Article
Chemistry, Multidisciplinary
Sankar Monika, Rengan Ramesh
Summary: This study reports the synthesis of a new series of organometallic dinuclear ruthenium(ii) arene complexes and investigates their in vitro antiproliferative activity and cancer cell death mechanism. The formation of complexes was confirmed by various spectroscopic techniques. The synthesized complexes showed higher inhibition of cancer cells compared to the standard cisplatin drug, and apoptosis was confirmed through morphological changes and phosphatidylserine externalization.
NEW JOURNAL OF CHEMISTRY
(2023)
Article
Chemistry, Inorganic & Nuclear
Alexandre Abherve, Maurizio Mastropasqua Talamo, Nicolas Vanthuyne, Francesco Zinna, Lorenzo Di Bari, Maxime Grasser, Boris Le Guennic, Narcis Avarvari
Summary: Enantiopure helicene-based bis(pyrazol-1-yl)pyridine (bpp-[6]helicene) ligands have been synthesized and characterized. The chiroptical properties of these ligands have been studied and circularly polarized luminescence in the visible region has been observed in chiral Eu(III) complexes based on these ligands, supported by theoretical calculations suggesting the antenna effect of the bpp ligand.
EUROPEAN JOURNAL OF INORGANIC CHEMISTRY
(2022)
Article
Chemistry, Inorganic & Nuclear
Srividya Swaminathan, Jebiti Haribabu, Mahendiran Dharmasivam, Nikhil Maroli, Jayachandra Prakasan Jayadharini, Nithya Balakrishnan, Nattamai Bhuvanesh, Cesar Echeverria, Ramasamy Karvembu
Summary: We designed and synthesized bipodal ligands with varying substitution on the phenyl group spacer. Ligands and complexes with different arene units were successfully synthesized and characterized. The coordination behavior of the ligands was minimally influenced by substitution change, but differences were observed in the anticancer activity of the complexes. DFT and X-ray diffraction studies revealed structural variations between the different substitutions, and UV-visible spectroscopy determined the correlation between anticancer activity, hydrolysis rate, and lipophilicity index of the complexes. Staining assays, flow cytometry, and Western blot analysis confirmed the apoptotic cell death mechanism of the active complexes.
INORGANIC CHEMISTRY
(2023)
Article
Chemistry, Organic
Maxym Tansky, Zipeng Gu, Robert J. Comito
Summary: This report introduces a new method for the synthesis of bis(pyrazolyl)alkanes, avoiding common issues in traditional methods and suitable for systematic ligand optimization. Additionally, new reactants including pyrazoles and aldehydes have been explored, providing a new direction for the development of novel catalysts.
JOURNAL OF ORGANIC CHEMISTRY
(2021)
Article
Chemistry, Medicinal
Na Wang, Amjad Ali, Zongwei Liu, Huiqin Chi, Zhimin Lv, Xing Zhao, Zeqing Zhang, Huifang Hao, Yongmin Zhang, Faiz-Ur Rahman
Summary: ONS donor ligands L1-L4 were used to prepare mono-functional dimetallic Ru(η6-arene) complexes (C1-C4). These complexes, which contain novel tridentate Ru(II) complexes with η6-arene co-ligand, were synthesized with high yields and characterized by various spectroscopic techniques. In vitro anticancer assays demonstrated that C2, the most potent complex, exhibited dose-dependent growth inhibition against breast, liver, and lung cancer cells. Furthermore, C2 showed cytotoxic activity comparable to cisplatin and oxaliplatin, induced morphological changes, and suppressed invasion, migration, cell senescence, and cancer stem cell formation. Combination treatment of C2 with cisplatin and Vitamin C demonstrated synergistic anticancer effects, suggesting its potential application in cancer therapy. Mechanistically, C2 inhibited NOTCH1-dependent signaling pathway, thereby suppressing tumorigenesis. These findings highlight the high anticancer potency of these novel Ru(η6-arene) complexes and provide a basis for further exploration of their cytotoxicity.
EUROPEAN JOURNAL OF MEDICINAL CHEMISTRY
(2023)
Article
Chemistry, Inorganic & Nuclear
Sourav Deb, Anik Sahoo, Sujoy Baitalik
Summary: The anion-responsive conduct of a Ru(II)-bipyridine complex incorporating pyrazolyl-bis(benzimidazole) ligand was investigated in acetonitrile and water using absorption and emission spectroscopy and square-wave voltammetry. The photo-redox behavior of the complex was significantly altered in the presence of selected anions, with emission being quenched in the off-state. The complex functions as an anion- and acid-responsive molecular switch, and its anion sensing behavior was thoroughly analyzed using neural network based deep learning methodologies.
