Article
Engineering, Electrical & Electronic
Subhrajit Konwar, Pramod K. Singh, Pawan Dhapola, Abhimanyu Singh, Serguei V. Savilov, Muhd Zu Azhan Yahya, Sirin Siyahjani Gultekin, Burak Gultekin
Summary: This paper deals with the synthesis, characterization, and application of low-viscosity ionic liquids as dopants and biopolymers as the host. The ionic liquid enhances the ionic conductivity and thermal stability of the biopolymer electrolyte, leading to the development of highly conducting ionic-liquid-doped biopolymer electrolyte-based devices such as electrochemical double-layer capacitors and dye-sensitized solar cells.
ACS APPLIED ELECTRONIC MATERIALS
(2023)
Article
Chemistry, Physical
Elham Aram, Hanieh Shaki, Morteza Ehsani
Summary: High-performance gel polymer electrolytes based on PEO/PMMA incorporating different weight percentage of GO nanosheets were prepared, and the addition of GO increased the ionic conductivity and thermal properties of the electrolytes. The optimized polymer gel electrolyte, containing 1 wt% GO, showed a higher photon conversion efficiency of 6.98%, compared to the neat PEO/PMMA gel electrolyte (4.92%). The presence of GO also increased the charge recombination resistance and long-term stability of the gel electrolyte.
Article
Chemistry, Physical
Dustin J. Boogaart, Jeremy B. Essner, Gary A. Baker
Summary: Studies characterized three choline chloride-based DESs as DSSC electrolytes and found DES guaniline to be a superior electrolyte option for DSSCs compared to the three most widely studied canonical DESs.
JOURNAL OF CHEMICAL PHYSICS
(2021)
Review
Chemistry, Multidisciplinary
Sultana Rahman, Abdul Haleem, Muhammad Siddiq, Muhammad Khalid Hussain, Samina Qamar, Safia Hameed, Muhammad Waris
Summary: The financial progress of a country depends heavily on the energy sector, which is crucial for the growth and development of various industries. The use of renewable resources is essential to overcome the energy crisis and reduce the negative impact of hydrocarbon fuels on the environment. This review focuses on the dyes used in dye-sensitized solar cells (DSSC) and discusses the progress in both inorganic and natural dyes.
Article
Chemistry, Multidisciplinary
Ezgi Yilmaz Topuzlu, Burak Ulgut, Omer Dag
Summary: By utilizing LLC gel electrolyte and dye N719 in the manufacture of DSSC, the performance of the cell is enhanced. Increasing the water content in the gel phase leads to improved ion conductivity and short-circuit current of the DSSC, but has negative effects on the open-circuit voltage, equilibrium reaction, and dye anchoring over the titania surface.
Review
Chemistry, Physical
Dheeraj Devadiga, M. Selvakumar, Prakasha Shetty, M. S. Santosh
Summary: Dye-sensitized solar cells are an efficient method of converting energy and have the potential to be a future energy source. Integration with rechargeable energy storage systems has addressed the issue of power output in photovoltaic conversion systems.
JOURNAL OF POWER SOURCES
(2021)
Article
Polymer Science
Ahalya Gunasekaran, Hsuan-Ying Chen, Vinoth Kumar Ponnusamy, Andrea Sorrentino, Sambandam Anandan
Summary: Dye-sensitized solar cells have gained popularity for their environmental friendliness and low cost. This study successfully synthesized PLA with different PDI and developed a high ionic conductivity polymer gel electrolyte (PGE) for the solar cells, achieving a photocurrent conversion efficiency of 5.64%.
