Article
Nanoscience & Nanotechnology
Yanxian Zeng, Qijie Li, Xiaochun Niu, Suying Wang, Andrew T. Smith, Mingtao Zheng, Luyi Sun, Weixing Wang
Summary: Photoluminescent mesoporous silica with high surface area and pore diameter was successfully synthesized using a co-templating method, with the photoluminescence originating from the trapped carbon in the co-templates.
ADVANCED COMPOSITES AND HYBRID MATERIALS
(2021)
Article
Biochemistry & Molecular Biology
Misun Kang, Jong-tak Lee, Jae Young Bae
Summary: Formaldehyde emitted from household products is harmful to human health. This study compares the formaldehyde adsorption characteristics of mesoporous and mesoporous hollow silicas synthesized with or without a calcination process. The mesoporous hollow silica synthesized without a calcination process has the best adsorption performance, followed by the mesoporous hollow silica synthesized with a calcination process and mesoporous silica. This research demonstrates the potential of mesoporous hollow silica as an effective support for harmful gas adsorption.
INTERNATIONAL JOURNAL OF MOLECULAR SCIENCES
(2023)
Article
Agronomy
Jianguo Feng, Zhiyang Chen, Wang Chen, Li Sun, Jinghan Yang, Kangli He, Sa Dong, Shuzhong Yuan
Summary: The study demonstrated that the PYR@MSNs had regular spherical shapes, uniform particle size (200 nm), high drug loading (38.9%), and enhanced UV resistance. Compared to traditional formulations, PYR@MSNs showed improved control effects against Fusarium graminearum, prolonged control period, and lower toxicity to zebrafish, earthworms, and BEAS-2B cells.
PEST MANAGEMENT SCIENCE
(2022)
Article
Biochemistry & Molecular Biology
Jingxin Zhu, Haijuan Wu, Ding Wang, Yanlong Ma, Lan Jia
Summary: This paper presents a facile and low-cost strategy for fabricating lysozyme-loaded mesoporous silica nanotubes using silk fibroin nanofiber templates. By loading lysozyme, the MSNTs exhibited relatively high drug encapsulation efficiency and excellent long-term sustained release. These results suggest that MSNTs with a hierarchical structure will be a promising carrier for biomacromolecular drug delivery systems.
Article
Chemistry, Analytical
Wei Hu, Lu Liu, Yunhui Fan, Mingxian Huang
Summary: By synthesizing novel mesoporous copper silicate materials, high selectivity and binding capacity for histidine-rich proteins have been achieved, showing great potential for pretreatment of complex biological samples.
MICROCHEMICAL JOURNAL
(2021)
Article
Engineering, Environmental
Yige Guo, Ying Zhao, Tianxue Yang, Bin Gong, Bin Chen
Summary: A new hybridization strategy of Fe/Cu bimetal and silica-based mesoporous molecular sieve MCM-41 has been proposed to improve the performance of Fe-0 in removing Cr (VI) from water. The results showed that the two-dimensional mesoporous structure of MCM-41 can provide skeleton support for Fe-0 and overcome aggregation bottleneck, leading to a high Cr(VI) removal rate of 98.98% after 40 minutes.
JOURNAL OF HAZARDOUS MATERIALS
(2021)
Article
Pharmacology & Pharmacy
Paz de la Torre, Juan L. Paris, Miguel Fernandez-de la Torre, Maria Vallet-Regi, Ana Flores
Summary: Combination therapies utilizing tumor-migrating decidua-derived mesenchymal stromal cells as therapeutic agents show potential for cancer treatment, combining antiangiogenic therapy and chemotherapy. The study successfully demonstrated the expression of the antiangiogenic protein endostatin and the efficacy of doxorubicin-loaded mesoporous silica nanoparticles in in vitro models.
Article
Biochemistry & Molecular Biology
Adrian Szewczyk, Joanna Brzezinska-Rojek, Justyna Osko, Dorota Majda, Magdalena Prokopowicz, Malgorzata Grembecka
Summary: This study investigated the adsorption and desorption of gallic acid (GA), protocatechuic acid (PCA), chlorogenic acid (CGA), and 4-hydroxybenzoic acid (4-HBA) using commercially available mesoporous silica materials (MSMs). The results showed that amine-modified SBA-15 mesoporous silica exhibited the highest adsorption capacity for GA, and the antioxidant capacity of the adsorbed compounds was preserved after desorption.
