Article
Materials Science, Multidisciplinary
Alaa Y. Y. Ali, Natalie P. P. Holmes, Nathan Cooling, John Holdsworth, Warwick Belcher, Paul Dastoor, Xiaojing Zhou
Summary: The performance of P3HT:PCBM organic photovoltaic devices is influenced by environmental conditions, thermal annealing, and material blend composition. Optimized laboratory fabricated devices show that humidity during fabrication can cause electrode oxidation and photo-oxidation, while thermal annealing can enhance device performance by modifying the morphology of the active layer. Additionally, the choice of PEDOT:PSS material affects the performance of P3HT:PCBM devices.
Article
Polymer Science
Syed Abdul Moiz, Mohammed Saleh Alzahrani, Ahmed N. M. Alahmadi
Summary: In this study, a relatively novel polymer solar cell with different electron transport layers was proposed and tested for photovoltaic responses. The ITO/Zn(O,S)/PTB7:PC70BM/PEDOT:PSS/Au device showed the highest power conversion efficiency.
Article
Chemistry, Physical
Difei Zhang, Wenkai Zhong, Lei Ying, Baobing Fan, Meijing Li, Ziqi Gan, Zhaomiyi Zeng, Dongcheng Chen, Ning Li, Fei Huang, Yong Cao
Summary: Research demonstrates that utilizing quasi-orthogonal solvents in traditional planar heterojunction structures can overcome limitations of nanoscale phase separation in bulk-heterojunction organic solar cells, leading to an improved power conversion efficiency of 14.2%. Additional experiments confirm the key factors in forming optimal nanoscale morphology.
Article
Materials Science, Multidisciplinary
Pujia Cheng, Dongping Zheng, Yingjie Zhang, Xinqi Chen, Tianjun Chen, Tiansheng Zhang, Fan Wu
Summary: An inorganic-organic hybrid bulk heterojunction (BHJ) consisting of a CuO nanocone array (NCA)/methyl [6,6]-phenyl-C-61-butyrate (PC61BM) was fabricated and showed enhanced photocurrent response and better photogenerated charge transfer properties.
Article
Chemistry, Multidisciplinary
Sudhakar Narra, Shuo-En Tsai, Kamlesh Awasthi, Shailesh Rana, Eric Wei-Guang Diau, Nobuhiro Ohta
Summary: The study investigated the photoluminescence and electrophotoluminescence of bulk heterojunction samples of P3HT and PCBM thin films, finding that as the PCBM content increased, the PL quantum yield decreased monotonically, with static quenching playing a dominant role.
JOURNAL OF THE CHINESE CHEMICAL SOCIETY
(2022)
Article
Materials Science, Characterization & Testing
Falk Niefind, Rishi Shivhare, Stefan C. B. Mannsfeld, Bernd Abel, Mike Hambsch
Summary: The nanoscale morphology of bulk heterojunctions plays a crucial role in charge dissociation and transport, affecting the performance of organic solar cells. Photoemission electron microscopy offers a fast and intuitive method to visualize and analyze the nanomorphology of different polymer blends, providing valuable insights for evaluating film suitability.
Article
Chemistry, Multidisciplinary
Yanling Wu, Deyu Liu, Jiabo Le, Huanglong Zhuang, Yongbo Kuang
Summary: In order to create a high-efficiency bulk-heterojunction (BHJ)-based photocathode, it is crucial to introduce suitable interfacial modification layer(s). Surface engineering plays a significant role in achieving high-performance photocathodes as the photoelectrochemical reactions at the photocathode/electrolyte interface are the limiting process. However, the impact of interfacial layer morphology regulation on PEC activity has not received enough attention. In this study, a Pt nanoparticle-assisted homogeneous RuO2 layer deposition method was developed to overcome the challenge of uniform coverage of hydrophilic RuO2 on the hydrophobic BHJ surface, leading to improved PEC performance compared to conventional interface engineering strategies. The FTO/J71:N2200(Pt)/RuO2 photocathode exhibited the best photocurrent density of -9.0 mA cm(-2) at 0 V with an onset potential of up to 1.0 V under AM1.5 irradiation.
