4.4 Article

Optical, thermophysical and electrical characterization of PMMA (CdSe QDs) composite films

期刊

JOURNAL OF POLYMER RESEARCH
卷 20, 期 2, 页码 -

出版社

SPRINGER
DOI: 10.1007/s10965-013-0076-x

关键词

CdSe QDs; PMMA; Composite; Optical and thermal properties; Photoacoustic technique; dc electrical conductivity

资金

  1. Taif University [1/432/432]

向作者/读者索取更多资源

The concentration dependence of optical, thermophysical and electrical behavior, based on poly-methyl methacrylate filled with CdSe quantum dots (PMMA (CdSe)) have been investigated. The PMMA(CdSe) concentration was 0.001, 0.005, 0.01 and 0.05 wt.%. The composites were prepared in the form of films by the solution casting technique. The optical properties of PMMA(CdSe) films have showed that, there is a red shift of the absorption and photoluminescence (PL) after the QDs were added into PMMA. The PL peak intensity of the composite was enhanced by approximate to 2.5 times compared to the CdSe QDs. The thermal conductivity (k) was obtained by measuring the thermal diffusivity (alpha) and thermal effusivity (e) using the photoacoustic (PA) technique. The composites exhibit approximate to 120 % improvement in k at 0.05 wt.%. Furthermore, the dc electrical conductivity measurements of pure and doped PMMA, showed that the obtained values were enhanced about four orders of magnitude for the highest concentration compared with pure PMMA at 500 degrees C.

作者

我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。

评论

主要评分

4.4
评分不足

次要评分

新颖性
-
重要性
-
科学严谨性
-
评价这篇论文

推荐

Article Materials Science, Multidisciplinary

Impact of preparation temperature on the structure, optical and electronic characteristics of Zn0.9V0.1S nanoparticles with Williamson-Hall model mechanistic view

Zein K. Heiba, Mohamed Bakr Mohamed, Ali Badawi

Summary: This work investigates the impact of preparation temperature on the structural, optical, and electronic characteristics of vanadium doped ZnS nanoparticles. The results show that the parameters related to lattice defects, such as lattice size and microstrain, change with increasing temperature. The optical properties exhibit a decrease in the optical band gap energy and a blue shift in emitted colors with temperature. The electronic characteristics show that ZnS is a semiconductor, while doped samples exhibit half metallic or metallic characteristics.

APPLIED PHYSICS A-MATERIALS SCIENCE & PROCESSING (2022)

Article Multidisciplinary Sciences

Exploring the functional properties of PVP/PVA blend incorporated with non-stoichiometric SnS for optoelectronic devices

Sami S. Alharthi, M. G. Althobaiti, Ali A. Alkathiri, Essam E. Ali, Ali Badawi

Summary: The functional properties of PVP/PVA blend incorporated with non-stoichiometric SnS have been explored, showing improved structure, optical properties, and emission spectra in the visible region.

JOURNAL OF TAIBAH UNIVERSITY FOR SCIENCE (2022)

Article Physics, Multidisciplinary

Structure, half-metallic and magnetic properties of bulk and (001) surface of Rb2XMoO6 (X = Cr, Sc) double perovskites: a DFT plus U study

Abdelazim M. Mebed, Muhammad Mushtaq, Iltaf Muhammad, Ikram Un Nabi Lone, Samah AL-Qaisi, Norah Algethami, E. F. EL-Shamy, Amel Laref, N. M. AL-Hosiny

Summary: In this study, the geometric features, electronic structure, and magnetism of two new double perovskites were investigated. The results showed stable magnetic and half-metallic properties for these materials, with potential applications in spintronics.

PHYSICA SCRIPTA (2023)

Article Materials Science, Multidisciplinary

Enhancement the optical and electrical performance of PVA/MWCNTs blend via Cu/ZnS nanoparticles doping for flexible eco-friendly applications

Ali Badawi, Sami S. Alharthi

Summary: This study aims to enhance the optical and electrical performance of PVA/MWCNTs blend by doping with Cu/ZnS nanoparticles, for flexible eco-friendly applications. Undoped and Cu/ZnS doped MWCNTs/PVA polymeric nanocomposite films were fabricated. The structure and optical characteristics were analyzed using FT-IR and UV-visible-NIR spectrophotometry. The electrical properties were studied as a function of temperature. The results show that doping with Cu/ZnS improves the optical and electrical properties of MWCNTs/PVA blend.

