Article
Polymer Science
Zongao Dou, Ruru Wan, Hui Shen, Xiaoli Sun, Huihui Li, Shouke Yan
Summary: The structure and organization of PVDF spherulites in blends with PMMA-H and PMMA-L have been studied. It is found that PMMA-H and PMMA-L have different effects on the morphologies of PVDF spherulites, including ring-band spacing, growth rate, alpha- gamma ' transition rate, and the formation mechanism of Wagon-Wheel spherulites.
Article
Chemistry, Multidisciplinary
Daniela M. Correia, Carlos M. Costa, Jose C. Rodriguez Hernandez, Isabel Tort-Ausina, Laura Teruel Biosca, Constantino Torregrosa Cabanilles, Jose Meseguer-Duenas, Ivan Krakovsky, Senentxu Lanceros-Mendez, Jose Luis Gomez Ribelles
Summary: The crystallization of PVDF is influenced by various factors, and when blended with ionic liquid [Emim][PF6], different crystalline phases are produced, leading to changes in the structure of the blend. Addition of [Emim][PF6] suppresses the formation of a-phase crystals in PVDF and causes phase separation at room temperature.
CRYSTAL GROWTH & DESIGN
(2021)
Article
Polymer Science
Jia-Yi Ren, Shu-Gui Yang, Yue Li, Jun Lei, Hua-Dong Huang, Mingwang Pan, Hao Lin, Gan-Ji Zhong, Zhong-Ming Li
Summary: This study investigates the impact of external flow, pressure, and temperature on the crystallization behavior of polymeric blends during processing. It is found that shear flow and pressure can induce the formation of specific phases, while the addition of PMMA stabilizes shear-induced local trans conformation. The synergistic effect of shear flow and PMMA leads to the transformation of PVDF crystalline structure.
Article
Polymer Science
Jian Zhou, Shanshan Xu, Jian Song, Ying Zheng, Chengtao Yu, Guorong Shan, Yongzhong Bao, Pengju Pan
Summary: The multilevel structures and structural evolutions of PVDF and PVDF/PMMA films during processing were investigated. PVDF cast films with higher melt-draw ratio showed raw-nucleated lamellar morphology, while blending PVDF with PMMA resulted in the formation of the PVDF beta phase. In the post-stretching process, PVDF cast films underwent various changes, while PVDF/PMMA films were more sensitive to the presence of the alpha phase.
Article
Nanoscience & Nanotechnology
Jiale Fang, Chengqi Chen, Hongxing Qi, Jie Zhang, Xiaoxuan Hou, Likun Pan, Xianghui Wang
Summary: Developing flexible electromagnetic interference (EMI SE) shielding materials is crucial for protecting humans from harmful radiation. We designed and fabricated a flexible multilayer structure of PVDF/GNP-PVDF composite film, which exhibited high EMI SE performance (averaging 69.7 dB in X-band), excellent flexibility, and stability (98.85% retention after bending 1000 cycles at 60 degrees). The theoretical study indicates that the multiple reflection and absorption of electromagnetic waves between layers contribute to the high EMI SE performance of the PVDF/GNP-PVDF multilayer film.
ACS APPLIED NANO MATERIALS
(2023)
Article
Chemistry, Physical
Dong Je Han, Seonwoo Kim, Hyeon Jun Heo, Chaewon Jin, Jin-young Kim, Hongsoo Choi, In Jun Park, Hong Suk Kang, Sang Goo Lee, Jong-Chan Lee, Eun-Ho Sohn
Summary: Antimicrobial PVDF-based polymers were prepared by grafting quaternary ammonium or quaternary pyridinium monomers to effectively kill bacteria and yeast. Adding these polymers to PVDF films through blending method enhanced both mechanical properties and antimicrobial performances, while maintaining biocompatibility.
APPLIED SURFACE SCIENCE
(2021)
Article
Chemistry, Physical
Benjamin Cromwell, Mara Dubnicka, Lasanthi Sumathirathne, Angela Thach, William B. Euler
Summary: Membranes of PVDF and related polymers are used to decompose RhB under low power sonication, and the change in visible spectrum of RhB allows determination of rate constants for different polymer compositions and membrane thicknesses. The piezoelectric field generated by mechanical deformation of the polymer catalyzes the scission of the C-N bond in RhB. Doping PVDF with transition-metal nitrates increases the rate constants, but the analysis is complicated by concurrent RhB adsorption onto the membrane. A proposed mechanism suggests that the piezocatalytic effect of the membrane leads to heterolytic cleavage of the C-N bond followed by formation of a C-Cl bond on the new xanthene ring.
