Article
Chemistry, Multidisciplinary
Zhanyou Ji, Bingyan Zhai, Nana Wang, Yinkun He, Huidi Wang, Guiqiang Fei, Caiyun Wang, Guohong Zhang, Liang Shao
Summary: Through the utilization of camphorsulfonic acid as the dopant, nanofeatured polyaniline (PANI) electrodes can be directly deposited on substrates without the need for dedoping. Five different nanofeatures have been successfully transferred onto indium tin oxide substrate by utilizing a formic acid/acetonitrile system, demonstrating a morphology memory effect. The method is also applicable for PANI/gold nanorod composites (PANI-CSA/AuNRs), which exhibit excellent sensing performance as an ascorbic acid sensor.
Article
Engineering, Chemical
Min Kaung Htet Ko Ko, Swee Pin Yeap, Ayu Haslija Abu Bakar
Summary: This study investigated the interfacial interactions between reduced graphene oxide (rGO), polyaniline (PANI), and their composites. The results showed that the interfacial interaction between 0-D PANI and rGO was the strongest, resulting in the highest electrical conductivity.
JOURNAL OF THE TAIWAN INSTITUTE OF CHEMICAL ENGINEERS
(2023)
Article
Polymer Science
Araceli Flores, Susana Quiles-Diaz, Patricia Enrique-Jimenez, Aranzazu Martinez-Gomez, Marian A. Gomez-Fatou, Horacio J. Salavagione
Summary: PEEK, as a promising candidate to replace epoxy resins in high-performance aeronautical applications, undergoes property optimization, including the interaction between fibers and the matrix. Incorporating modified graphene into the polymer layer results in a significant modulus improvement for the PEEK layer. Additionally, anisotropic electrical conductivity and high modulus values near the carbon fiber front are observed in the laminates.
Article
Chemistry, Multidisciplinary
Sheeraz Mehboob, Ju-Young Lee, Jee Hun Ahn, Saleem Abbas, Xuan Huy Do, Jaewon Kim, Hyun-Jin Shin, Dirk Henkensmeier, Heung Yong Ha
Summary: In this study, multi-layered PANI-Nafion composite membranes with low vanadium ion permeability were successfully fabricated, which greatly improved the performance of VRFBs and preserved electric capacity almost perfectly. The fabricated membrane showed a high coulombic efficiency of 99% and an energy efficiency of 91% at 50 mA cm-2, outperforming the pristine Nafion 115 membrane. Moreover, it exhibited remarkable durability and capacity retention with a 100% discharge capacity retention over 100 cycles of charge/discharge operation.
JOURNAL OF INDUSTRIAL AND ENGINEERING CHEMISTRY
(2023)
Article
Chemistry, Multidisciplinary
Yubo Zou, Zeyu Chen, Zhiyuan Peng, Chuying Yu, Wenbin Zhong
Summary: The proposed method in this study allows for the preparation of ANF/rHGO and ANF/rHGO/PANI hydrogels with high mechanical properties and thermal stability, demonstrating excellent recoverability and oil absorption capacity, as well as high tensile strength in the obtained films, promising for various applications.
Article
Chemistry, Physical
Shiliang Chen, Shuoshuo Lei, Binbin Wu, Weiping Yang
Summary: This study employed a green strategy to immobilize sulfonated cobalt phthalocyanine onto reduced graphene and investigated its catalytic activity in the degradation of phenol. The results showed that more than 90% of phenol can be removed within 75 min, and the presence of graphene positively affected the catalytic activity. Theoretical calculations revealed the nature of the catalytic activity and a detailed degradation route was established based on theoretical calculations and experimental results.
JOURNAL OF COLLOID AND INTERFACE SCIENCE
(2022)
Article
Materials Science, Multidisciplinary
Veronica A. Veloso, Diego L. Silva, Pedro L. Gastelois, Clascidia A. Furtado, Adelina P. Santos
Summary: This study investigates the effect of graphene surface modification with a long-chain fatty acid on the interaction and distribution of PANI/graphene nanocomposites. By using ball milling, the graphene surface is successfully functionalized with a fatty acid, allowing the uniform growth of PANI. The characterization results suggest that the functionalized graphene enables the production of a nanocomposite with a uniform distribution, better graphene incorporation, and good electronic properties.
MATERIALS CHEMISTRY AND PHYSICS
(2022)
Article
Electrochemistry
Yangbin Ding, Haonan Sheng, Baozhi Gong, Peisong Tang, Guoxiang Pan, Yunxiong Zeng, Liming Yang, Yanhong Tang, Chengbin Liu
Summary: The dynamics of charge storage in both the surface and bulk of materials is a key issue in energy storage, with maintaining a high surface-induced capacitive contribution proposed as a solution to slow kinetics. Using TiO2 nanotube arrays on Ti foil as the current collector for electrodeposition of PANI/rGO hybrid film, it was found to achieve high specific capacity and outstanding rate capacity, demonstrating the effectiveness of the approach.
