4.6 Article

Optical and Magnetic Properties of Zn1-xMnxO Nanorods Grown by Chemical Vapor Deposition

期刊

JOURNAL OF PHYSICAL CHEMISTRY C
卷 117, 期 12, 页码 6443-6453

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AMER CHEMICAL SOC
DOI: 10.1021/jp312080v

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资金

  1. Converging Research Center Program
  2. Ministry of Education, Science and Technology [2012K001431]

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We prepared successfully Zn1-xMnxO nanorods (x = 0, 0.008, 0.013, and 0.020) by using chemical vapor deposition. Their crystal structural and optical and magnetic properties at room temperature were then investigated in detail. Experimental results have revealed that all the samples have a single phase with the wurtzite structure, and the lattice parameters slightly increase with increasing Mn-doping content. This is ascribed to an incorporation of Mn2+ into the Zn site of the ZnO host lattice. The Mn incorporation also creates more lattice defects and disorders, which influence directly characteristic photoluminescence (PL) and Raman scattering (RS) spectra of Zn1-xMnxO nanorods. For example, there are the blue shift of ultraviolet emission and the rapid decline of visible PL emission when Mn-doping content (x) in Zn1-xMnxO increases. Besides conventional phonon-vibration modes, there are additional ones associated with defects and Mn impurities. The origin and nature of these additional modes is identified and assessed carefully. Interestingly, under the resonant-RS condition we have recorded the overtones/replicas of the longitudinal-optical phonon up to the seventh order. Magnetic measurements have been also performed, which reveal Zn1-xMnxO nanorods with x = 0.013 and 0.020 exhibiting the room-temperature ferromagnetic order. We believe that the ferromagnetic nature is related to both Mn2+ ions and intrinsic defects of zinc vacancies, rather than Mn-related secondary phases.

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