Article
Chemistry, Physical
Yanjie Wu, Nan Ding, Yuhong Zhang, Bin Liu, Xinmeng Zhuang, Shuainan Liu, Zhaogang Nie, Xue Bai, Biao Dong, Lin Xu, Donglei Zhou, Hongwei Song
Summary: This study focuses on extending the near-infrared (NIR) spectral response and increasing ultraviolet (UV) utilization for perovskite solar cells (PSCs). By integrating new organic bulk-heterojunction and gold nanotriangles, the NIR spectral response of PSCs is extended to 1100 nm. The study also demonstrates the potential of CsPbCl3:Yb3+, Ce3+, Cr3+ nanophosphors for down-conversion in PSCs, resulting in a significant increase in power conversion efficiency (PCE) and short circuit current density (Jsc).
ADVANCED ENERGY MATERIALS
(2022)
Article
Chemistry, Physical
Masahiro Nakano, Akira Takahara, Kenji Genda, Md. Shahiduzzaman, Makoto Karakawa, Tetsuya Taima, Kohshin Takahashi
Summary: This study introduces a method for the selective extraction of nonfullerene acceptors (NFAs) from a BHJ layer in OSCs and provides a detailed analysis of the remaining BHJ films based on AFM. By using this method, the morphologies of NFA-free BHJ films fabricated under various conditions were studied in detail. The results may be useful for the optimization of BHJ film structures composed of NFAs and donor polymers.
Article
Chemistry, Multidisciplinary
Saurav Limbu, Kyung-Bae Park, Jiaying Wu, Hyojung Cha, Sungyoung Yun, Seon-Jeong Lim, Hao Yan, Joel Luke, Gihan Ryu, Chul-Joon Heo, Sunghan Kim, Yong Wan Jin, James R. Durrant, Ji-Seon Kim
Summary: The study identified the critical role of donor molecular structure in organic photodetectors, showing that subtle structural changes in blends can significantly impact optoelectronic performance. These insights provide valuable information for the development of high-performance OPDs and highlight key differences in the design of BHJ blends for OPD and OPV devices.
Article
Crystallography
Brett Setera, Ching-Hua Su, Bradley Arnold, Fow-Sen Choa, Lisa Kelly, Rachit Sood, N. B. Singh
Summary: Chromium- and cobalt-doped zinc selenide nanoparticles were synthesized using a low-temperature reactive solution growth method. The particles agglomerated, but the thioglycerol capping agent helped limit grain growth and agglomeration. This method allows for doping by adding chromium and cobalt salts to the solution.
Article
Chemistry, Physical
Yaxiong Guo, Junjie Ma, Feihong Ye, Haibing Wang, Zongwei Pan, Liangbin Xiong, Zuojun Tan
Summary: The introduction of the nonfullerene Y6 additive effectively suppressed nonradiative recombination by passivating electronic defects, leading to high quality perovskite films with improved stability. Simultaneously, it enabled a well-matched energy alignment at the perovskite/electronic transport material interface, facilitating charge extraction through graded heterojunction structure and achieving a power conversion efficiency of up to 20.6% in planar inverted perovskite solar cells.
JOURNAL OF POWER SOURCES
(2021)
Article
Chemistry, Multidisciplinary
Sunan Bao, Hang Yang, Hongyu Fan, Jianqi Zhang, Zhixiang Wei, Chaohua Cui, Yongfang Li
Summary: Controlling the self-assembly of organic semiconductors to form well-developed nanoscale phase separation is critical for building high-performance organic solar cells. A new approach utilizing the synergistic effect of DTT and CN is developed to tune the morphology of the photoactive layer, leading to a significant increase in power-conversion efficiency and fill factor in ternary OSCs processed with dual additives of CN and DTT.
