期刊
JOURNAL OF PHYSICAL CHEMISTRY C
卷 114, 期 13, 页码 6027-6034出版社
AMER CHEMICAL SOC
DOI: 10.1021/jp911069t
关键词
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资金
- EPSRC
- Cambridge Commonwealth Trust
- BP Institute
- University of Cambridge
- European Community [FP7/2007-2013]
- Engineering and Physical Sciences Research Council [EP/E001211/1] Funding Source: researchfish
- EPSRC [EP/E001211/1] Funding Source: UKRI
In this work we present a study on the adsorption of linear alkyl aldehydes physisorbed from their bulk liquid onto a graphite substrate combining calorimetry for all homologues from C6 to C13, with more detailed diffraction, incoherent neutron scattering, and scanning tunneling microscopy techniques for one (C12) representative member. We identify solid monolayer formation for some of these species for alkyl chain lengths of 6 to 13 carbons at high surface coverages. The C12 monolayer structure is determined to be most likely Pgg and this structure is discussed in terms of the importance of dipolar interactions.
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