Article
Chemistry, Multidisciplinary
Cheng Xu, Hannah E. Dobson, Mengjie Yu, Wang Gong, Xiaoqi Sun, Kyung Soo Park, Andrew Kennedy, Xingwu Zhou, Jin Xu, Yao Xu, Andrew W. Tai, Yu Leo Lei, James J. Moon
Summary: This study developed a manganese-silica nanoplatform (MnOx@HMSN) that enhances the adjuvant effects of CDNs for vaccination against cancer and SARS-CoV-2. The nanoplatform efficiently co-loaded CDNs and antigens, resulting in robust immune responses and therapeutic efficacy.
JOURNAL OF CONTROLLED RELEASE
(2023)
Article
Chemistry, Multidisciplinary
Gabriela Petrisor, Denisa Ficai, Ludmila Motelica, Roxana Doina Trusca, Alexandra Catalina Birca, Bogdan Stefan Vasile, Georgeta Voicu, Ovidiu Cristian Oprea, Augustin Semenescu, Anton Ficai, Mircea Ionut Popitiu, Irina Fierascu, Radu Claudiu Fierascu, Elena Lacramioara Radu, Lilia Matei, Laura Denisa Dragu, Ioana Madalina Pitica, Mihaela Economescu, Coralia Bleotu
Summary: This study developed two types of support materials with a mesoporous structure and loaded them with gallic acid. The results showed that loading gallic acid significantly reduced the specific surface area and inhibited gram-negative bacterial strains. Moreover, these materials may be useful for the recovery of gut microbiota after antibiotic exposure.
Article
Medicine, Research & Experimental
Ahmad Alkhazaleh, Sundes Elfagih, Leela Raghava Jaidev Chakka, Steven R. Armstrong, Carissa L. Comnick, Fang Qian, Aliasger K. Salem, C. Allan Guymon, Amanda J. Haes, Cristina M. P. Vidal
Summary: This study investigated the use of mesoporous silica nanoparticles (MSNs) for dental tissue biomodification. The incorporation of MSNs loaded with proanthocyanidin (PAC) improved the mechanical properties and bonding performance of dental restorative materials.
MOLECULAR PHARMACEUTICS
(2022)
Article
Chemistry, Applied
Jing Hu, Ruoyi Xu, Jing Hu, Weijun Deng
Summary: In this paper, a dual stabilization method for Pickering emulsions, which can stabilize both the oil phase and the antioxidant, is introduced. The use of mesoporous silica nanospheres (MSN) loaded with an antioxidant called epigallocatechin gallate (EGCG) improves the physical and chemical stabilization of the emulsion. Olfactory evaluation and chemical analysis demonstrate that the Pickering emulsion effectively preserves the odor and chemical compounds of the essential oil.
Article
Chemistry, Inorganic & Nuclear
Huan Liu, Qian Liu, Yongjun Feng, Dianqing Li, Dongmei Xu, Pinggui Tang
Summary: Mesoporous In2O3 nanoparticles were synthesized and used for ethanol detection. Loading Au nanoparticles into mesoporous In2O3 resulted in highly sensitive Au/In2O3 for ethanol gas sensing, showing excellent selectivity, short response/recovery time, low detection limit, good linear relationship, superb repeatability, and wonderful long-term stability.
DALTON TRANSACTIONS
(2023)
Article
Materials Science, Multidisciplinary
Sara Saber Younes Mohamed, Alberto Gambino, Mauro Banchero, Silvia Ronchetti, Luigi Manna, Roberta Cavalli, Barbara Onida
Summary: The aim of this study was to develop a hemostat based on mesoporous silica particles for bleeding control. The synthesized mesoporous silica microspheres loaded with tranexamic acid showed promising hemostatic activity and blood compatibility. In vitro release tests demonstrated the complete release of tranexamic acid from the carrier within one hour. This material can be considered as a potential candidate for the development of new hemostats.
