期刊
JOURNAL OF POLYMER RESEARCH
卷 18, 期 5, 页码 1119-1124出版社
SPRINGER
DOI: 10.1007/s10965-010-9514-1
关键词
Polyhedral oligomeric silsesquioxanes(POSS); Vinyl acetate(VAc); Emulsion polymerization; Thermal properties
资金
- National Nature Science Foundation of China [50673023]
A novel material containing polyhedral oligomeric silsesquioxane (POSS) was prepared by semi-continuous emulsion polymerization. Incompletely condensed, phenyl POSS (Na3O12Si7(C6H5)(7)) with the highly reactive group of trisodium silanolate was used to prepare 1, 3, 5, 7, 9, 11, 13-heptaphenyl-15-vinyl silsesquioxane (vinyl-POSS) by corner-capping method. Then this cubic structure molecule was chemically bonded with PVAc chain to synthesize POSS/PVAc composite. The structures of POSS and composite were characterized by FTIR, H-1-NMR and XRD. The results confirmed that vinyl-POSS could be successfully incorporated into the PVAc matrix via emulsion polymerization. Transmission electron microscope (TEM) was used to observe the morphology of copolymers. The thermal properties were investigated by differential scanning calorimetry and thermal gravimetric analysis. Data indicated that the POSS/PVAc composite displayed higher thermal stability than that of the parent PVAc homopolymer.
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