JOURNAL OF PHYSICAL CHEMISTRY C
(2023)
Article
Nanoscience & Nanotechnology
Farzin Rahmani, Paul Scovazzo, Melissa A. Pasquinelli, Sasan Nouranian
Summary: The study revealed that nanoconfinement of a highly CO2/CH4-selective ionic liquid ([EMIM][SCN]) in porous poly(vinylidene fluoride) (PVDF) matrices can enhance the gas separation performance of membranes. Experimental and simulation results show that decreasing the IL nanoconfinement length can suppress CH4 sorption and increase CO2 affinity to nonpolar PVDF surfaces. Analysis of the IL charge/density distribution in PVDF-confined regions provides insights for better molecular design of membranes for critical gas separation and CO2 capture applications.
ACS APPLIED MATERIALS & INTERFACES
(2021)
Article
Polymer Science
Ruru Wan, Xiaoli Sun, Zhongjie Ren, Haijun Wang, Huihui Li, Shouke Yan
Summary: Poly(vinylidene fluoride) (PVDF) films with polymorphic crystal structure were prepared and the effects of heat treatment on the crystal morphology and properties were studied. The results provide a useful way to induce the formation of polar PVDF phases.
Article
Chemistry, Physical
P. Durga Prasad, J. Hemalatha
Summary: A two-step synthesis method was used to prepare a flexible PVDF/ZnFe2O4 multiferroic nanocomposite film. The incorporation of ZnFe2O4 nanofibers into a PVDF matrix resulted in composite films with 88% beta-phase, which exhibited increased dielectric constant with higher ZnFe2O4 loading. Ferroelectric and magnetic properties were analyzed using DC-EFM and MFM, respectively. A nanogenerator was fabricated from the composite films, demonstrating a peak-peak open circuit voltage of 7 V and an output power of 4 μW at a load resistance of 500 kΩ.
JOURNAL OF ALLOYS AND COMPOUNDS
(2021)
Article
Engineering, Chemical
Yueping Bao, Nupur Gupta, Chong Yang Chuah, Yen Nan Chuah, Chun-Po Hu, Xiao Hu
Summary: This study reported a novel water gel material for the selective recovery of high concentration PFOA. The results showed that the water gel had a high adsorption capacity and selectivity for PFOA under specific conditions. Additionally, the water gel exhibited pH responsiveness, allowing for easy release of PFOA. Incorporating the water gel into a dense membrane enabled effective separation of colloidal particles in a water system.
SEPARATION AND PURIFICATION TECHNOLOGY
(2022)
Article
Nanoscience & Nanotechnology
Qingqing Li, Jinghua Zhao, Baosheng He, Zhijun Hu
Summary: PVDF, a ferroelectric polymer with the polar beta-phase, has the highest dipolar moment and piezoelectric response. The development of flexible electronics highly requires effective methods for producing beta-PVDF.
Article
Chemistry, Physical
Seyed Mohsen Seraji, Xing Jin, Zhifeng Yi, Chunfang Feng, Nisa V. Salim
Summary: This study demonstrates the crystalline transformation of PVDF influences aerogel formation and compressible sensing properties of a graphene composite. The fabricated PVDF/graphene foams and aerogels show high sensitivity and improved compressive strength. The results provide new pathways for fabricating porous composites with lighter density and high mechanical and electrical properties.
Article
Materials Science, Characterization & Testing
Insun Woo, Jong In Lee, Dong Je Han, Dong-Heon Han, Seung-Ju Oh, Jae Uk Yoon, Soon-Mok Choi, Eun-Ho Sohn, Jin Woo Bae
Summary: To solve the problem of bacterial growth on PVDF surfaces, pyridinium group grafted-PVDF (Pyd-PVDF) was added to PVDF to prepare antibacterial materials. The antibacterial PVDF-based blends were prepared by melt-blending of PVDF and Pyd-PVDF, and their structural, thermal, mechanical, and antibacterial properties were characterized. The impact strengths and elongations of the blends increased with increasing Pyd-PVDF concentration, while the flexural moduli and tensile strengths slightly decreased.