JOURNAL OF POLYMER RESEARCH
(2021)
Article
Chemistry, Physical
Kumarasinghe Divakara Mudiyanselage Sakunthala Pubudu Kumari Kumarasinghe, Buddhika C. Karunarathne, Shashiprabha P. Dunuweera, Rajapakse Mudiyanselage Gamini Rajapakse, Kirthi Tennakone, Gamaralalage Rajanya Asoka Kumara
Summary: The study investigates the effect of 4-tertiary-butylpyridine (TBP) on improving the performance of dye-sensitized solar cells. The presence of TBP increases the transport number of iodide ions and the ionic conductivity of the electrolyte. The optimized DSC with TBP shows a conversion efficiency of 7.94%, a high V-OC of 0.709 V, and J(SC) of 17.22 mA cm(-2), a 35% increase in efficiency compared to when TBP is not present.
ACS APPLIED ENERGY MATERIALS
(2021)
Article
Chemistry, Multidisciplinary
Abisharani Johnson Mary Leeda Rani, Ahalya Gunasekeran, Devikala Sundaramurthy, Anandan Sambandam
Summary: In this study, Mn3O4 and Mn3O4·CuS nanocomposites were proposed as novel additives in locust bean gum (LBG) gel electrolytes for aqueous dye-sensitized solar cells (DSSCs). By incorporating these additives, an enhanced photoconversion efficiency and longer electron lifetime were achieved.
NEW JOURNAL OF CHEMISTRY
(2022)
Review
Materials Science, Multidisciplinary
Laura Manceriu, Anil Kumar Bharwal, Nathan Daem, Jennifer Dewalque, Pierre Colson, Frederic Boschini, Rudi Cloots
Summary: Dye-sensitized solar cells (DSSCs) are a promising solution for portable electronics and IoT applications due to their low-cost fabrication and high efficiency. However, the main obstacle to their large-scale exploitation is their limited long-term stability caused by liquid electrolytes. This review summarizes advances in alternative polymer electrolytes, with a focus on polysiloxane-based poly(ionic liquid)s, and evaluates their behavior in DSSCs. The assessment of printability for liquid and gel polymer electrolytes, particularly polysiloxane-based electrolytes, is also discussed.
Article
Optics
M. F. Aziz, M. A. Azam, M. H. Buraidah, A. K. Arof
Summary: The presence of potassium iodide in gel polymer electrolytes can improve conductivity, leading to potential applications in dye-sensitized solar cells with an efficiency improvement of approximately 30%.
Article
Chemistry, Physical
Kai Ling Chai, Min Min Aung, Hong Ngee Lim, Luqman Chuah Abdullah, Hiroshi Uyama
Summary: The addition of ionic liquid to the polyurethane acrylate gel polymer electrolyte system enhanced both the ionic conductivity and photovoltaic performance. The system with 6 wt % of 1-butyl-3-methylimidazolium iodide showed the highest improvement in ionic conductivity, leading to the highest solar conversion efficiency in DSSCs.
ACS APPLIED ENERGY MATERIALS
(2021)
Article
Polymer Science
Huda Abdullah, Savisha Mahalingam, Nur Aisyah Abu Bakar, Abreeza Manap, Mohd Hafiz Dzarfan Othman, Md Akhtaruzzaman
Summary: The addition of Fe2O3 can improve the efficiency of DSSC, however, an excessive amount can impede electron transport. The optimal concentration is found to be 0.2% for efficient performance.
Article
Materials Science, Multidisciplinary
Samah Alhorani, Sarvesh Kumar, Mahaveer Genwa, P. L. Meena
Summary: This study explores the use of Bael tree leaves as a source for efficient dye extraction for green energy harvesting through DSSCs. The extracted dye shows chlorophyll as the main constituent with high ionic conductivity, enabling efficient power generation in DSSCs under different light sources. The fabricated DSSC using the novel Bael tree leaves-based dye demonstrates promising characteristics for green energy harvesting.
MATERIALS RESEARCH EXPRESS
(2021)
Article
Energy & Fuels
Balasubramanian Karuppasamy, Balusamy Shenbagabalakrishnan, Venkatachari Gayathri
Summary: The photovoltaic performance of aqueous Al-ion electrolyte-based dye-sensitized solar cells was investigated, showing an efficiency 50% higher than the quoted value and an 80% enhancement with antimony-doped tin oxide compared to undoped tin oxide.
