期刊
JOURNAL OF ORGANOMETALLIC CHEMISTRY
卷 723, 期 -, 页码 207-213出版社
ELSEVIER SCIENCE SA
DOI: 10.1016/j.jorganchem.2012.10.004
关键词
Palladium catalyst; Crystal structure; Suzuki cross-coupling reaction
资金
- Bu-Ali Sina University
In this paper it is reported the synthesis of the complexes of the type {[Ph2PCH2PPh2CH=C(O)R]PdCl2} (R=4'-biphenyl (1), OCH2Ph (2), 4-methylphenyl (3), 2-naphtyl (4), 2,4-dichlorophenyl (5), 3-nitrophenyl (6)) derived from the reactions of the dichloro(1,5-cyclooctadiene)palladium(II) with related phosphorus ylides in dichloromethane under mild conditions. These compound have been characterized by, elemental analysis and spectroscopic methods. The structure of complex 1 has been characterized crystallographically. This structure consists of five-membered ring formed by coordination of the ligand through the phosphine group and the ylidic carbon atom to the metal center. The coordination geometry around the Pd atoms in this complex can be defined as slightly distorted square planar. At a supramolecular level C -H center dot center dot center dot Cl and C-H center dot center dot center dot pi intermolecular interactions are responsible for the crystal packing. This complex has been found to act as efficient catalysts for the Suzuki cross-coupling reaction. Various aryl bromides were coupled with aryl boronic acids in DMF, under air, in the presence of 0.2 mol% of the catalyst to afford corresponding cross- coupled products in good to excellent yields. (C) 2012 Elsevier B.V. All rights reserved.
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