期刊
JOURNAL OF PHYSICAL CHEMISTRY LETTERS
卷 5, 期 20, 页码 3486-3491出版社
AMER CHEMICAL SOC
DOI: 10.1021/jz5018202
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类别
资金
- NRCan through their EcoEII program
- NSERC
- Joint Center for Energy Storage Research, an Energy Innovation Hub - U.S. Department of Energy, Office of Science, Basic Energy Sciences
A comprehensive and general kinetic model is developed for the oxygen reduction reaction in aprotic Li-O-2 cells. The model is based on the competitive uptake of lithium superoxide by the surface and solution. A demonstrative kinetic study is provided to demystify the origin of curvature in Tafel plots as well as the current dependency and aberrant diversity of the nature and morphology of discharge products in these systems. Our results are general and extend to any system where solubilization of superoxide is favored, such as where phase-transfer catalysts play an important role.
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