4.6 Article

Tunable Metal/Silicon Hybrid Dots Catalysts for Hydrocarbon Selective Oxidation

期刊

JOURNAL OF PHYSICAL CHEMISTRY C
卷 116, 期 38, 页码 20363-20367

出版社

AMER CHEMICAL SOC
DOI: 10.1021/jp305411u

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资金

  1. National Basic Research Program of China (973 Program) [2012CB825800]
  2. National Natural Science Foundation of China (NSFC) [51132006, 21073127, 21071104]
  3. Foundation for the Author of National Excellent Doctoral Dissertation of P. R. China (FANEDD) [200929]
  4. Priority Academic Program Development of Jiangsu Higher Education Institutions (PAPD)
  5. Suzhou Planning Project of Science and Technology [ZXG2012028]
  6. Natural Science Foundation of the Jiangsu Higher Education Institutions of China [11KJB150015]

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Metal (Au, Ag, and Pt)/silicon hybrid dots were facially prepared by a one-step reaction between Si quantum dots (SiQDs) and metal salts at room temperature without any templates and surfactants. The obtained Au/SiQDs were demonstrated to be a superior catalyst for selective oxidation of cyclohexene. By altering the composition of Au/SiQDs catalysts, the selectivity of main products can be tuned step-by-step.

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