4.8 Article

Multiferroic and Magnetoelectric Oxides: The Emerging Scenario

向作者/读者索取更多资源

Multiferroics were considered to be rare because magnetism and ferroelectricity require entirely different criteria for the materials. Several multiferroic oxides have, however, been discovered in the past few years by virtue of novel operating mechanisms, the most effective one being ferroelectricity driven by magnetism itself Many such oxides where the magnetic and electric order parameters interact also exhibit magneto electric or magnetodielectric properties. In this Perspective, properties of manganites, ferrites, and other monophasic multiferroic oxides with spin induced electric polarization are described. Multiferroic properties arising from charge ordering are examined. The present status of BiMnO3, which is an unusual example of a ferromagnetic-ferroelectric, is presented. Recent findings suggest that it is likely that many more multiferroic and magnetoelectric oxide materials exhibiting magnetically induced ferroelectricity will be found in the future.

作者

我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。

评论

主要评分

4.8
评分不足

次要评分

新颖性
-
重要性
-
科学严谨性
-
评价这篇论文

推荐

Article Multidisciplinary Sciences

Observation of Neel-type skyrmions in acentric self-intercalated Cr1+δTe2

Rana Saha, Holger L. Meyerheim, Boerge Goebel, Binoy Krishna Hazra, Hakan Deniz, Katayoon Mohseni, Victor Antonov, Arthur Ernst, Dmitry Knyazev, Amilcar Bedoya-Pinto, Ingrid Mertig, Stuart S. P. Parkin

Summary: This study reveals that the self-intercalation of e(2)Cr atoms in CrTe2 can cause an asymmetry in the number of intercalated atoms in the van der Waals gaps between the layers, leading to the formation of non-collinear spin-textures and Neel-type magnetic skyrmions.

NATURE COMMUNICATIONS (2022)

Article Chemistry, Inorganic & Nuclear

Elucidating Structure-Property Correlation in Perovskitoid and Antiperovskite Piperidinium Manganese Chloride

Debendra Prasad Panda, Diptikanta Swain, Rohit Kumar Rohj, D. D. Sarma, A. Sundaresan

Summary: Organic-inorganic hybrid (OIH) halide perovskite is a promising material in the field of semiconductors, and efforts have been made to design new lead-free OIH halides for optoelectronic applications. We have synthesized a perovskitoid compound and an antiperovskite compound with unique structures and properties. The perovskitoid compound displays switchable dielectric property, while the antiperovskite compound exhibits higher photoluminescence quantum yield and magnetic properties. This structure-property relationship in OIH manganese halides will contribute to the design of new perovskites and antiperovskites.

INORGANIC CHEMISTRY (2023)

Article Chemistry, Physical

Halogen Bond Induced Structural and Photophysical Properties Modification in Organic-Inorganic Hybrid Manganese Halides

Debendra Prasad Panda, Diptikanta Swain, Sounak Sarkar, A. Sundaresan

Summary: In this study, two organic-inorganic hybrid halides were synthesized and the role of halogen bonding was revealed. The first compound showed a unique type-II halogen bonding between organic and inorganic ions, leading to structural changes and modulation of photophysical properties. The second compound demonstrated dual-band emission, possibly due to energy transfer from the organic amine to Mn centers. The role of halogen bonding was explored through quantitative electron density analysis and intermolecular interaction energies.

JOURNAL OF PHYSICAL CHEMISTRY LETTERS (2023)

Article Chemistry, Inorganic & Nuclear

Role of dipole relaxation in measuring electric polarization in type-II multiferroics

Rahul Kumar, A. Sundaresan

Summary: Type-II multiferroics often have lower polarization values than Type-I multiferroics, which requires the use of pyrocurrent measurements. However, this method becomes inadequate when faster dipole relaxation and thermally stimulated free charge carriers overshadow the magnitude of the pyrocurrent. This study demonstrates the effectiveness of the DC bias current technique in overcoming this limitation and characterizing type-II multiferroic materials with small polarization.

ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE (2023)

Article Nanoscience & Nanotechnology

Impact of organic amine cations on photoluminescence and magnetic properties in Dion-Jacobson hybrid manganese halide perovskites

Debendra Prasad Panda, Diptikanta Swain, Sundaresan Athinarayanan

Summary: Efforts have been made to design multifunctional lead-free organic-inorganic hybrid (OIH) halide compounds, which are considered as next-generation solar cell materials. However, it is challenging to design OIH halides that exhibit both long-range magnetic ordering and high photoluminescence quantum yield (PLQY) due to the contrasting effect of the compounds' dimensionality. In this study, we demonstrated an approach to enhance PLQY in two-dimensional (2D) Heisenberg antiferromagnets by increasing the alkylene chain length of [H3N-(CH2)(m)-NH3]MnCl4 compounds. These compounds showed long-range antiferromagnetic ordering and an increase in PLQY with increasing spacer cation length. The findings provide insight into the design of new OIH halides with desirable magnetic ordering and PLQY.

APL MATERIALS (2023)

Article Materials Science, Multidisciplinary

Canonical spin glass and cluster glass behavior in the polymorphs of LiFeSnO4

Souvik Banerjee, Debendra Prasad Panda, Premakumar Yanda, A. Sundaresan

Summary: We conducted a comprehensive and comparative study on the structural, static, dynamic, and nonequilibrium magnetic properties of the polymorphs of LiFeSnO4. It was found that LiFeSnO4 exhibits two polymorphs, an orthorhombic phase (HT) and a hexagonal phase (LT), which differ in their crystal structures and magnetic properties. Both polymorphs show spin glass behavior and the presence of an exchange bias effect due to magnetic inhomogeneity.

PHYSICAL REVIEW MATERIALS (2023)

Article Chemistry, Inorganic & Nuclear

Fixing CO2 under Atmospheric Conditions and Dual Functional Heterogeneous Catalysis Employing Cu MOFs: Polymorphism, Single-Crystal-to-Single-Crystal (SCSC) Transformation and Magnetic Studies

Krishna Manna, Rahul Kumar, Athinarayanan Sundaresan, Srinivasan Natarajan

Summary: New Cu MOFs show polymorphism and have the ability to fix CO2 to cyclic carbonates. They also exhibit Lewis acid catalysis, Lewis base catalysis, and interesting magnetic behavior. The compounds were prepared using different ligands and different reaction conditions, resulting in various structure dimensionalities. The Cu center in the compounds was explored for different catalytic reactions, showing good yields and recyclability. Magnetic studies revealed antiferromagnetic or ferromagnetic interactions in different compounds. This research demonstrates the diversity of copper-containing compounds in extended framework structures.

INORGANIC CHEMISTRY (2023)

Article Chemistry, Physical

Photophysical Properties of S=5/2 Zigzag-1D (2-Bromoethylammonium)3MnBr5 Antiferromagnet

Debendra Prasad Panda, Diptikanta Swain, Rajamani Raghunathan, A. Sundaresan

Summary: In this study, a newly synthesized lead-free organic-inorganic hybrid compound with one-dimensional chain structure is investigated. The compound exhibits interesting magnetic and photoluminescence properties, including long-range antiferromagnetic ordering and low-dimensional magnetic susceptibility hump. Additionally, the compound displays orange-red emission and shows evidence of electron-phonon coupling.

JOURNAL OF PHYSICAL CHEMISTRY LETTERS (2023)

Article Physics, Multidisciplinary

Bipartite entanglement via distance between the states in a one dimensional spin 1/2 dimer copper acetate monohydrate

S. Athira, Saulo L. L. Silva, Probal Nag, Sushma Lakshmi, C. Sharath Kumar, Debendra Prasad Panda, Sayan Das, Sarita Rajput, Andrews P. Alex, A. Sundaresan, Sivaranjana Reddy Vennapusa, T. Maitra, D. Jaiswal-Nagar

Summary: In this paper, the authors used the distance between the states as a theoretical measure to determine the bipartite entanglement in a one-dimensional magnetic dimer system. The calculation was compared with the concurrence, a well-known entanglement measure, and found to be the same. Experimental verification was done on single crystals of copper acetate, showing the existence of bipartite entanglement even at room temperature. Characterization and calculations revealed the weak intermolecular interactions and low probability of direct Cu-Cu exchange in copper acetate.