Article
Chemistry, Multidisciplinary
Do-Hyeong Kim, Min-Ah Park, So-Eun Kim, Jae-Hong Kim, Kwang-Soon Ahn, Moon-Sung Kang
Article
Electrochemistry
Do-Hyeong Kim, Young-Eun Choi, Jin-Soo Park, Moon-Sung Kang
ELECTROCHIMICA ACTA
(2019)
Article
Chemistry, Multidisciplinary
Hyeon-Bee Song, Do-Hyeong Kim, Moon-Sung Kang
Article
Chemistry, Physical
Myung-Jin Lee, Seoksoo Lee, Victor Roev, Dongmin Im, Wonsung Choi, Moon-Sung Kang
Editorial Material
Polymer Science
Moon Sung Kang, Do Hwan Kim
MACROMOLECULAR RESEARCH
(2020)
Article
Energy & Fuels
Do-Hyeong Kim, Moon-Sung Kang
Article
Chemistry, Multidisciplinary
Byung Su Kim, Seul Chan Park, Do-Hyeong Kim, Gi Hyeon Moon, Jong Gyu Oh, Jaeyoung Jang, Moon-Sung Kang, Kyung Byung Yoon, Yong Soo Kang
Article
Polymer Science
Do-Hyeong Kim, Moon-Sung Kang
MACROMOLECULAR RESEARCH
(2020)
Article
Chemistry, Applied
Hongsun Hwang, Sujik Hong, Do-Hyeong Kim, Moon-Sung Kang, Jin-Soo Park, Sunghyun Uhm, Jaeyoung Lee
JOURNAL OF ENERGY CHEMISTRY
(2020)
Article
Energy & Fuels
Hyeon-Bee Song, Jong-Hyeok Park, Jin-Soo Park, Moon-Sung Kang
Summary: Novel pore-filled proton-exchange membranes (PFPEMs) have been developed in this study, combining a partially fluorinated ionomer with high cross-linking density with a porous polytetrafluoroethylene (PTFE) substrate. The prepared PFPEMs showed stable PEMFC performance equivalent to 72% of Nafion 212, with conductivity corresponding to 58-63% of that of Nafion 212. Further lowering membrane resistance is expected to achieve higher fuel cell performance.
Article
Environmental Sciences
Tae-Han Kim, Boo-Hun Choi, Moon-Sung Kang, Han-Ju Lee
Summary: The study investigated the effectiveness of a vegetation biofilter in reducing metallic particulate pollutants, particularly iron oxide. Results showed a significant reduction in iron oxide, but it is unclear whether the air quality improvements are sufficient to prevent negative effects on human health. Additional studies are needed for further clarification.
Article
Environmental Sciences
Tae-Han Kim, Boo-Hun Choi, Choong-Sik Yoon, Yong-Kyu Ko, Moon-Sung Kang, Joongjin Kook
Summary: Illegal open burning is a major source of air pollutants in agricultural activities, requiring continuous effort and attention from countries worldwide. This study conducted experiments to simulate open-air incineration and analyzed particulate matter using automated SEM-EDS. The results showed that waste mulching adsorbs metal chemicals from the soil and emits particulate matter containing transition metals and other metals during incineration, leading to excessive ROS production and reduction.
Article
Biochemistry & Molecular Biology
Ha-Neul Moon, Hyeon-Bee Song, Moon-Sung Kang
Summary: The study developed pore-filled ion-exchange membranes (PFIEMs) for VRFB with superior tensile strength and lower electrical resistance, improving oxidation stability and reducing vanadium ion permeability by introducing a fluorine moiety and porous PE substrate. The PFIEMs exhibited better charge-discharge performance in VRFB compared to commercial membranes due to higher current efficiency and voltage efficiency.