EUROPEAN JOURNAL OF INORGANIC CHEMISTRY
(2023)
Article
Chemistry, Inorganic & Nuclear
Lucinda R. B. Wilson, Marco Coletta, Reshma Jose, Gopalan Rajaraman, Scott J. Dalgarno, Euan K. Brechin
Summary: The reaction results in the formation of a mixed valent decametallic cluster with a complex structure. The ligands are arranged to accommodate the metallic skeleton, resulting in significant changes in the magnetic properties of the compound.
DALTON TRANSACTIONS
(2021)
Review
Chemistry, Inorganic & Nuclear
Srividya Swaminathan, Jebiti Haribabu, Nithya Balakrishnan, Punitharaj Vasanthakumar, Ramasamy Karvembu
Summary: This article mainly discusses the structural and molecular alterations in the design and development of Ru(II)-arene complexes with monodentate ligands for anticancer applications, and their behavior in vitro or in vivo.
COORDINATION CHEMISTRY REVIEWS
(2022)
Article
Chemistry, Inorganic & Nuclear
Pragti, Sreshtha Nayek, Satyam Singh, Avinash Sonawane, Ivo Grabchev, Rakesh Ganguly, Suman Mukhopadhyay
Summary: In this study, three Ru(II) arene complexes with a bidentate benzimidazole-based ligand were synthesized and their antitumor activity was studied by varying the co-ligand X. The synthesized compounds showed good interactions with serum albumin proteins, had good drug stability and lipophilic character. They were found to bind with DNA and could induce apoptosis in cancer cells, as well as upregulate cleaved caspase-3 expression and downregulate BCLXL expression. These findings provide a new direction for the investigation of antitumor ruthenium-based metallodrugs using benzimidazole-based ligands.
DALTON TRANSACTIONS
(2023)
Article
Chemistry, Inorganic & Nuclear
Stephen Mensah, Joseph D. Rosenthal, Mamta Dagar, Tyson Brown, Jonathan J. Mills, Christopher G. Hamaker, Gregory M. Ferrence, Michael I. Webb
Summary: The evolution of high virulence bacterial strains has led to the development of novel therapeutic agents. Metal-based therapeutics, with their structural variability and unique modes of action, show great promise. This study focused on the preparation and evaluation of ruthenium(ii)-arene complexes containing Schiff base ligands with an attached ferrocene, and identified a complex with prominent activity against clinically relevant bacterial strains.
DALTON TRANSACTIONS
(2022)
Article
Chemistry, Inorganic & Nuclear
Lucinda R. B. Wilson, Marco Coletta, Mukesh K. Singh, Simon J. Teat, Adam Brookfield, Muralidharan Shanmugam, Eric J. L. McInnes, Stergios Piligkos, Scott J. Dalgarno, Euan K. Brechin
Summary: The reaction of 2,2'-bis-p-Bu-t-calix[4]arene (H8L) with Cu(NO3) (2)center dot 3H(2)O and N-methyldiethanolamine (MedeaH(2)) in a basic dmf/MeOH mixture results in the formation of [Cu-II (16)(L)(2)(Me-dea)(4)(mu(4)-NO3)(2)(mu-OH)(4)(dmf)(3.5)(MeOH)(0.5)(H2O)(2)] (H6L)center dot 16dmf center dot 4H(2)O (4). The metallic skeleton of the compound consists of a tetracapped square prism, [Cu-12], with Cu-II ions housed in the calix[4]arene polyphenolic pockets. Magnetic measurements show antiferromagnetic exchange interactions and a ground state of S = 1, while EPR indicates a large zero-field splitting.
DALTON TRANSACTIONS
(2023)
Article
Chemistry, Multidisciplinary
Bijeta Mitra, Pranab Ghosh
Summary: The study demonstrates that humic acid can be utilized as an efficient and environmentally friendly catalyst for the preparation of various organic compounds, with advantages such as non-toxicity, biodegradability, low catalyst loading, and good functional group tolerance. This strategy has significant environmental implications, and humic acid can be reused multiple times without losing its activity.