APPLIED PHYSICS A-MATERIALS SCIENCE & PROCESSING (2023)

Article Materials Science, Multidisciplinary

Tailoring the structural and optical characteristics of hematite (α-Fe2O3) nanostructures by barium/aluminum dual doping for eco-friendly applications

Ali Badawi, Sami S. Alharthi, Abdullah A. Alotaibi, M. G. Althobaiti

Summary: In this study, the structural and optical characteristics of hematite were modified by doping Ba and Al for photocatalytic and eco-friendly applications. The doped and undoped hematite nanostructures were synthesized onto quartz substrates. Surface morphology, vibrational bands, and structural properties were examined using FE-SEM, FT-IR, and XRD measurements. The doped hematite samples showed improved crystallite size, optical absorption, and refractive index compared to the undoped sample. These results suggest that Ba, Al, and Ba/Al dual doped hematite nanoparticles have potential applications in photocatalysis and eco-friendly devices.

APPLIED PHYSICS A-MATERIALS SCIENCE & PROCESSING (2023)

Article Engineering, Electrical & Electronic

Facile synthesis of Cu0.9Co0.1-xSnxO nanostructures and their structural, optical and dielectric properties for optoelectronic applications

M. G. Althobaiti, Abdullah A. Alotaibi, Sami S. Alharthi, Ali Badawi

Summary: The structural, linear/nonlinear optical and dielectric properties of Cu0.9Co0.1-xSnxO (CCTO) nanostructured films were investigated. Different compositions of CCTO films were prepared by spray pyrolysis. The films exhibited variations in structure, crystallography, and morphology. The UV-Vis. NIR measurements revealed that the films had high absorption coefficients and energy band gaps ranging from 1.24 to 1.14 eV. The linear optical properties of CCTO were influenced by the composition. The study suggests that CCTO nanostructured films have potential applications in photocatalysis, solar cells, optoelectronics, and ultra-fast optical switching devices.

JOURNAL OF MATERIALS SCIENCE-MATERIALS IN ELECTRONICS (2023)

Article Polymer Science

Modification of the Structure and Linear/Nonlinear Optical Characteristics of PVA/Chitosan Blend through CuO Doping for Eco-Friendly Applications

Sami S. Alharthi, Ali Badawi

Summary: The solution casting technique was used to prepare blank and CuO-doped polyvinyl alcohol/chitosan (PVA/CS) blends for eco-friendly applications. The structure and surface morphologies of the samples were characterized by Fourier transform infrared (FT-IR) spectrophotometry and scanning electron microscopy (SEM), respectively. FT-IR analysis confirmed the incorporation of CuO particles in the PVA/CS structure, while SEM analysis showed a well-dispersed distribution of CuO particles. The optical properties of the CuO-doped PVA/CS films were improved, as indicated by the decrease in transmittance and optical bandgap.

POLYMERS (2023)

Article Materials Science, Multidisciplinary

A promising alternative: examining TVS tellurite glass for gamma radiation shielding applications

M. A. M. Uosif, Shams A. M. Issa, Antoaneta Ene, A. M. A. Mostafa, Ali Atta, Ali Badawi, E. F. El Agammy, Hesham M. H. Zakaly

Summary: The TVS5 sample in the 65TeO(2)-(35-x)V2O5-xSm(2)O(3) glass composition was found to have the highest G(MAC) and lowest G(HVL) and G(MFP), suggesting its potential use in radiation shielding activities to enhance nuclear safety.

FRONTIERS IN MATERIALS (2023)

Article Materials Science, Multidisciplinary

Role of substitution of sulfur atoms by oxygen atoms on optical characteristics of lead sulfide semiconductor

Zein K. Heiba, Ahmed R. Wassel, Hassan Elshimy, Essam E. Ali, Ali Badawi, Mohamed Bakr Mohamed

Summary: PbS1-xOx (x = 0, 0.05, 0.1, 0.15, 0.2) samples were prepared via the solid-state reaction method and analyzed using various techniques such as Rietveld refinement, energy-dispersive X-ray spectroscopy (EDS), field emission scanning electron microscopy (FESEM), Fourier-transform infrared spectroscopy (FTIR), UV diffused reflectance technique, and photoluminescence measurements. The results showed that the diffusion of oxygen ions at Wyckoff position 4b increased and sulfur decreased in the PbS1-xOx samples. The effect of sulfur deficiency on the optical parameters and the origin of different emitted colors were also investigated.