Article
Biochemistry & Molecular Biology
Hyeon-Bee Song, Do-Hyeong Kim, Moon-Sung Kang
Summary: Thin-reinforced anion-exchange membranes with excellent physical and chemical stability were developed, showing both high ion-exchange capacity and limited swelling through a double cross-linking reaction. These membranes exhibited superior performance in electrochemical energy conversion processes.
Article
Biochemistry & Molecular Biology
Hyeon-Bee Song, Moon-Sung Kang
Summary: Water-splitting electrodialysis (WSED) is an eco-friendly and efficient electro-membrane process that can produce acids and bases from salt solutions. In this study, various iron metal compounds were prepared and analyzed for their catalytic activities in bipolar membranes (BPMs). Fe(OH)(2)EDTA showed the highest catalytic activity and best stability among the considered metal compounds.
Article
Chemistry, Physical
Wiem Bouali, Muejgan Yaman, Nurgul Seferogu, Zeynel Seferogu
Summary: Novel chemosensors, including coumarin hydrazide, were synthesized and demonstrated the ability to detect cyanide ions through absorption and fluorescence turn-off response. The reaction mechanism between the sensors and the ions was determined through experimental and theoretical studies. The sensors exhibited high detection ability and effectiveness.
JOURNAL OF PHOTOCHEMISTRY AND PHOTOBIOLOGY A-CHEMISTRY
(2024)
Article
Chemistry, Physical
Parinaz Abdollahian, Hassan Heidari, Soheila Hassanzadeh, Mohammad Hasanzadeh
Summary: This study successfully synthesized various types of thiolated-graphene quantum dots (GQDs) and utilized them in a one-droplet microfluidic paper-based analytical device for the simultaneous multi-sensing of heavy metal ions. The GQDs were functionalized and stabilized on the surface of hydrophobic fiber-glass, enabling colorimetric chemosensing of ions including iron, copper, cobalt, mercury, chrome, manganese, and nickel. The results were confirmed using fluorescence spectrometry, and the platform showed potential for facile metal ion detection in human urine models and environmental fluids.
JOURNAL OF PHOTOCHEMISTRY AND PHOTOBIOLOGY A-CHEMISTRY
(2024)
Article
Chemistry, Physical
S. L. Barrett, C. Meyer, E. Cwiklik, V Fieglein, M. Burns, J. Guerrero, W. J. Brittain
Summary: Laboratory illumination is strong enough to create a photostationary state (PSS) of amphiphilic azo-benzene compounds in water. The [cis]PSS/[trans]PSS ratios were observed to be 0.33-1.2 in D2O and 0.37-3.8 in dimethyl sulfoxide-d6. ortho-Fluoroazobenzene amphiphiles show higher cis-isomer concentration at equilibrium compared to non-fluorinated compounds due to differences in optical absorption profiles. The kinetics of isomerization were measured using UV-Vis spectroscopy and the ratio of trans-to-cis rates does not directly correlate with the observed PSS. The half-life for PSS formation is 40 minutes for fluorinated compounds and 80 minutes for non-fluorinated compounds.
JOURNAL OF PHOTOCHEMISTRY AND PHOTOBIOLOGY A-CHEMISTRY
(2024)
Article
Chemistry, Physical
Jalil Khodayari, Karim Zare, Omid Moradi, Mohammadreza Kalaee, Niyaz Mohammad Mahmoodi
Summary: In this study, an eco-friendly biocomposite (CMC/MIL/CuO) was synthesized and characterized, and its ability to decolorize Acid Blue 92 dye was investigated. The results showed that CMC/MIL/CuO can be used as a suitable photocatalyst for dye decolorization.