Article
Chemistry, Inorganic & Nuclear
Arunachalam Abirami, Umapathy Devan, Rengan Ramesh, Arockiam Antony Joseph Velanganni, Jan Grzegorz Malecki
Summary: This study synthesized six arene ruthenium(ii) complexes and evaluated their inhibitory effects on breast cancer cells. The complexes exhibited good antiproliferative activities by inducing apoptotic cell death through an intrinsic mitochondrial pathway.
DALTON TRANSACTIONS
(2023)
Article
Multidisciplinary Sciences
Pedro Segui, John J. Aguilera-Correa, Elena Dominguez-Jurado, Christian M. Sanchez-Lopez, Ramon Perez-Tanoira, Ana V. Ocana, Jose A. Castro-Osma, Jaime Esteban, Antonio Marcilla, Carlos Alonso-Moreno, Francisco C. Perez-Martinez, Milagros Molina-Alarcon
Summary: This study synthesized a series of nitrogen-based compounds and found that compound 2P had a strong inhibitory effect on Gram-positive bacteria (especially S. aureus), while its effects on other bacteria were relatively weak. At non-toxic concentrations, 2P showed minimal harm to eukaryotic cell cultures.
SCIENTIFIC REPORTS
(2021)
Review
Chemistry, Multidisciplinary
Mahdieh Sadeghpour, Abolfazl Olyaei
Summary: Pyrazole and its derivatives are important heterocyclic compounds found in biologically and medicinally active compounds. Two main strategies for the synthesis of bis(pyrazolyl)methane derivatives include one-pot pseudo three-component reactions and one-pot pseudo five-component reactions. This review provides an overview of the recent research on the multi-component synthesis and applications of bis(pyrazolyl)methanes from 2014 to early 2021.
RESEARCH ON CHEMICAL INTERMEDIATES
(2021)
Article
Energy & Fuels
Ali Alsalme, Rais Ahmad Khan, Malak Faisal Altowairqi, Nouf Abdul Rahman Almuryyi
Summary: This article reports on the simulation of FTO/TiO2/MA(3)Sb(2)I(9)/spiro-OMeTAD solar cells. The thickness of the absorber layer, hole-transport layer, or electron-transport layer was varied during the simulation process and the optimized solar cells demonstrated a high efficiency of 14.90% and an open circuit voltage of 1.41 V.
Article
Biochemistry & Molecular Biology
Ali Alsalme, Malak Faisal Altowairqi, Afnan Abdullah Alhamed, Rais Ahmad Khan
Summary: In this study, SCAPS-1D was used for the numerical simulation of lead-free perovskite solar cells (PSCs), and the thickness of the zinc oxysulphide, MAGeI(3), and spiro-OMeTAD layers was optimized. The optimized PSCs showed excellent power conversion efficiency of 21.62%.
Review
Chemistry, Inorganic & Nuclear
Claudio Pettinari, Alessia Tombesi
Summary: Metal organic frameworks (MOFs) are crystalline porous materials with ordered structures and large surface areas, which have attracted much attention for their potential applications in energy electrochemical conversion and storage devices. This review summarizes the recent research on the use of MOFs in fuel cells, solar cells, supercapacitors, and batteries. The different applications of MOFs in Li-ion, Na-ion, and other metal ion batteries are differentiated. The review also provides an overview of the water splitting reaction catalyzed by MOFs.
Article
Chemistry, Medicinal
Daphne Romani, Fabio Marchetti, Corrado Di Nicola, Massimiliano Cuccioloni, Chunmei Gong, Anna Maria Eleuteri, Agustin Galindo, Farzaneh Fadaei-Tirani, Massimo Nabissi, Riccardo Pettinari
Summary: A series of Ga(Q(n))(3) coordination compounds were synthesized and characterized through various techniques. Cytotoxicity studies showed interesting results in terms of selectivity and toxicity values compared with cisplatin. Mechanistic investigations revealed that the gallium(III) complexes induced cancer cell death through ferroptosis, triggering various cell death signals and altering cell redox homeostasis.
JOURNAL OF MEDICINAL CHEMISTRY
(2023)
Article
Biochemistry & Molecular Biology
Silvia Bordoni, Riccardo Tarroni, Magda Monari, Stefano Cerini, Fabio Battaglia, Gabriele Micheletti, Carla Boga, Giacomo Drius
Summary: The reaction between Ru complex 1 and thymine acetic acid (THAcH) unexpectedly gives rise to macrocyclic dimer 4 and doubly coordinated species 5. By considering the energetics calculated by DFT, two possible reaction paths were proposed. The stable symmetric 14-membered binuclear macrocycle 4 is formed through self-aggregation, whereas species 2 achieves additional stabilization through k(2)(N,O) thymine heteroleptic side-chelation.
