Article
Chemistry, Analytical
Siyuan Jing, Yu Huang, Yinjuan Chen, Xueqing He, Zhong Chen, Xingyu Lu, Minghuo Wu, Thomas C. Wanger
Summary: This study developed a simple and effective method using density gradient ultracentrifugation (DGU) to extract and separate various types of nano-/microplastics (NMPs) from environmental samples. By changing the density of the density gradient medium, different sizes of NMPs could be extracted and separated from soil samples. The effectiveness and compatibility of DGU were confirmed through the correct identification of NMPs using various analytical methods.
ANALYTICAL CHEMISTRY
(2022)
Article
Chemistry, Multidisciplinary
Shiyi Han, Nguyen Tuan Hung, Ying Xie, Riichiro Saito, Jin Zhang, Lianming Tong
Summary: The helicity-dependent Raman spectra of an isolated, chiral, single-wall carbon nanotube were studied using circularly polarized light. It was found that the polarized Raman intensity for the radial breathing mode exhibited an asymmetric angle dependence, reflecting the axial chirality of the nanotube. The complex phase of each component of the Raman tensor reached a maximum at a chiral angle of 15 degrees, which was between two non-chiral nanotubes.
Article
Chemistry, Multidisciplinary
Yi-Bo Tian, Koichi Tanaka, Li-Mei Chang, Christof Woell, Zhi-Gang Gu, Jian Zhang
Summary: In this study, monolithic and highly oriented chiral metal-organic framework (MOF) thin films were successfully prepared using a layer-by-layer method. The helicity-sensitive absorption of these films showed excellent performance, with an anisotropy factor of 0.41. The chiral MOF thin films also exhibited significant differences in the uptake of enantiomers. A portable sensor device was fabricated to demonstrate the potential for chiral recognition and analysis by monitoring photocurrent signals. This research introduces a new concept for direct circularly polarized photodetectors using chiral building blocks and offers a blueprint for novel devices in chiral optics.
Article
Chemistry, Physical
Lin Liu, Xiaojun Wei, Zhihui Yao, Xiao Li, Wenke Wang, Yanchun Wang, Weiya Zhou, Feibing Xiong, Hiromichi Kataura, Sishen Xie, Huaping Liu
Summary: This study reports the use of a sodium hyodeoxycholate derivative for the separation of metallic and semiconducting SWCNTs. The addition of NaOH can enhance the adsorbability of metallic SWCNTs coated with SHC and SDS surfactants on dextran-based gel, allowing for their separation. The study provides an effective strategy for the separation of metallic SWCNTs.
JOURNAL OF PHYSICAL CHEMISTRY C
(2022)
Article
Chemistry, Multidisciplinary
Fuli Zhou, Oleksii Shemchuk, Maxime D. Charpentier, Chloe Matheys, Laurent Collard, Joop H. ter Horst, Tom Leyssens
Summary: This study explores a new method for simultaneous chiral resolution of two racemic compounds through preferential cocrystallization. By combining RS-mandelic acid and RS-etiracetam as enantiospecific cocrystals and implementing a cyclic preferential crystallization process, the research achieves excellent enantiopurity levels for both compounds.
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
(2021)
Article
Environmental Sciences
Guobin Song, Anqi Li, Yawei Shi, Wanran Li, Haonan Wang, Chunchao Wang, Ruijuan Li, Guanghui Ding
Summary: In this study, five magnetic multi-walled carbon nanotubes with different diameters were prepared and their performance in removing methylene blue from water was investigated. The surface of these nanotubes was decorated with Fe3O4 nanoparticles, making them superparamagnetic. The results showed promising potential for these nanotubes as adsorbents for dye removal in wastewater treatment.
ENVIRONMENTAL SCIENCE AND POLLUTION RESEARCH
(2021)
Article
Chemistry, Multidisciplinary
Dean Amir, Adi Hendler-Neumark, Verena Wulf, Roni Ehrlich, Gili Bisker
Summary: Researchers have developed a near-infrared optical nanosensor for the detection of the oncometabolite D2HG, which exhibits a fluorescence intensity increase upon interaction. The sensor's fluorescence response is independent of the chemical features of the target analytes and can discriminate D2HG from other related metabolites.