ELECTROCHIMICA ACTA
(2021)
Article
Chemistry, Physical
Maximilian Becker, Wengao Zhao, Francesco Pagani, Claudia Schreiner, Renato Figi, Walid Dachraoui, Rabeb Grissa, Ruben-Simon Kuehnel, Corsin Battaglia
Summary: The compatibility of LiNi0.8Mn0.1Co0.1O2 (NMC811) with non-flammable water-in-salt electrolytes is investigated. It is found that the enhanced salt concentration effectively diminishes degradation phenomena and that self-discharge reactions lead to irreversible capacity losses.
ACS APPLIED ENERGY MATERIALS
(2022)
Article
Chemistry, Multidisciplinary
Zhaokun Wang, Licong Jiang, Hongwei Pan, Yongyin Cui, Chengzhong Zong
Summary: In this study, resveratrol was used as a green reducing agent to prepare reduced graphene oxide with excellent electrochemical performance. The composite exhibited high specific capacitance, stable cycle performance, and ultrahigh-rate performance, making it a promising material for supercapacitors.
NEW JOURNAL OF CHEMISTRY
(2021)
Article
Biochemistry & Molecular Biology
Wei Chen, Bing Wang, Shanshan Liang, Meng Wang, Lingna Zheng, Si Xu, Jiali Wang, Hao Fang, Pu Yang, Weiyue Feng
Summary: This study investigated the deposition and injury of PEGylated graphene oxide sheets (GOs) in the kidneys of mice. High doses of GO injection induced significant histological and ultrastructural changes in the kidneys. GO uptake by renal cells triggered cellular membrane damage and increased oxidative stress, leading to cellular apoptosis and inflammation. The results suggest that the dosage of GOs should be considered, and the potential nephrotoxicity of high-dose GO deposition needs more attention.
Article
Materials Science, Multidisciplinary
Ufana Riaz, Nuzhat Nabi, Faith R. Nwanze, Fei Yan
Summary: This study for the first time reports the modification of aniline with alanine using ultrasound-assisted polymerization. The formation of Ala-incorporated polyaniline (PANI) was confirmed by various analyses. The binding affinity of Ala/PANI towards BSA and HSA was found to be good, with hydrogen bonding and Van der Waal's forces playing a significant role.
Article
Chemistry, Physical
Min Li, Bilin Xu, Linjuan Zheng, Jialiang Zhou, Zhengxin Luo, Wanfei Li, Wujun Ma, Qinghui Mao, Hengxue Xiang, Meifang Zhu
Summary: In this study, a PANI@CNT/PRGO hybrid fiber was designed and fabricated, enabling rapid ion diffusion, fast electron transport, and sufficient utilization of active sites. The strong interfacial interaction between PANI and CNT/PRGO fiber resulted in excellent deformation and cycling stability, while achieving a high volumetric capacitance of 50.2 F cm-3 and outstanding energy density of 6.97 mWh cm-3.
Article
Materials Science, Multidisciplinary
Arian Mohammadzadeh, Hamidreza Ghafouri Taleghani, Mohammad Soleimani Lashkenari
Summary: In this study, a novel anti-corrosion coating was synthesized using doped polyaniline, RGO, and modified Na-MMT. The addition of RGO and Na-MMT to polyaniline significantly enhanced the anti-corrosion properties of the coating. After the salt spray test, sample a showed a very high and desirable durability.
JOURNAL OF MATERIALS RESEARCH AND TECHNOLOGY-JMR&T
(2021)
Article
Chemistry, Multidisciplinary
Wen Chen, Shunqiong Jiang, Han Xiao, Xufeng Zhou, Xueyan Xu, Jingdong Yang, Ahmad Hassan Siddique, Zhaoping Liu
Summary: In this study, highly conductive graphene was incorporated into a hydrogel-based stretchable electrode to anchor polyaniline (PANI), improving the conductivity and structural stability of the electrode. The obtained supercapacitor exhibited high capacitance and excellent cyclic stability, maintaining a high capacitance even under stretching strain, demonstrating the potential application value of graphene in stretchable energy storage devices.