Article
Biochemistry & Molecular Biology
Giacomo Drius, Silvia Bordoni, Carla Boga, Magda Monari, Jessica Fiori, Erika Esposito, Chiara Zalambani, Luca Pincigher, Giovanna Farruggia, Natalia Calonghi, Gabriele Micheletti
Summary: In this study, three Ru(II) complexes containing hydroxy stearic acids (HSAs) were successfully synthesized and evaluated for their synergistic effects between the known antitumor activity of HSA bio-ligands and the metal center. The results showed that Ru-7-HSA and Ru-9-HSA complexes exhibited biological activity, with Ru-9-HSA showing increased antitumor activity on colon cancer cells, HT29.
Article
Chemistry, Inorganic & Nuclear
Lorenzo Pietracci, Riccardo Pettinari, Alessia Tombesi, Fabio Marchetti, Claudio Pettinari, Agustiïn Galindo, Farzaneh Fadaei-Tirani, Mouna Hadiji, Paul J. Dyson
Summary: This study investigates the coordination mechanisms of pyrazolone ligands containing a pyridine ring with the (Ru(II)) fragment through experimental and theoretical calculations. The ligands were found to coordinate in an unusual N,O-chelating fashion with Ru(II), and various complexes were synthesized. The study provides important insights into the properties of the ligands and complexes.
Article
Polymer Science
Yury A. Belousov, Mikhail T. Metlin, Darya A. Metlina, Mikhail A. Kiskin, Ilya A. Yakushev, Trofim A. Polikovskiy, Ilya V. Taydakov, Andrei A. Drozdov, Fabio Marchetti, Claudio Pettinari
Summary: A new strategy for the easy polymerization of anionic [Ln(Q(cy))(4)](-) into two-dimensional layers of [AgLn(Q(cy))(4)](n) is proposed by binding the single molecular anions [Ln(Q(cy))(4)](-) to silver cations through coordination. The luminescent properties of [AgLn(Q(cy))(4)](n) have been studied, and it was found that LMCT quenching is effectively suppressed in the heterometallic [AgEu(Q(cy))(4)](n) polymer, explaining the low PLQY in [Eu(Q(cy))(4)](-). Sensibilization coefficients for H3O[Eu(Q(cy))(4)], [AgEu(Q(cy))(4)](n), and H3O[Sm(Q(cy))(4)] complexes were estimated via theoretical analysis and PLQY measurements.
Article
Environmental Sciences
Ali Alsalme, Hilal Ahmad, Rais Ahmad Khan, Bon Heun Koo, Ghadah M. M. Alharbi, Shahad I. I. Alhadlaq
Summary: This study chemically introduced thioglycolic acid to improve the selectivity of graphene oxide (GO) nanosheets for metal ion extraction. A solid phase extraction method was developed and optimized, which showed good reliability, accuracy, and low detection limits for arsenic and mercury ions. Real samples were analyzed to validate the established procedure.
Article
Biochemistry & Molecular Biology
Alessia Garufi, Riccardo Pettinari, Fabio Marchetti, Mara Cirone, Gabriella D'Orazi
Summary: Organometallic ruthenium (Ru)(II)-cymene complexes have potential pharmacological properties as alternative therapeutic agents. Polyphenols, such as curcumin and curcuminoids, also display beneficial properties in medicine, including chemoprevention. This study investigated the anticancer effect of a cationic Ruthenium (Ru)(II)-cymene Bisdemethoxycurcumin (Ru-bdcurc) complex, revealing that targeting the interconnection between the endoplasmic reticulum (ER)-resident chaperone GRP78/BiP and NRF2 pathways enhances the cytotoxic effect of Ru-bdcurc on colon cancer cells.
Article
Biochemistry & Molecular Biology
Sonila Xhafa, Laura Olivieri, Corrado Di Nicola, Riccardo Pettinari, Claudio Pettinari, Alessia Tombesi, Fabio Marchetti
Summary: In this study, a new synthetic protocol based on microwave-assisted synthesis was used to prepare higher yields of zinc and copper in MOFs with different ligands. The antibacterial activity of these MOFs was tested against Gram-negative and Gram-positive bacteria, and the results showed that they exhibited broad-spectrum activity and strong efficiency in inhibiting bacterial growth. The mechanism of action was found to be based on the surface contact of MOF particles with bacterial cells and the generation of reactive oxygen species.
