期刊
JOURNAL OF PHYSICS D-APPLIED PHYSICS
卷 47, 期 40, 页码 -出版社
IOP PUBLISHING LTD
DOI: 10.1088/0022-3727/47/40/405103
关键词
carbon nanotube-polymer composite; electrical conductivity; micromechanics modelling; stretching
资金
- Ontario Ministry of Research Innovation
- LANXESS Inc.
A theoretical study is carried out to investigate the effects of uniaxial stretching on the electrical conductivity of carbon nanotube (CNT)-polymer composites using a mixed micromechanics model, which incorporates two conductivity mechanisms: electron hopping and conductive networks. The uniaxial stretching induces volume expansion of the composites, re- orientation of CNTs and a change in conductive networks, which are characterized by the variation of the CNT concentration, the CNT orientation distribution function and the percolation threshold, respectively. Modelling results demonstrate that stretching decreases the electrical conductivity of the composite in both the longitudinal and transverse directions. It is also observed that stretching has more significant effects on the electrical conductivity of the composites with a lower CNT volume fraction. Furthermore, the effects of Poisson's ratio on the electrical conductivity are also investigated. Possible reasons for the observed phenomena are interpreted. This work can be claimed to provide a theoretical prediction on the trend of the stretching effects on the electrical properties of CNT- polymer composites.
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