Article
Chemistry, Multidisciplinary
Chen Ye, Yangguang Zhu, Hongyan Sun, Feiyue Chen, Huifang Sun, Wen Dai, Qiuping Wei, Li Fu, Aimin Yu, Shiyu Du, Minghui Yang, Liang-Feng Huang, Jinhong Yu, Nan Jiang, Cheng-Te Lin
Summary: Graphene nanosheets are widely used in anti-corrosion polymeric coating as filler due to their excellent electrochemical inertness and barrier property. However, the difficulty in forming a perfect layered structure leads to the need for micron-scale thickness in polymeric coatings with graphene nanosheets. In this study, layer-by-layer stacked graphene nanocoatings were fabricated on stainless steel using a self-assembly method based on the Marangoni effect. The anti-corrosion properties of the graphene coatings were evaluated, with the optimized three-layered graphene-coated sample showing significantly lower self-corrosion current density compared to bare stainless steel.
CHINESE CHEMICAL LETTERS
(2021)
Article
Nanoscience & Nanotechnology
Yi Yang, Tianyu Sun, Fuliang Ma, Liang-Feng Huang, Zhixiang Zeng
Summary: A Fe3+ doped TiO2 film with long-lasting superhydrophilicity and antifogging is prepared in this study, and experiments along with density-functional theory calculations are conducted to investigate the antifogging performance and the underlying microscopic mechanism of Fe3+ doped TiO2. The results show that Fe3+ doping can enhance the photolysis ability of TiO2 under sunlight exposure and stabilize the hydroxyl adsorbate on TiO2 surface, leading to a long-lasting superhydrophilicity.
ACS APPLIED MATERIALS & INTERFACES
(2021)
Article
Materials Science, Multidisciplinary
Nathan Z. Koocher, Liang-Feng Huang, James M. Rondinelli
Summary: Materials exhibiting negative thermal expansion are crucial for microelectronic devices and optical systems. We studied the quasi-2D characteristics and thermal expansion of Can+1TinO3n+1 family with density-functional-theory calculations and the self-consistent quasiharmonic approximation method. The NTE trend with layer number in orthorhombic materials was found to be affected by the elastic moduli and the NTE capacity, which decreases monotonically with increasing n.
PHYSICAL REVIEW MATERIALS
(2021)
Article
Chemistry, Physical
Lauren N. Walters, Liang-Feng Huang, James M. Rondinelli
Summary: This study investigates the immunity, passivation, and corrosion behavior of copper under various environmental factors using density functional theory-calculated electrochemical Pourbaix diagrams. The discrepancies between thermodynamic predictions and electrochemical observations in aqueous conditions are discussed. It is found that corrosion phases compete with solid copper precipitates near neutral pHs, and elevated temperatures favor corrosion products over passivating oxides. Pressure is shown to alter the predominance of specific ionic species in the Pourbaix diagrams.
JOURNAL OF PHYSICAL CHEMISTRY C
(2021)
Article
Nanoscience & Nanotechnology
Ruyi Zhang, Xinyan Li, Fanqi Meng, Jiachang Bi, Shunda Zhang, Shaoqin Peng, Jie Sun, Xinming Wang, Liang Wu, Junxi Duan, Hongtao Cao, Qinghua Zhang, Lin Gu, Liang-Feng Huang, Yanwei Cao
Summary: This work reports the high-quality epitaxy of 2-in. titanium nitride (TiN) films on flexible fluorophlogopite-mica (F-mica) substrates via reactive magnetron sputtering, revealing superior plasmonic and superconducting performance of the TiN/F-mica films. The study demonstrates that strain can manipulate the superconductivity of TiN films, offering a promising route for high-performance plasmonics and superconducting electronics.
ACS APPLIED MATERIALS & INTERFACES
(2021)
Article
Chemistry, Multidisciplinary
Yinghao Wu, Tian-Yu Sun, Tianhao Ge, Wenjie Zhao, Liang-Feng Huang
Summary: The authors propose a rapid processing method to accurately heal various structural defects on graphene coatings, enhancing defect healing efficiency and accuracy through the self-assembly of hydrophobic molecules and microscopic factors.
ADVANCED FUNCTIONAL MATERIALS
(2022)
Article
Engineering, Environmental
Haichao Zhao, Tian-Yu Sun, Liang-Feng Huang, Jiayu Wei, Shihui Qiu
Summary: In this study, a new nitrogen-doped polymer nanodots (NPDs) was synthesized and found to have excellent corrosion inhibition efficiency towards mild steel, with an inhibition rate of 97.95%. The atoms present in unsaturated bonds of NPDs were confirmed to play a dominant role in the interaction between corrosion inhibitor and metal substrate.
