期刊
JOURNAL OF PHYSICAL CHEMISTRY B
卷 113, 期 19, 页码 6674-6681出版社
AMER CHEMICAL SOC
DOI: 10.1021/jp901714f
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资金
- BMBF [GIN-SF-049]
Two novel phosphonic acid-based dry proton exchange membrane materials that may allow for fuel cell operation above 100 degrees C have been prepared and characterized via solid-state H-1 and H-2 MAS NMR spectroscopy. We obtained information on both the nature of hydrogen bonding and local proton mobilities among phosphonic acid moieties. In particular, H-2 MAS NMR line shape analysis yielded apparent activation energies of the underlying motional processes. Using this approach, we have investigated both a model compound and a novel PEM system. It was found that the relation of estimated hydrogen-bond strength and local proton mobility accessible by solid-state NMR and bulk proton conductivity is complex. Improvements through admixture of a second component with protogenic groups are suggested.
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