MATERIALS TODAY COMMUNICATIONS
(2023)
Article
Pharmacology & Pharmacy
Ali Jadidi, Mohammad Ali Shokrgozar, Soroush Sardari, Amir Mohammad Maadani
Summary: This study developed a pH-sensitive drug delivery system for the treatment of gastric cancer. The system showed selective cytotoxicity towards gastric cancer cells, sustained release, and high mucoadhesive properties.
INTERNATIONAL JOURNAL OF PHARMACEUTICS
(2022)
Article
Chemistry, Physical
Jie Xu, Yu-Lin Gan, Jiao-Jiao Pei, Bing Xue
MOLECULAR CATALYSIS
(2020)
Article
Chemistry, Physical
Xin-Tong Yi, Tian-Lu Wang, Lin-Zhi Wen, Jie Xu, Bing Xue
Summary: In this study, nitrogen-containing ordered mesoporous materials (NOMCs) were prepared and utilized as supports to load vanadia for liquid-phase selective oxidation of benzyl alcohol to benzaldehyde using oxygen as an oxidant. The VxOy/NOMC materials exhibited good dispersion of vanadia species and steady interaction between V and N, showing good and stable catalytic performance with a maximum yield of 80% benzaldehyde at 95 degrees C.
Article
Chemistry, Physical
Jie Xu, Xin-Tong Yi, Tong Zhao, Lin-Zhi Wen, Fei Wang, Bing Xue
Summary: A series of nitrogen-containing ordered mesoporous carbon (NOMC) materials were prepared using a one-pot soft templating method, successfully loading palladium (Pd) catalysts and demonstrating enhanced catalytic activities.
MOLECULAR CATALYSIS
(2021)
Article
Chemistry, Multidisciplinary
Na Liu, Feng Wu, Jie Xu, Fei Wang, Bing Xue, Jun Luo
Summary: In this study, CN/SBA15 catalysts were prepared by impregnation method and applied in the Knoevenagel condensation reaction. The catalysts were characterized by various analytical techniques and the results showed that the introduction of carbon nitride maintained the ordered mesoporous structure of SBA-15. The distribution of nitrogen-containing functional groups in the CN/SBA15 catalysts could be controlled by adjusting the calcination temperature. The CN/SBA15-400 catalysts exhibited excellent catalytic activity in the Knoevenagel condensation reaction.
RESEARCH ON CHEMICAL INTERMEDIATES
(2022)
Article
Chemistry, Physical
Feng Wu, Juan Du, Na Liu, Jie Xu, Bing Xue
Summary: In this study, potassium-doped carbon nitride materials supported on SBA-15 (CN/SBA15-KCl) were successfully prepared and showed high catalytic performance in Knoevenagel condensation reaction. The incorporation of potassium enhanced the basic strength of CN/SBA15, leading to improved catalytic activity.
APPLIED CATALYSIS A-GENERAL
(2022)
Article
Chemistry, Physical
Na Liu, Feng Wu, Jie Xu, Bing Xue, Jun Luo
Summary: In this study, ZrO2/g-C3N4 materials were synthesized as efficient heterogeneous catalysts for the cycloaddition of CO2 with propylene oxide. The catalysts exhibited good catalytic activity, with a maximum yield of 68% propylene carbonate, and showed good recyclability and substrate generality.
Article
Chemistry, Multidisciplinary
Na Liu, Juan Du, Jie Xu, Bing Xue, Jun Luo
Summary: In this study, acid-base bifunctional g-C3N4 materials were synthesized by incorporating Zr and Al cations. The synthesized ZrxAlyO/g-C3N4 materials showed superior catalytic activity in the cycloaddition of CO2 with propylene oxide, with a maximum yield of propylene carbonate reaching 90%. The catalysts could be recycled at least five times without any loss in catalytic activity.
RESEARCH ON CHEMICAL INTERMEDIATES
(2022)
Article
Chemistry, Physical
Ye Zhu, Xue-Wen Zhang, Fei Wang, Bing Xue, Jie Xu
Summary: Mesoporous carbon nitride (mpg-C3N4) was prepared and used as a catalytic support for CoOx in the selective oxidation of ethylbenzene. The physicochemical properties of the CoOx/mpg-C3N4 materials were characterized, and their catalytic activities were examined under atmospheric pressure. The mpg-C3N4 showed a higher specific surface area and strong interaction with Co (II) species, resulting in a conversion rate of 62% and a selectivity of 84.7% for ethylbenzene under specific reaction conditions.