CHEMICAL ENGINEERING JOURNAL
(2022)
Article
Engineering, Environmental
Shihui Qiu, Tian-Yu Sun, Yue Su, Liang-Feng Huang, Haichao Zhao, Qunji Xue, Liping Wang
Summary: This study introduces a hierarchical nanocarrier containing gallic acid and reduced graphene oxide to prevent leakage of self-healing agents and simplify the response factor of self-healing effect. The self-healing technology applied to mild steel, coupled with the formation of a metal-phenolic passivating film on the coating, effectively inhibits coating delamination and corrosion activity.
CHEMICAL ENGINEERING JOURNAL
(2021)
Article
Materials Science, Multidisciplinary
Tian-Yu Sun, Yu Hao, Ying-Hao Wu, Wen-Jie Zhao, Liang-Feng Huang
Summary: Ultrathin two-dimensional coatings like graphene and hexagonal boron nitride have attracted attention in the field of corrosion protection for their unique properties, but understanding the microstructure, mechanisms, and interactions with substrates are crucial for their anticorrosion performance, requiring first-principles calculations based on DFT for insight into the microscopic mechanisms.
Article
Chemistry, Multidisciplinary
Kaiyuan Shi, Arghya Dutta, Yu Hao, Mengting Zhu, Lingyan He, Yu Pan, Xing Xin, Liang-Feng Huang, Xiayin Yao, Jinghua Wu
Summary: A universal strategy of dendrite suppression in lithium metal batteries is proposed by electrochemical polishing of the lithium metal surface. This technique smoothes the surface and regenerates a homogeneous solid electrolyte interphase film, resulting in a dendrite-free deposition of lithium and improved battery performance.
ADVANCED FUNCTIONAL MATERIALS
(2022)
Review
Chemistry, Physical
Yu Hao, Tian-Yu Sun, Liang-Feng Huang
Summary: This article reviews the role and microscopic mechanisms of defective MoS2 in electrochemical reactions from the perspective of density-functional-theory simulation. It also projects the future research trends and challenges in the electrochemical catalysis and corrosion of defective MoS2.
CURRENT OPINION IN ELECTROCHEMISTRY
(2022)
Article
Chemistry, Multidisciplinary
Yuming Jin, Qinsheng He, Gaozhan Liu, Zhi Gu, Ming Wu, Tianyu Sun, Zhihua Zhang, Liangfeng Huang, Xiayin Yao
Summary: In this study, Li10GeP2S12 is fluorinated to form a LiF-coated solid electrolyte LiF@Li10GeP2S12, which shows superior moisture stability and lower electronic conductivity. The LiF shell can reduce H2O adsorption and PS43- dissociation in Li10GeP2S12, resulting in improved moisture resistance. Additionally, the LiF shell can suppress lithium dendrite growth and reduce side reactions, leading to higher critical current density and better battery performance.
ADVANCED MATERIALS
(2023)
Article
Multidisciplinary Sciences
Yu Hao, Liping Wang, Liang-Feng Huang
Summary: By combining calculations and simulations, the authors discovered enhanced oxygen reduction activity with a biperiodic chemical trend on lanthanide-doped MoS2 materials. A defect-state pairing mechanism selectively stabilizes the adsorbates involved in the oxygen reduction reaction.
NATURE COMMUNICATIONS
(2023)
Article
Chemistry, Multidisciplinary
Jinbo Chen, Guangming Lu, Yu Hao, Yichao Lu, Liang-Feng Huang, Yajie Zhang
Summary: Highly efficient and eco-friendly antimicrobial agents are essential for the development of future marine antifouling coatings. A bio-based anti-biofoulant, 2,5-diformylfuran dioxime chelating with copper ions (E-DFFD-Cu), showed excellent performance in inhibiting biofouling in the marine environment. The mechanism involves enhanced alkyl and hydrogen radicals, which disrupt microbe cell membranes and pili.
ADVANCED MATERIALS INTERFACES
(2023)
Article
Chemistry, Physical
Guiyuan Ma, Jintao Ye, Mengyuan Qin, Tianyu Sun, Wenxue Tan, Zunhao Fan, Liangfeng Huang, Xing Xin
Summary: Researchers prepared Mn-doped nickel cobalt phosphide (Mn-NiCoP) with nanopins arrays on nickel foam, which exhibited low overpotentials of 148 mV for HER and 266 mV for OER at a high current density. The water splitting performance of Mn-NiCoP as both anode and cathode was 1.69 V and maintained 94% efficiency after 240 hours. By conducting first-principles calculations, it was determined that the synergistic effect of moderate Mn doping and Co alloying contributed to the improvement of both OER and HER performance on Mn-NiCoP. This study provides inspiration for optimizing the OER performance of traditional HER catalysts, facilitating overall water splitting using a single catalyst in the same solution.