Article
Engineering, Chemical
Pratyush Patnaik, Suman Sarkar, Sandip Pal, Uma Chatterjee
Summary: An anion exchange membrane (AEM) with controlled graft length and density was prepared through grafting 2-(dimethylamino)ethyl methacrylate (DMA) chains from the backbone of poly(vinylidene fluoride) (PVDF) using Cu(I) catalyzed atom transfer radical polymerization. The AEM showed exclusive selectivity and excellent stability in the diffusion dialysis process for separating hydrochloric acid from metal salts.
JOURNAL OF MEMBRANE SCIENCE
(2023)
Article
Chemistry, Multidisciplinary
Chaiti Ray, Su Chan Lee, Bingjun Jin, Aniruddha Kundu, Jong Hyeok Park, Seong Chan Jun
ACS SUSTAINABLE CHEMISTRY & ENGINEERING
(2018)
Article
Chemistry, Physical
Chaiti Ray, Su Chan Lee, Bingjun Jin, Aniruddha Kundu, Jong Hyeok Park, Seong Chan Jun
JOURNAL OF MATERIALS CHEMISTRY A
(2018)
Article
Chemistry, Physical
Aniruddha Kundu, Byeongho Park, Juyeong Oh, K. Vijaya Sankar, Chaiti Ray, Wook Sung Kim, Seong Chan Jun
Article
Chemistry, Physical
Aniruddha Kundu, Akhmad Irhas Robby, Arnab Shit, Hyeong Jun Jo, Sung Young Park
Review
Nanoscience & Nanotechnology
Aniruddha Kundu, Sourav Mallick, Santanu Ghora, C. Retna Raj
Summary: This article highlights the importance of nonprecious metal oxygen electrocatalysts in electrochemical energy conversion and storage technologies, as well as the emerging trends and advantages of these catalysts.
ACS APPLIED MATERIALS & INTERFACES
(2021)
Article
Nanoscience & Nanotechnology
Aniruddha Kundu, Arpan Samanta, C. Retna Raj
Summary: The article demonstrates a facile method for synthesizing nitrogen-doped carbon nanotube-encapsulated Co0.25Ni0.75 alloy electrocatalyst, which shows excellent catalytic activity for oxygen reduction and oxygen evolution reactions, making it suitable for air cathode in metal-air batteries.
ACS APPLIED MATERIALS & INTERFACES
(2021)
Review
Chemistry, Multidisciplinary
Aniruddha Kundu, Tapas Kuila, Naresh Chandra Murmu, Prakas Samanta, Srijib Das
Summary: Electrochemical energy storage devices with stable performance and high power output, such as Zn-air batteries, are in high demand for global energy requirements. Noble metal-based electrocatalysts have limitations in rechargeable Zn-air batteries, leading to the exploration of transition-metal-based materials and heteroatom-doped metal-free carbon materials as alternatives. Metal-organic frameworks (MOFs) have gained attention as precursors for the synthesis of advanced functional materials due to their unique structural flexibility and uniformly dispersed active sites.
MATERIALS HORIZONS
(2023)
Article
Chemistry, Physical
Aniruddha Kundu, Saikat Bolar, Srijib Das, Haradhan Kolya, Chun-Won Kang, Tapas Kuila, Naresh Chandra Murmu
Summary: Designing effective multifunctional electrocatalysts is crucial for developing electrochemical energy storage/conversion devices. In this study, a general approach to synthesize a multilayer N-doped graphitic carbon nanotube (CNT)-encapsulated NiCo alloy with robust trifunctional electrocatalytic activity is established. The synthesized NiCo alloy exhibits admirable performance in oxygen reduction reaction (ORR), oxygen evolution reaction (OER), and hydrogen evolution reaction (HER), with excellent stability.