ADVANCED MATERIALS
(2021)
Article
Chemistry, Physical
Jingzhuo Tian, Wenhua Xue, Meixin Li, Tao Sun, Xiaoyun Hu, Jun Fan, Enzhou Liu
Summary: An efficient CoSx/T-CZS photocatalyst with zinc-blende/wurtzite homojunction and heterojunction between CoSx and T-CZS was successfully constructed. The introduction of amorphous CoSx significantly improved the H-2 evolution rate of the photocatalyst. This work provides new ideas for constructing noble metal-free photocatalysts with homo-heterojunction.
CATALYSIS SCIENCE & TECHNOLOGY
(2022)
Article
Chemistry, Physical
Yan Zang, Shicheng Huang, Baopeng Yang, Gen Chen, Xiaohe Liu, Ning Zhang
Summary: A hybrid Mo2N/NiS heterojunction with synergistic effect is developed as a bifunctional electrocatalyst for high-efficiency water splitting in alkaline media. The Mo2N/NiS hybrids exhibit enhanced electrocatalytic activities for both the hydrogen evolution reaction (HER) and oxygen evolution reaction (OER) due to the synergistic effect between Mo2N and NiS. Furthermore, the Mo2N/NiS hybrids demonstrate excellent long-term durability and have a favorable solar-to-hydrogen energy conversion efficiency.
APPLIED SURFACE SCIENCE
(2023)
Article
Materials Science, Multidisciplinary
Peiyao Xue, Jingming Xin, Guanyu Lu, Boyu Jia, Heng Lu, Guanghao Lu, Wei Ma, Ray P. S. Han, Xiaowei Zhan
Summary: This study investigated the performance evaluation parameters of semitransparent organic solar cells (ST-OSCs), namely, the average visible transmittance (AVT) and power conversion efficiency (PCE). By reducing the donor content, light absorption in the visible region can be decreased and the AVT values of ST-OSCs can be increased. However, a lower donor content affects exciton generation, exciton dissociation, and charge transport, thereby limiting the PCEs of the cells.
JOURNAL OF MATERIALS CHEMISTRY C
(2023)
Article
Materials Science, Multidisciplinary
Hongmei Qin, Shijie Ju, Wenyan Su, Baofeng Zhao, Qunping Fan, Zhaozhao Bi, Sen Zhang, Jifa Yu, Guanghao Lu, Ji-Ting Hou, Wei Ma, Chao Gao, Yuxiang Li
Summary: Despite the advantages of morphological stability in PSMA-based polymer solar cells, the microstructure evolution of the active layer over thermal stress remains a challenge. By developing a new PSMA and conducting systematic studies, we reveal that the thermal-disaggregation process of PSMA-based PSCs is mainly dominated by the polymer donor, rather than the polymerized small molecular acceptor.
JOURNAL OF MATERIALS CHEMISTRY C
(2023)
Article
Chemistry, Multidisciplinary
Xiaobo Zhou, Hongbo Wu, Urvashi Bothra, Xingze Chen, Guanyu Lu, Heng Zhao, Chao Zhao, Qun Luo, Guanghao Lu, Ke Zhou, Dinesh Kabra, Zaifei Ma, Wei Ma
Summary: By optimizing the morphology through a layer-by-layer (LBL) processing strategy, low leakage current and low non-radiative recombination loss can be achieved in PM6:Y6-O based devices. The optimized morphology results in a reduced voltage loss and an impressive fill factor (FF) of 81.5%, leading to a high power conversion efficiency (PCE) of 31.2% under 1000 lux LED illumination, which is the best reported efficiency for indoor OPVs. This LBL strategy also shows great universality in promoting the performance of indoor OPVs with other non-fullerene acceptor systems.