Article
Crystallography
Magda Monari, Emanuele Attolino, Gianfranco Lopopolo, Fabrizio Bosco, Massimo Gazzano
Summary: Two solvates of estetrol, Estetrol.H2O and Estetrol.0.5CH(3)OH, were isolated and characterized using SCXRD, PXRD, thermal analyses, morphology, and spectroscopy. The structures of both solvates show intricate networks of intermolecular hydrogen bonds, with Estetrol.H2O containing 12 molecules in its asymmetric unit and Estetrol.0.5CH(3)OH establishing six O-H...O bonds with different neighbors and additional H-bonds with methanol. The higher thermal stability of Estetrol.0.5CH3OH crystals compared to Estetrol.H2O crystals can be attributed to the strengthened network of hydrogen bonds.
Article
Chemistry, Analytical
Theophile Niyitanga, Mohd Quasim Khan, Khursheed Ahmad, Rais Ahmad Khan
Summary: Azithromycin is a widely used and prioritized antibiotic, but its side effects can cause significant harm to humans and the environment. Therefore, developing effective and sensitive sensors to monitor the concentration of Azithromycin is crucial. In this study, a MoS2@Ti3AlC2 composite was used to fabricate an Azithromycin sensor, which exhibited excellent performance.
Article
Chemistry, Multidisciplinary
Corrado Di Nicola, Fabio Marchetti, Alessia Tombesi, Sonila Xhafa, Patrizio Campitelli, Marco Moroni, Simona Galli, Riccardo Pettinari, Claudio Pettinari
Summary: Novel copper(ii) coordination polymers were synthesized and their thermal behavior and structural features were investigated. The nanoparticles showed potential antibacterial activity through a contact kill mechanism involving ROS production.
NEW JOURNAL OF CHEMISTRY
(2023)
Article
Chemistry, Inorganic & Nuclear
Guojun Hu, Ziyue Deng, Yanwei Wang, Dan Yuan, Yong Zhang, Yingming Yao
Summary: A series of rare-earth metal complexes were synthesized and used as efficient initiators for the polymerization of trimethylene carbonate (TMC) and (L)-lactide ((L)-LA).
JOURNAL OF ORGANOMETALLIC CHEMISTRY
(2024)
Article
Chemistry, Inorganic & Nuclear
Van Ha Nguyen, John H. K. Yip
Summary: In this study, eight PtII-azulene complexes were synthesized to investigate the effect of metalation on the electronic structures, spectroscopy, and luminescence of organic chromophores. The results showed that the attachment of Pt substituents to azulene affected the HOMOs, LUMOs, and luminescence properties. The study provides insights into the role of metalation in modifying the properties of organic chromophores.
JOURNAL OF ORGANOMETALLIC CHEMISTRY
(2024)
Article
Chemistry, Inorganic & Nuclear
Moon Kedia, Virender Singh, Bhaskaran Shankar, Malaichamy Sathiyendiran
Summary: This study synthesized two types of neutral binuclear metallocycles using a one-pot solvothermal method and characterized their structures. The analysis revealed that these complexes adopt a binuclear heteroleptic cyclic architecture and belong to phosphine oxide donor (P=O)-based supramolecular coordination cyclic complexes.
JOURNAL OF ORGANOMETALLIC CHEMISTRY
(2024)
Article
Chemistry, Inorganic & Nuclear
Radhey S. Srivastava
Summary: This study demonstrates the effectiveness of zero-valent elements as reductants for the deoxydehydration reaction of polyols catalyzed by ONO-pincer ligated molybdenum dioxo. The insolubility and easy separability of the reductants and their oxidized products during the reaction are emphasized. Additionally, the choice of ligand has an impact on the catalytic performance of the reaction.
JOURNAL OF ORGANOMETALLIC CHEMISTRY
(2024)
Article
Chemistry, Inorganic & Nuclear
Hao Zhou, Yajun Sun, Li Deng, Weiran Yang, Yuehui Li
Summary: Efficient Ru-catalyzed hydrogenation of aldehydes was achieved using carbazole-derived phosphine ligands, with the crucial role of N-H moiety in promoting the catalytic reaction. The method was successfully applied in the Co/Ru-catalyzed hydroformylation process, resulting in the production of long-chain alcohols with excellent yields.