APPLIED PHYSICS A-MATERIALS SCIENCE & PROCESSING (2023)

Article Polymer Science

Role of Cu/ZnO Nanostructures Doping on the Optical Behavior of Polyvinyl Alcohol/Polyvinyl Pyrrolidone/Graphene Composites for Optoelectronic Applications

M. G. Althobaiti, Ali Badawi

Summary: Cu/ZnO (ZCO) nanoparticles (NPs) were doped into PVA/PVP/graphene composites to enhance their linear/non-linear optical and dielectric performance for optoelectronic applications. The synthesized ZCO NPs and ZCO PNCs showed a wurtzite structure, with ZCO NPs integrating with the host blend's structure. Optical analysis revealed a decrease in the band gap and an increase in refractive index, as well as a significant enhancement in non-linear optical constants through ZCO doping. These achievements make PVA/PVP/graphene blend by ZCO doping a promising candidate for improving optical devices.

JOURNAL OF MACROMOLECULAR SCIENCE PART B-PHYSICS (2023)

Correction Engineering, Electrical & Electronic

Influence of composition ratio on structural, optical and magnetic properties of NiFe2O4/(1 - x)MnO - xCoO composites (vol 33, pg 23555, 2022)

Zein K. Heiba, Mohamed Bakr Mohamed, Ah. Abd Ellatief, A. M. El-naggar, Ali Badawi

JOURNAL OF MATERIALS SCIENCE-MATERIALS IN ELECTRONICS (2023)

Article Materials Science, Ceramics

Investigation of the structural and linear/nonlinear optical characteristics of ZnO nanostructures alloyed with Co3O4 and NiO

Zein K. Heiba, Mohamed Bakr Mohamed, M. Abdellatief, Hassan Elshimy, Essam E. Ali, Ali Badawi

Summary: ZnO/(1-x)Co3O4/xNiO/(x = 0.0, 0.3, 0.5, 0.7, 0.9 and 1) samples were prepared using co-precipitation method. Rietveld analysis, XPS and FTIR techniques were used to investigate the phases, structures, microstructures, and ion exchanges in the system. TEM microscopy showed homogeneous spherical particles with nano size. Diffuse reflectance measurements revealed high absorbance in the visible region for samples with x = 0, 0.7, and 1.0, which could be used in coating eyeglasses to protect the skin around the eyes. The optical band gap and refractive index behaviors were influenced by the oxide composition, and the effect of alloying on optical parameters was explored.

JOURNAL OF SOL-GEL SCIENCE AND TECHNOLOGY (2023)

Article Chemistry, Applied

Effect of Ag/CuS nanoparticles loading to enhance linear/nonlinear spectroscopic and electrical characteristics of PVP/PVA blends for flexible optoelectronics

Sami S. Alharthi, Ali Badawi

Summary: With the unique physicochemical properties, polymeric nanocomposites (PNCs) have played a remarkable role in flexible optoelectronic applications. By using a solution casting procedure, Ag1.6Cu0.2S (ACS) nanoparticles were successfully incorporated into PVP/PVA blend. The influence of ACS on the structure and morphology of PVP/PVA was investigated, and it was found that ACS doping led to enhancements in the optical properties and nonlinear effects of PVP/PVA. The electrical performance of ACS PNCs was also greatly enhanced. These findings demonstrate that ACS PNCs can be efficiently used in various optoelectronic applications.

JOURNAL OF VINYL & ADDITIVE TECHNOLOGY (2023)

Article Materials Science, Multidisciplinary

Sonochemical synthesis of Ag2CO3/CeO2 p-n heterojunction for decomposition of rhodamine B dye

Zein K. Heiba, M. A. Ahmed, M. Hassan, Ali Badawi, A. M. El-naggar, Mohamed Bakr Mohamed

Summary: In this study, an effective Ag2CO3/CeO2 p-n junction was developed for the photocatalytic reduction of a model cationic pollutant, rhodamine B dye. The Ag2CO3/CeO2 heterojunction was formed through sol-gel and sonochemical routes, with silver carbonate successfully distributed on localized active sites. The physicochemical features of the solid specimen were analyzed through various experimental methods. The results showed that the p-n junction exhibited enhanced photocatalytic activity for the decomposition of the dye compared to pristine CeO2 nanoparticles.

OPTICAL MATERIALS (2023)

Article Materials Science, Multidisciplinary

The influence of La/Mg co-doping on the structure, linear and nonlinear optical properties of Fe2O3 nanoparticles for environmentally friendly applications

Ali Badawi, M. G. Althobaiti, Abdullah A. Alotaibi, Essam E. Ali, Sami S. Alharthi

Summary: The structure and optical properties of Fe2O3 nanoparticles films were studied for environmentally friendly applications. The effects of La/Mg co-doping on the properties were explored. The ability to tailor the linear/nonlinear optical properties of the films makes them promising for various environmentally friendly applications.

OPTICAL MATERIALS (2023)

暂无数据