zn-MOFs as next-generation battery anodes due to their tailorable properties and high performance.
Article
Chemistry, Multidisciplinary
Yichen Cai, Jie Shen, Jui-Han Fu, Nadeem Qaiser, Cailing Chen, Chien-Chih Tseng, Mariam Hakami, Zheng Yang, Hung-Ju Yen, Xiaochen Dong, Lain-Jong Li, Yu Han, Vincent Tung
Summary: This study presents the design of a flexible conductive hydrogen-substituted graphdiyne nanofilm for the fabrication of on-skin sensors with high sensitivity and fast response. These sensors can monitor human body movements and health conditions in real-time, providing a new approach for the design of next-generation wearable organic bioelectronics.
Article
Chemistry, Multidisciplinary
Atanu Roy, Theresa Schoetz, Leo W. Gordon, Hung-Ju Yen, Qingli Hao, Daniel Mandler
Summary: Researchers have developed a simple one-step approach to embed a faradaic material (layered double hydroxide - LDH) in electrochemically exfoliated graphite, resulting in high areal capacitance and energy density. The capacitance was attributed to the exfoliation of graphite and deposition of LDH, while the energy density was achieved through the combination of LDH and graphite.
Article
Chemistry, Multidisciplinary
Chin May Ngue, Febri Baskoro, Hui Qi Wong, Hung-Ju Yen, Man-Kit Leung
Summary: In this study, two polymer compounds were successfully synthesized and their redox behavior was investigated using a solid-state electrochemical method. The results showed that both compounds exhibited efficient Li+ storage capability and stability in lithium-ion batteries. Further spectroscopic and electrochemical analyses revealed the important role of the organic moiety in the storage mechanism.
CRYSTAL GROWTH & DESIGN
(2022)
Article
Electrochemistry
Febri Baskoro, Pin-Chieh Chiang, Yao-Chih Lu, Jonathan N. Patricio, Susan D. Arco, Hsieh-Chih Chen, Wen-Shyong Kuo, Long-Li Lai, Hung-Ju Yen
Summary: This study describes the electrochemical performance of a triazine-based dendrimer as a lithium-ion battery anode, and demonstrates that the addition of a small amount of carbon nanotube paper significantly enhances its energy-storing capabilities. The results showed that the specific capacity of the composite anode increased to 656 mA h g(-1) after adding 1% carbon nanotube.
ELECTROCHIMICA ACTA
(2022)
Article
Chemistry, Physical
Febri Baskoro, Hong-Jhen Lin, Cha-Wen Chang, Ching-Lan Wang, Andre Lammiduk Lubis, Hung-Ju Yen
Summary: In this study, three new aramid-containing dicyanotriphenylamine skeletons were reported as anode materials for organic lithium-ion batteries. The aramid anodes exhibited high specific capacity, superior rate performance, excellent coulombic efficiency, and capacity retention after 1000 cycles. Mechanistic studies revealed that the outstanding electrochemical performance of aramids as battery anode materials are highly related to their physical and chemical properties.
JOURNAL OF MATERIALS CHEMISTRY A
(2023)
Article
Chemistry, Multidisciplinary
Hui Qi Wong, Hung-Ju Yen
Summary: Fluorescent high-performance polymers are widely used in the design of optoelectronic devices due to their low cost, excellent thermal stability, high mechanical strength, low flammability, good chemical and radiation resistance, and good electronic properties. However, conventional organic luminophores suffer from aggregation-caused quenching, limiting their application as solid light-emitting materials. The aim of this study was to develop new high-performance polymers with high photoluminescent efficiency, good processability, and film-forming properties for potential optoelectronic applications.
JOURNAL OF THE CHINESE CHEMICAL SOCIETY
(2023)
Article
Chemistry, Physical
Febri Baskoro, Andre Lammiduk Lubis, Hui Qi Wong, Guey-Sheng Liou, Hung-Ju Yen
Summary: Multifunctional energy-storage devices have great potential in reducing size and volume, improving storage capacity, and decreasing material and fabrication costs. This research presents three new triphenylamine-based polynaphthalimides (TPA-PNIs) that can serve as cathodes, anodes, and binders in lithium-ion batteries simultaneously. These TPA-PNI electrodes demonstrate high specific capacity, stable cycling performance, and excellent rate capability, making them among the best polymer-based electrodes reported. Detailed mechanistic studies and structural design of these ambipolar TPA-PNI electrodes could provide valuable insights and pave the way for the development of high-performance multifunctional energy-storage systems.
JOURNAL OF MATERIALS CHEMISTRY A
(2023)
Article
Materials Science, Multidisciplinary
Jazer Jose H. Togonon, Pin-Chieh Chiang, Hong-Jhen Lin, Wei-Che Tsai, Hung-Ju Yen
Summary: This review focuses on the application and control mechanisms of carbon-based electrode materials in different metal-ion batteries, summarizes the latest developments and electrochemical performance, and considers the critical challenges and prospects for future use.
Review
Chemistry, Physical
Febri Baskoro, Hui Qi Wong, Hung-Ju Yen
ACS APPLIED ENERGY MATERIALS
(2019)