JOURNAL OF PHOTOCHEMISTRY AND PHOTOBIOLOGY A-CHEMISTRY
(2024)
Article
Chemistry, Physical
Bo Ma, Qian Xu, Huajun Yao, Yalin Chen, Yiyang Wang, Yunfei Yang, Hongfang Shen, Youjun Lu
Summary: This study designed an integrated structure of Cu2O@Au/Cu2O heterostructure particles, which achieved significantly enhanced photocatalytic performance by simultaneously considering the integrated structural characteristics and localized surface plasmon resonance (LSPR) effect. Experimental characterization and theoretical simulation confirmed the three-in-one synergy of the integrated heterostructure, including the LSPR effect of Au nanoparticles, the light scattering based on core-shell heterostructure, and the effective charge separation based on inter-embedded heterostructure. The concept of integrated heterostructure cooperated with LSPR effect provides a new strategy for designing future catalysts.
JOURNAL OF PHOTOCHEMISTRY AND PHOTOBIOLOGY A-CHEMISTRY
(2024)
Article
Chemistry, Physical
Robert G. H. Marks, Sarah P. Rockel, Klaus Kerpen, Holger Somnitz, Philipp R. Martin, Maik A. Jochmann, Torsten C. Schmidt
Summary: This study investigated the pH-dependent photolysis of phosphonates in aqueous solutions and analyzed the transformation products. The results showed that the photolysis rate of phosphonates was influenced by pH and light conditions. Furthermore, the carbon kinetic isotope effects varied for different types of phosphonates.
JOURNAL OF PHOTOCHEMISTRY AND PHOTOBIOLOGY A-CHEMISTRY
(2024)
Article
Chemistry, Physical
T. M. Naren Vidaarth, S. Surendhiran, K. S. G. Jagan, S. Savitha, K. S. Balu, A. Karthik, B. Kalpana
Summary: In this study, magnesium oxide nanoparticles were synthesized using plant seed extracts, which exhibited excellent performance in removing dyes from textile water bodies. These nanoparticles also showed strong antibacterial and antioxidant properties.
JOURNAL OF PHOTOCHEMISTRY AND PHOTOBIOLOGY A-CHEMISTRY
(2024)
Article
Chemistry, Physical
Mikhail Yu. Ovchinnikov, Vyacheslav A. Antipin, Sergey L. Khursan
Summary: In this study, the recombination of separated ion-radical states (SIRS) in PAPh films was analyzed, and it was found that the contribution of X-SIRS recombination to total luminescence varies with different environments. It was also shown that the recombination of labile SIRS is independent of the nature of the atmosphere. The study theoretically substantiated that SIRS recombination can occur via the transfer of both positive and negative charges, and the efficiency of thermal activation of recombination processes depends on the ratio of radiant and conductive channels of energy transfer.
JOURNAL OF PHOTOCHEMISTRY AND PHOTOBIOLOGY A-CHEMISTRY
(2024)
Article
Chemistry, Physical
Sumaira Naeem, Tayyaba Mubashir, Mudassir Hussain Tahir, Jawayria Najeeb, Ahmed Z. Dewidar, Hosam O. El-ansary, Silas Lagat, Anthony Pembere
Summary: This study presents an alternative methodology using machine learning for the selection of novel organic molecules to develop high-performance organic solar cell devices.
JOURNAL OF PHOTOCHEMISTRY AND PHOTOBIOLOGY A-CHEMISTRY
(2024)
Article
Chemistry, Physical
D. Thirumoolan, S. Ragupathy, S. Renukadevi, P. Rajkumar, Rajakumar S. Rai, R. M. Saravana Kumar, Imran Hasan, Mani Durai, Young-Ho Ahn
Summary: In this study, the photodegradation of brilliant green dye was studied in relation to the comparative photocatalytic activity of pure ZnO and Ni-doped ZnO/CSAC. The Ni-doped ZnO/CSAC showed a higher photocatalytic degradation rate under visible light irradiation, suggesting its potential as an effective wastewater treatment material.