ADVANCED MATERIALS INTERFACES
(2022)
Article
Chemistry, Multidisciplinary
Xiaoxuan Wang, Song Xiang, Chunxuan Qi, Mingyu Chen, Xiaolong Su, Jun-Cheng Yang, Jingjing Tian, Hai-Tao Feng, Ben Zhong Tang
Summary: Enantioselective recognition and separation have been achieved using optically active luminogens with aggregation-induced emission (ME) characteristics. The AIEgens show strong discrimination for various chiral acids and amino acids. By aggregating the AIEgens with one enantiomer in the mixed acid solution, enantioselective separation is achieved. The aggregates possess high enantiomeric excess, which is in good agreement with chiral HPLC analysis results.
Article
Polymer Science
Liang Xu, Michal Valasek, Frank Hennrich, Regina Fischer, Manfred M. Kappes, Marcel Mayor
Summary: This study utilized conjugated polymer sorting to purify as-produced single-walled carbon nanotubes, obtaining high-purity semiconducting SWCNTs. Several degradable copolymers were synthesized for selective extraction of s-SWCNTs, with successful removal of the polymer after acid treatment to obtain dispersant-free s-SWCNTs. This research paves the way for the development of the next generation of CNT devices using dispersant-free semiconducting carbon nanotubes.
Article
Chemistry, Physical
Joanna Dobrzynska, Agnieszka Mroz, Rafal Olchowski, Emil Zieba, Ryszard Dobrowolski
Summary: This study investigated the effect of different modifiers on multiwalled carbon nanotubes (MWNTs). The results showed that amine-modified CNTs exhibited excellent adsorption performance for Pt(IV) ions, and achieved high enrichment factor and low detection limit in the enrichment of platinum.
APPLIED SURFACE SCIENCE
(2022)
Article
Chemistry, Inorganic & Nuclear
Yanyu Zhu, Tianyang Ding, Xu Zhang, Yanan Zhou, Jiahui Yu, Xin Li, Hanwen Zheng, Zhengang Sun, Chengqi Jiao
Summary: A series of monometallic and bimetallic metal-organic frameworks were successfully synthesized for studying the noncovalent induced circular dichroism (ICD) sensing mechanism. Among them, LNNU-2 exhibited excellent ICD sensing performance due to the strong metal coordination interaction with chiral tryptophan. In contrast, LNNU-3 showed no ICD effect with chiral tryptophan due to the absence of metal coordination interaction.
INORGANIC CHEMISTRY FRONTIERS
(2023)
Article
Engineering, Environmental
Hong Wang, Sha Zhu, Zhanshuo Dai, Xinze Li, Taigang Zhou
Summary: A low cost and green catalyst (Co/RH-SiO2) using rice husk-derived SiO2 as support selectively synthesized large diameter single-walled carbon nanotubes (SWCNTs) with a percentage of 70.7% at 950 degrees Celsius. The catalyst had abundant small mesopores (2-4 nm) and reducible Co hydrosilicate and surface Co silicates highly dispersed in the pore structures, resulting in the growth of large-diameter SWCNTs. This study provides insights for the development of low cost and green catalysts for selective growth of SWCNTs from biomass waste.
JOURNAL OF ENVIRONMENTAL CHEMICAL ENGINEERING
(2023)
Review
Chemistry, Multidisciplinary
Jaehyoung Ko, Yongho Joo
Summary: The development of sorting techniques for SWCNTs has led to the replacement of unsorted SWCNTs with electronically enriched SWCNTs in various applications to improve device performance. While research has focused on semiconducting SWCNTs, the potential of metallic SWCNTs has been largely disregarded despite their exceptional properties that complement those of semiconducting SWCNTs. A comprehensive review of research on metallic SWCNTs in the past decade is necessary to highlight their role in various applications.