ACS APPLIED ENERGY MATERIALS
(2022)
Article
Chemistry, Multidisciplinary
Prakas Samanta, Souvik Ghosh, Aniruddha Kundu, Haradhan Kolya, Chun-Won Kang, Pranab Samanta, Naresh Chandra Murmu, Tapas Kuila
Summary: Aqueous rechargeable Zn-ion batteries (ZiBs) are gaining popularity due to their safety and cost effectiveness. However, poor anode reversibility and cathode dissolution in aqueous electrolytes limit their performance. This study introduces a cyanide functional group-containing electrolyte to improve performance by delaying oxidation and promoting uniform Zn nucleation. The optimized ZiB with this electrolyte demonstrated a working potential window of around 2.3 V and retained about 79.56% capacity after 5000 cycles. The study also investigates the H+ and Zn2+ insertion/extraction and Zn deposition/dissolution mechanism. This work provides a new approach for developing high-performance ZiBs using green electrolytes and layered materials.
ACS SUSTAINABLE CHEMISTRY & ENGINEERING
(2023)
Article
Chemistry, Physical
Ujjwal Phadikar, Srijib Das, Saikat Bolar, Aniruddha Kundu, Haradhan Kolya, Chun-Won Kang, Naresh Chandra Murmu, Tapas Kuila
Summary: A heterostructure electrocatalyst with a three-dimensional FeNi2S4@Mo-doped Ni3S2/NF structure is successfully synthesized, achieving low overpotential and high stability in alkaline solution, providing a new electrode material for water electrolysis.
JOURNAL OF POWER SOURCES
(2023)
Article
Chemistry, Physical
Srijib Das, Aniruddha Kundu, Tapas Kuila, Naresh Chandra Murmu
Summary: Metal-air batteries, especially rechargeable zinc-air batteries (ZABs), have attracted extensive research attention as a promising sustainable energy technology due to their environmental friendliness, low manufacturing cost, and high theoretical specific energy density. However, the sluggish kinetics of oxygen-involved reactions hinder the real-time application of ZABs. Developing novel design strategies for effective bifunctional electrocatalysts is crucial to overcome this hurdle and promote the commercialization of ZABs.
ENERGY STORAGE MATERIALS
(2023)
Article
Chemistry, Physical
Prakas Samanta, Aparna Paul, Aniruddha Kundu, Haradhan Kolya, Chun-Won Kang, Naresh Chandra Murmu, Tapas Kuila
Summary: Conventional rechargeable aqueous Zn-ion batteries store charges through the cationic redox conversion mechanism, which provides limited capacity and energy density. Triggering the oxygen redox chemistry (ORC) can enhance the performance, and this study proposes a layered-type V2P2O9 cathode material that exhibits the ORC process at a high working potential window. The ORC process not only enhances the capacity performance but also improves the electrochemical stability window.
ACS APPLIED ENERGY MATERIALS
(2023)
Review
Engineering, Electrical & Electronic
Prakas Samanta, Souvik Ghosh, Aniruddha Kundu, Pranab Samanta, Naresh Chandra Murmu, Tapas Kuila
Summary: Rechargeable aqueous Zn-ion batteries (ZiBs) have great potential for large-scale electrical grid energy storage due to their safety, energy density, and cost advantages. However, the performance of ZiBs is hindered by the limitations of the aqueous electrolyte, such as its narrow stability window and sluggish ion kinetics. This review provides a comprehensive understanding of electrolyte formulation, interface mechanics, and optimization strategies to overcome these challenges and enable the development of advanced ZiBs.
ACS APPLIED ELECTRONIC MATERIALS
(2023)
Article
Chemistry, Multidisciplinary
Abhirup Bhadra, Aniruddha Kundu, C. Retna Raj
Summary: The electrochemical detection of Cr(VI) using surface-engineered mesoporous carbon-based material was demonstrated in this study. The modified electrode showed excellent sensitivity, selectivity, and stability, with a low detection limit and wide linear range. The porous nature of the material facilitated mass transport and electron transfer kinetics for efficient reduction of Cr(VI) at a favorable potential.
JOURNAL OF CHEMICAL SCIENCES
(2021)
Article
Chemistry, Multidisciplinary
Aniruddha Kundu, Byeongho Park, Chaiti Ray, Juyeong Oh, Seong Chan Jun
NEW JOURNAL OF CHEMISTRY
(2019)