NEW JOURNAL OF PHYSICS (2023)

Article Materials Science, Multidisciplinary

Unconventional multiferroicity induced by structural distortion and magnetostriction effect in the layered spin-1/2 ferrimagnet Bi2Cu5B4O14

Arkadeb Pal, T. W. Yen, T. W. Kuo, C. W. Wang, S. M. Huang, M. C. Chou, Y. C. Lai, Y. C. Chuang, P. Yanda, A. Sundaresan, H. S. Kunwar, V. G. Sathe, Ajay Tiwari, D. Chandrasekhar Kakarla, H. D. Yang

Summary: We report the unconventional and interesting multiferroic behavior of a layered noncentrosymmetric ferrimagnetic spin-1/2 system Bi2Cu5B4O14. Neutron powder-diffraction study reveals a robust ferrimagnetic (up arrow down arrow down arrow down arrow down arrow) ordering below TC = 25 K, which remains unaffected even under a high magnetic field of H = 10 T. Interestingly, two successive ferroelectric transitions are observed, one triggered by the magnetostriction effect at TC = TE2 = 25 K and another caused by a structural distortion at TE1 = 32 K.

PHYSICAL REVIEW B (2023)

Article Materials Science, Multidisciplinary

Unveiling a hidden multiferroic state under magnetic fields in BaHoFeO4

Rahul Kumar, A. Sundaresan

Summary: In this paper, the field-induced ferroelectricity in BaHoFeO4 within a narrow range of applied magnetic fields (1.5 T H 5 T) is reported. Magnetization measurements reveal magnetic anomalies at TFe ordering of Fe3+, a possible spin structure change of Fe3+, and the antiferromagnetic ordering of Ho3+ sublattices. Heat capacity data did not show any anomaly at TNFe, but exhibited a broad N . Isothermal magnetization measurements indicate a metamagnetic transition at 1.5 T below 40 K. Temperature-dependent dielectric measurements below 1 T reveal two anomalies corresponding to Ho3+ ordering and a possible change in the magnetic phase of the Fe sublattice. These anomalies disappear at higher magnetic fields, and a different dielectric anomaly appears above the metamagnetic transition. A switchable electric polarization appears below 25 K and above the metamagnetic transition field (H 1.5 T), but disappears above 5 T.

PHYSICAL REVIEW B (2023)

Article Materials Science, Multidisciplinary

Sc1-xErxAlO3 perovskites: high-pressure synthesis, photoluminescence properties, and in vitro bioimaging

Debendra Prasad Panda, Akash Kumar Singh, Tapas K. Kundu, A. Sundaresan

Summary: This article introduces the synthesis of Sc1-xErxAlO3 perovskite phosphors using high-pressure method, which have high thermal photostability and low cytotoxicity in optical imaging. The biocompatibility and potential biomedical application of these phosphors in HEK293 cells are demonstrated.

JOURNAL OF MATERIALS CHEMISTRY C (2022)

Correction Materials Science, Multidisciplinary

Magnetic-field-induced ferroelectric states in centrosymmetric R2BaCuO5 (R = Dy and Ho) (vol 104, 144401, 2021)

Premakumar Yanda, F. Orlandi, P. Manuel, N. Boudjada, J. Rodriguez-Carvajal, A. Sundaresan

PHYSICAL REVIEW B (2022)

Article Materials Science, Multidisciplinary

Effects of Ga doping on the phase transitions of V2O3

Pavitra N. Shanbhag, Anjana Joseph, Fabio Orlandi, Pascal Manuel, R. Mahendiran, Francois Fauth, Chandrabhas Narayana, A. Sundaresan, C. N. R. Rao

Summary: A comprehensive study on gallium-doped polycrystalline V2O3 reveals interesting features of the structural, magnetic, and electronic phase transitions, including the enhancement of the Néel temperature by gallium doping and the decoupling of the structural transition from the magnetic and insulator-insulator transition.

PHYSICAL REVIEW B (2022)

Article Materials Science, Multidisciplinary

Experimental and first-principles studies on superconductivity in noncentrosymmetric La3Se4

Moumita Naskar, Soumen Ash, Debendra Prasad Panda, Chandan Kumar Vishwakarma, Brajesh Kumar Mani, A. Sundaresan, Ashok Kumar Ganguli

Summary: We report the synthesis and detailed characterization of superconducting La3Se4, and found that it has a high critical temperature and strong-coupling superconductivity. By experimental measurements and theoretical simulations, the superconducting parameters of La3Se4 were determined, and band crossings and band splitting near the Fermi energy due to spin-orbit coupling were observed.

PHYSICAL REVIEW B (2022)

暂无数据