JOURNAL OF ORGANOMETALLIC CHEMISTRY
(2024)
Article
Chemistry, Inorganic & Nuclear
Theodor Danescu, Alexandru Lupan, Radu Silaghi-Dumitrescu, R. Bruce King
Summary: The structures and energies of complexes containing (Me2C2N2P)2Ru2(CO)n and (Me2C2N2P)2Fe2(CO)n have been studied. Low-energy structures are characterized by the presence of bridging diazaphospholyl rings, while higher-energy structures involve different ligand structures.
JOURNAL OF ORGANOMETALLIC CHEMISTRY
(2024)
Article
Chemistry, Inorganic & Nuclear
Savannah C. Kapper, Aamani Ponnekanti, Jonas Schaab, Tian-yi Li, Christine L. Chung, Gael Ung, Peter I. Djurovich, Mark E. Thompson
Summary: Organometallic iridium complexes with two cyclometalated ligands and one bis-oxazoline derived ancillary ligand were studied. These complexes have emission spanning across the visible and near-ultraviolet region, with moderate to high photoluminescence quantum yields. The (ppy)2Ir(BOX-CN) complexes were resolved into Delta- and Lambda-diastereomers based on solubility differences.
JOURNAL OF ORGANOMETALLIC CHEMISTRY
(2024)
Article
Chemistry, Inorganic & Nuclear
Zahra Karimi Sangari, Hossein Naeimi
Summary: In this research, a nanostructured CoCuFe2O4 catalyst was prepared using a brief and useful synthetic strategy. This catalyst was used for synthesizing 1,2,4,5-tetrasubstituted imidazole derivatives under ultrasonic irradiation. The approach offers advantages such as high efficiency, short reaction times, simplicity of the reaction medium, accelerated reaction rates, and easier separation and purification of products.
JOURNAL OF ORGANOMETALLIC CHEMISTRY
(2024)
Article
Chemistry, Inorganic & Nuclear
Rukhsana Gul, Wajid Munir, Ebraheem Abdu Musad Saleh, Shaukat Shujah, Muhammad Sirajuddin, Saira Tabassum, Khalil Ur Rehman, Dilfaraz Khan, Sameerah I. Al-Saeedi, Ehab A. Abdelrahman
Summary: Two new Schiff base ligands were synthesized and used to form copper, nickel, and cobalt complexes. The synthesized compounds were characterized and screened for various biological activities. The metal complexes showed better activities in antibacterial, antifungal, antidiabetic, and antioxidant assays.
JOURNAL OF ORGANOMETALLIC CHEMISTRY
(2024)
Review
Chemistry, Inorganic & Nuclear
Ahsan Nazir, Pengwei Huo, Ameena Tur Rasool
Summary: This review explores the potential of g-C3N4-based S-scheme heterojunctions in addressing environmental issues. It summarizes the mechanism and preparation techniques of S-scheme heterojunctions based on g-C3N4, and presents recent studies on their applications in pollutant removal, CO2 reduction, hydrogen production, and bacterial disinfection. The review concludes with an outlook on future challenges for g-C3N4-based S-scheme heterojunctions.
JOURNAL OF ORGANOMETALLIC CHEMISTRY
(2024)
Article
Chemistry, Inorganic & Nuclear
Francois Mazars, Koffi Senam Etse, Guillermo Zaragoza, Lionel Delaude
Summary: The activity of three Pd-PEPPSI catalyst precursors with N-heterocyclic carbene (NHC) ligands derived from caffeine and theophylline in Mizoroki-Heck reactions was tested. The results showed that the catalysts achieved high conversions and yields, especially in the presence of electron-withdrawing substituents.
JOURNAL OF ORGANOMETALLIC CHEMISTRY
(2024)
Article
Chemistry, Inorganic & Nuclear
Bo-Han Wu, Xue Zhou, Lin Liu, Zheng-Bo Han
Summary: Researching carbon dioxide removal from flue gas and natural gas is crucial. Metal-organic frameworks (MOFs) are commonly used in adsorption due to their high surface area, porosity, and chemical properties. An ultra-microporous MOF CPM-20(Co) with mixed ligand was synthesized using inexpensive ligands. The material exhibited high selectivities and low regenerative energy, making it a promising option for CO2 separation in industries.
JOURNAL OF ORGANOMETALLIC CHEMISTRY
(2024)