ADVANCED MATERIALS INTERFACES
(2021)
Review
Chemistry, Multidisciplinary
Raha Kaviani, Abolghasem Jouyban, Ali Shayanfar
Summary: This review outlines the crucial importance of pharmaceutical cocrystals in chiral resolution techniques of racemic compounds, discussing different cocrystallization methods.
Article
Multidisciplinary Sciences
Weichao Peng, Shuaihu Yan, Ke Zhou, Hai-Chen Wu, Lei Liu, Yuliang Zhao
Summary: By using a modified density gradient ultracentrifugation method, ultrashort single-walled carbon nanotubes (SWCNTs) with a narrow conductance range can be separated and inserted into lipid bilayers to construct high-resolution nanopore sensors. These SWCNT nanopores exhibit 3-5 times higher ion mobility compared to bulk mobility, and are capable of discriminating homologous and isomeric proteinogenic amino acids, which is challenging for other types of nanopore sensors. These findings hold great importance for the development of protein sequencing technologies.
NATURE COMMUNICATIONS
(2023)
Article
Chemistry, Multidisciplinary
Mitsunori Inoue, Atsuhiro Osuka
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
(2010)
Article
Chemistry, Multidisciplinary
Tomohiro Higashino, Jong Min Lim, Takahiro Miura, Shohei Saito, Jae-Yoon Shin, Dongho Kim, Atsuhiro Osuka
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
(2010)
Article
Chemistry, Multidisciplinary
Jianxin Song, Naoki Aratani, Pyosang Kim, Dongho Kim, Hiroshi Shinokubo, Atsuhiro Osuka
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
(2010)
Article
Chemistry, Multidisciplinary
Shin-Ya Hayashi, Jooyoung Sung, Young Mo Sung, Yasuhide Inokuma, Dongho Kim, Atsuhiro Osuka
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
(2011)
Article
Chemistry, Multidisciplinary
Tomoki Yoneda, Shohei Saito, Hideki Yorimitsu, Atsuhiro Osuka
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
(2011)
Article
Chemistry, Multidisciplinary
Taro Koide, Atsuhiro Osuka
BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN
(2010)
Article
Chemistry, Multidisciplinary
Jong Min Lim, Mitsunori Inoue, Young Mo Sung, Masaaki Suzuki, Tomohiro Higashino, Atsuhiro Osuka, Dongho Kim
CHEMICAL COMMUNICATIONS
(2011)
Article
Chemistry, Multidisciplinary
Pyosang Kim, Toshiaki Ikeda, Jong Min Lim, Jaeheung Park, Manho Lim, Naoki Aratani, Atsuhiro Osuka, Dongho Kim
CHEMICAL COMMUNICATIONS
(2011)
Article
Chemistry, Multidisciplinary
Atsuhiro Osuka, Shohei Saito
CHEMICAL COMMUNICATIONS
(2011)
Article
Chemistry, Organic
Hisashi Sugimoto, Masahiro Muto, Takayuki Tanaka, Atsuhiro Osuka
EUROPEAN JOURNAL OF ORGANIC CHEMISTRY
(2011)
Article
Chemistry, Multidisciplinary
Tsuneaki Sakurai, Kentaro Tashiro, Yoshihito Honsho, Akinori Saeki, Shu Seki, Atsuhiro Osuka, Atsuya Muranaka, Masanobu Uchiyama, Jungeun Kim, Sunyeo Ha, Kenichi Kato, Masaki Takata, Takuzo Aida
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
(2011)
Article
Chemistry, Organic
Chihiro Maeda, Hiroshi Shinokubo, Atsuhiro Osuka
Article
Chemistry, Organic
Shin-ya Hayashi, Yasuhide Inokuma, Atsuhiro Osuka
Article
Chemistry, Inorganic & Nuclear
Keita Yoshida, Shigeru Yamaguchi, Atsuhiro Osuka, Hiroshi Shinokubo
Article
Chemistry, Multidisciplinary
Jianxin Song, Naoki Aratani, Hiroshi Shinokubo, Atsuhiro Osuka