MATERIALS HORIZONS
(2023)
Article
Nanoscience & Nanotechnology
Zichao Shen, Wanlong Lu, Peng Wei, Yuanwei Zhu, Yihang Jiang, Laju Bu, Guanghao Lu
Summary: Although metal or oxide conductive films are widely used, organic electrodes have advantages for next-generation organic electronics. A class of highly conductive and optically transparent polymer ultrathin layers are reported here, using model conjugated polymers as examples. These ultrathin layers have high conductivity due to the vertical phase separation of semiconductor/insulator blends and the thermally evaporated dopants. Metal-free monolithic coplanar field-effect transistors with high field-effect mobility and optical transparency are realized using the same ultrathin layers as electrodes.
ACS APPLIED MATERIALS & INTERFACES
(2023)
Article
Chemistry, Multidisciplinary
Jinde Yu, Zichao Shen, Wanlong Lu, Yuanwei Zhu, Yi-Xin Liu, Dieter Neher, Norbert Koch, Guanghao Lu
Summary: Organic thin films deposited from solution have attracted wide interest for next-generation (opto-)electronic and energy applications. The phase evolution dynamics for different components at different locations during solvent evaporation are not synchronic within the incrementally concentrated liquid films, determining the final anisotropic morphology and performance.
ADVANCED FUNCTIONAL MATERIALS
(2023)
Article
Physics, Applied
Yang Feng, Mingru Li, Kai Shang, Huan Niu, Guanghao Qu, Guanghao Lu, Shengtao Li
Summary: A high-energy storable polymer dielectric with an exceptionally high energy density of 10.7 J/cm(3) has been successfully synthesized by combining reversible addition-fragmentation chain transfer polymerization and polyaddition polymerization techniques. The end-group functionalized copolymer significantly enhances the dielectric constant and breakdown strength. The conformational transitions of the thiourea groups and the charge trapping from the unique dithioesters are the key factors responsible for the improved dielectric properties.
APPLIED PHYSICS LETTERS
(2023)
Article
Instruments & Instrumentation
Guanyu Lu, Zichao Shen, Hong Wang, Laju Bu, Guanghao Lu
Summary: Organic thin films with vertical phase segregation were characterized using film-depth-dependent light absorption spectroscopy. Interference effects on peak intensity and position were investigated, and a numerical method was proposed to obtain optical constants. The error caused by interference was reduced by 95% compared to traditional measurements. The modified spectroscopy approach enabled accurate analysis of the optical properties of thin films.
REVIEW OF SCIENTIFIC INSTRUMENTS
(2023)
Article
Instruments & Instrumentation
Zongze Qin, Songyu Han, Dongfan Li, Chenyang Zhai, Wanlong Lu, Peng Wei, Yuanwei Zhu, Zhen Hu, Laju Bu, Guanghao Lu
Summary: Semiconducting polymers have a broad distribution of energy levels due to their polydispersity, resulting in charge density-dependent bulk mobility. This study proposes a method to measure the charge-density-dependent bulk mobility of conjugated polymer films using a field-effect transistor configuration. The gate-induced variation of bulk charge density ranges within +/- 10(18) cm(-3), depending on the energetic dispersion width of localized states. The field-effect bulk mobility and field-effect mobility near the semiconductor-dielectric interface can be simultaneously obtained from transistor characteristics using different gate voltage ranges.
REVIEW OF SCIENTIFIC INSTRUMENTS
(2023)
Article
Chemistry, Physical
Shujuan Liu, Yuchen Zhou, Zezhou Liang, Baofeng Zhao, Weiping Wang, Zeyu Xue, Kai Ding, Zhiyuan Cong, Haimei Wu, Guanghao Lu, Chao Gao
Summary: Recently, high-performance pseudo-bilayer organic solar cells (OSCs) based on sequential deposition (SD) have been successfully fabricated using chloroform as a single solvent. These SD OSCs exhibit improved performance compared to the traditional bulk heterojunction (BHJ)-based devices. By finely adjusting the vertical phase distribution, the SD D18/Y6 pseudo-bilayer device achieved a champion efficiency of 17.94% and a high short-circuit current density of 27.24 mA cm-2, outperforming other devices with different structures and preparation methods.
