期刊
JOURNAL OF PHYSICAL CHEMISTRY C
卷 118, 期 51, 页码 30145-30152出版社
AMER CHEMICAL SOC
DOI: 10.1021/jp507991e
关键词
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资金
- UGC [SEG_CUHK06]
- National Basic Research Program of China [2012CB933101]
Employing an electron energy-loss spectrum (EELS), we have found that the structure of ZnFe2O4 nanotubes deviated from the normal spinel structure as the calcination temperature decreases. More Fe3+ ions migrate to the tetrahedral sites (A sites) rather than staying in their equilibrium octahedral sites (B sites). This results in the enhanced superexchange interactions between Fe3+ ions, thus affecting the magnetic properties of the nanotubes, i.e., higher blocking temperature (T-B) and larger saturation magnetization (M-S), etc. On the other hand, we have also found that deviation of the Fe/Zn from 2 affects the magnetic properties of the nanotube samples. This should be caused by the enhanced superexchange interactions resulting from the extra Fe3+ ions in the nonstoichiometric sample.
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