Article
Chemistry, Physical
Meng Feng, Mei-Yang Wang, Fei Wang, Bing Xue, Jie Xu
Summary: Selective oxidation of alcohols under solvent-free and atmosphere-pressure conditions is a promising strategy for the synthesis of aldehydes and carboxylic compounds. In this study, Pd/CeO2 catalysts were prepared using CeO2 as the support material, and exhibited high catalytic activity for the conversion of benzyl alcohol to benzaldehyde. The activity of the catalyst was correlated with the oxygen vacancy and the percentage of Pd2+ in the catalyst.
APPLIED CATALYSIS A-GENERAL
(2023)
Article
Chemistry, Physical
Chun-Yuan Li, Meng Feng, Lei Cui, Fei Wang, Bing Xue, Jie Xu
Summary: In this study, a catalyst support was synthesized by controlling thermal exfoliation of g-C3N4, and Pd nanoparticles were loaded on it for the selective oxidation of benzyl alcohol. The results showed that the chemical valence and dispersion of Pd nanoparticles were key factors for the catalytic activity, and the gas conditions affected the distribution of Pd and nitrogen species. Under the optimal conditions of the catalyst 2.5Pd/eg-C3N4-AN, the conversion of benzyl alcohol and the selectivity to benzaldehyde reached 88% and 92%, respectively.
Article
Chemistry, Multidisciplinary
Ye Zhu, Lin-Zhi Yu, Fei Wang, Jie Xu, Bing Xue
Summary: In this study, exfoliated graphitic carbon nitride (eg-C3N4) was used as a support to load cobalt catalysts (CoOx/eg-C3N4) via a simple impregnation method. The physical and chemical properties of the synthesized CoOx/eg-C3N4 materials were characterized using various analytical techniques. The introduction of Co2+ species did not alter the graphitic structure of eg-C3N4, but probably interacted coordinatively with the nitrogen-containing group of eg-C3N4. The catalytic performance of the CoOx/eg-C3N4 materials, particularly 3CoO(x)/eg-C3N4-400, showed high conversion of ethylbenzene due to its superior percentages of Co2+ and tertiary nitrogen species.
Article
Chemistry, Physical
Rui-Ming Wang, Meng Feng, Fei Wang, Bing Xue, Jie Xu
Summary: This study focuses on the sustainable synthesis of benzaldehyde through the selective oxidation of benzyl alcohol under atmospheric oxygen, with a particular emphasis on the development of low-cost metal catalysts. Vanadia catalysts supported on carbon nitride (VO/eg-C3N4) were prepared using a wet-impregnation method and characterized using various techniques. The results showed that the catalyst exhibited moderate catalytic activity and outperformed vanadia catalysts supported on SBA-15 and CNTs materials under the same reaction conditions.
Article
Chemistry, Multidisciplinary
Xin-Tong Yi, Chun-Yuan Li, Fei Wang, Jie Xu, Bing Xue
Summary: In this work, Pd catalysts supported on carbon nitride-ceria composites were prepared and evaluated for the oxidation of benzyl alcohol under solvent-free and aerobic conditions. The catalyst exhibited high activity, good stability, and generality for reactions with various substrates.
NEW JOURNAL OF CHEMISTRY
(2022)
Article
Chemistry, Multidisciplinary
Xin-Tong Yi, Tong Zhao, Fei Wang, Jie Xu, Bing Xue
Summary: The study introduced the utilization of g-C3N4 as catalyst support to load palladium nanoparticles for alcohol oxidation reactions. Through the analysis of the properties of Pd/eg-C3N4 materials, it was found that the catalyst exhibited high and stable catalytic activity in the selective oxidation of benzyl alcohol, showing promising potential for applications.
NEW JOURNAL OF CHEMISTRY
(2021)
Article
Chemistry, Multidisciplinary
Yu-Lin Gan, Xiao-Qian Hu, Lin-Zhi Wen, Jie Xu, Bing Xue
NEW JOURNAL OF CHEMISTRY
(2020)