JOURNAL OF PHOTOCHEMISTRY AND PHOTOBIOLOGY A-CHEMISTRY
(2024)
Article
Chemistry, Physical
Ajmal Khan, Zhidong Chang, Wenjun Li, Xiaohui Ma, Mei Dong, Liang Geng, Ghulam Yasin, Shuaib Khan, Hira Anwar
Summary: Due to its functional structure and tunable shape, 2D zeolitic imidazole framework (ZIFs) have gained significant interest in various fields. In this study, thin ZIF-8 sheets were prepared using a mixed solvent and then delaminated into single layers through physical sonication. These hexagonal sheets exhibited high stability and controlled morphology, and showed excellent performance in dye degradation compared to 3D ZIF-8 crystals.
JOURNAL OF PHOTOCHEMISTRY AND PHOTOBIOLOGY A-CHEMISTRY
(2024)
Article
Chemistry, Physical
Vitaly A. Podshibyakin, Evgenii N. Shepelenko, Leonid D. Popov, Tatyana M. Valova, Anton O. Ayt, Lyudmila G. Kuzmina, Anton V. Lisovin, Oleg N. Burov, Mikhail E. Kletskii, Alexander D. Dubonosov, Vladimir A. Bren
Summary: Bifunctional hybrids containing photochromic indolyl(thienyl) diarylethenes and an ionochromic rhodamine moiety connected by a dimethylene spacer were synthesized. These hybrids exhibit absorption at 450-455 nm and fluorescence at 560 nm in toluene. UV light triggers ring-closed non-fluorescent diarylethene formation, which can be reversed under visible light or in the dark. In the presence of H+ cation, a naked eye effect is observed with the opening of the rhodamine-spirolactam ring and a pink-crimson coloration at 561 nm accompanied by intense long-wavelength emission at 586 nm. This process is reversible by exposure to triethylamine, as confirmed by NMR experiments. The light-induced isomerizations and proton-induced transformations were explained using computational methods. Reversible switching of fluorescent properties can be achieved by light irradiation and proton.
JOURNAL OF PHOTOCHEMISTRY AND PHOTOBIOLOGY A-CHEMISTRY
(2024)
Article
Chemistry, Physical
Majid Sharifi-Rad, Hazem S. Elshafie, Pawel Pohl
Summary: The study investigated the synthesis of silver nanoparticles using Lallemantia royleana leaf extract, characterized their physico-chemical properties, and evaluated their biopharmaceutical and catalytic applications. The synthesized nanoparticles showed good stability and exhibited higher antioxidant, antimicrobial, anti-inflammatory, anti-arthritic, and cytotoxic activities compared to the leaf extract. These results provide a promising green synthesis route for silver nanoparticles with potential biomedical and catalytic applications.
JOURNAL OF PHOTOCHEMISTRY AND PHOTOBIOLOGY A-CHEMISTRY
(2024)
Article
Chemistry, Physical
Meera Moydeen Abdul Hameed, Badr M. Thamer
Summary: Security encoding using photochromism is an effective method for creating authentication substrates. A unique photochromic ink has been developed that emits light continuously under UV rays and darkness. The ink is produced by dispersing lanthanidedoped aluminate nanoparticles in a polymer binder. The resulting composite ink can be used to create transparent films on paper, and the stamped patterns become visible under UV rays, changing from colorless to green.
JOURNAL OF PHOTOCHEMISTRY AND PHOTOBIOLOGY A-CHEMISTRY
(2024)
Article
Chemistry, Physical
Monika Lamoria, Rita Kakkar, Marilyn Daisy Milton
Summary: Four novel water-soluble benzimidazolium and bis-benzimidazolium salts with a fluorophore-spacer-receptor design were synthesized and demonstrated to selectively detect Fe3+ ions with large Stokes shifts. The binding mechanism and detection performance were investigated through theoretical and experimental studies.
JOURNAL OF PHOTOCHEMISTRY AND PHOTOBIOLOGY A-CHEMISTRY
(2024)