ACS APPLIED ENERGY MATERIALS
(2023)
Article
Chemistry, Multidisciplinary
Dongfan Li, Ning An, Kai Tan, Yurong Ren, Hong Wang, Shengtao Li, Qian Deng, Jianwei Song, Laju Bu, Guanghao Lu
Summary: The conversion of the n-type semiconductor C-8-PTCDI into C-8-PTCDI (D) electrets enhances the charge density and trap energy level, resulting in lower operation voltage and energy consumption of devices based on n-type electrets.
ADVANCED FUNCTIONAL MATERIALS
(2023)
Article
Chemistry, Multidisciplinary
Xin Wang, Shuting Yang, Zongze Qin, Bin Hu, Laju Bu, Guanghao Lu
Summary: This study reports on flexible organic light-stimulated synaptic transistors (LSSTs) enabled by alumina oxide (AlOX), which exhibit multiwavelength optical signal response and multifunctional simulation. Embedding AlOX nanoparticles improves the excitons separation efficiency, allowing for multiple wavelength responses. Optimized LSSTs can respond to multiple optical and electrical signals in a highly synaptic manner. The prepared flexible transistors exhibit mechanical flexibility and improved photosynaptic plasticity, facilitating the development of neuromorphic computing and multifunction integration systems at the device-level.
ADVANCED MATERIALS
(2023)
Article
Chemistry, Multidisciplinary
Yixin Ran, Wanlong Lu, Xin Wang, Zongze Qin, Xinsu Qin, Guanyu Lu, Zhen Hu, Yuanwei Zhu, Laju Bu, Guanghao Lu
Summary: Photonics neuromorphic computing has promising applications due to its advantages of low latency, low power consumption, and high bandwidth. Transistors with asymmetric electrode structures are gaining attention for their low power consumption, high optical response, and simple preparation technology. However, there is a lack of systematic research and mechanism analysis on intelligent optical synapses constructed by asymmetric electrodes.
MATERIALS HORIZONS
(2023)
Review
Chemistry, Multidisciplinary
Xin Wang, Yixin Ran, Xiaoqian Li, Xinsu Qin, Wanlong Lu, Yuanwei Zhu, Guanghao Lu
Summary: This paper comprehensively discusses the investigation of transistor-based artificial synapses in bioinspired information processing, which are stable building blocks for brain-like computing. However, the influence of the semiconductor and device structural design on synaptic properties is still poorly understood. The recent advances in novel structure design of semiconductor materials and devices used in synaptic transistors are emphasized, along with the discussion and prediction of crises and opportunities in transistor-based synaptic interconnection.
MATERIALS HORIZONS
(2023)
Article
Materials Science, Multidisciplinary
Zhen Hu, Dongfan Li, Wanlong Lu, Zongze Qin, Yixin Ran, Xin Wang, Guanghao Lu
Summary: Soft plasma etching can greatly reduce the number of charge traps in organic semiconductor films, resulting in a 60% decrease in subthreshold swing and an approach to 0 V threshold voltage in organic field-effect transistors (OFETs). It also eliminates the hysteresis of OFETs and improves operational stability.
MATERIALS ADVANCES
(2023)
Article
Chemistry, Multidisciplinary
Zichao Shen, Jinde Yu, Guanyu Lu, Keming Wu, Qingyu Wang, Laju Bu, Xinfeng Liu, Yuanwei Zhu, Guanghao Lu
Summary: This study investigates the phase evolution of PBDB-T:ITIC and PM6:Y6 systems with DIO/CN additives using position-resolved and time-resolved spectroscopy techniques. It is found that a solvent-free liquid film surface is formed during solvent evaporation, and the Flory-Huggins interaction parameters are calculated. Different phase evolution behaviors are observed for the two systems, and surface phase segregation significantly determines the photovoltaic performance.
ENERGY & ENVIRONMENTAL SCIENCE
(2023)