Reconsideration to the deactivation of TiO2 catalyst during simultaneous photocatalytic reduction of Cr(VI) and oxidation of salicylic acid

Photocatalytic reduction/oxidation and deactivation of TiO2 photocatalyst was investigated in the systems composed of Cr(VI) and salicylic acid. The selection of analysis method of Cr(IV) was very important to the monitoring of the photocatalytic process. It was found that as previously reported, serious deactivation of TiO2 catalyst in the simultaneous photo-reduction of Cr(VI) and oxidation of salicylic acid was incorrectly observed if the Cr(VI) level was analyzed by directly monitoring the absorbance at characteristic 348 nm band of Cr(VI), because it seriously suffers from the interferences of the intermediates generated from the degradation of salicylic acid. By using an appropriate method to determine the Cr(VI) concentration, it was observed that all the added Cr(VI) could be reduced, not showing marked deactivation of the photocatalyst. A longtime photocatalytic reduction of Cr(VI) under UV illumination induced the deposition of Cr(III) species on the surface of TiO2 particles, which could cause a mild deactivation of the photocatalyst. However, the accompanied oxidation of salicylic acid was demonstrated to depress the deactivation effect of the deposited Cr(III) species on the photocatalytic activity of the TiO2 photocatalyst. (c) 2008 Elsevier B.V. All rights reserved.