期刊
JOURNAL OF ORGANOMETALLIC CHEMISTRY
卷 696, 期 1, 页码 406-418出版社
ELSEVIER SCIENCE SA
DOI: 10.1016/j.jorganchem.2010.10.017
关键词
Aminotroponiminate; Aminotroponate; Hydroamination; N-Ligands; Zinc
资金
- Cluster of Excellence Unifying Concepts in Catalysis
- Deutsche Forschungsgemeinschaft
- Fonds der Chemischen Industrie
This review deals with the synthesis of aminotroponiminate and aminotroponate zinc complexes. The main focus is on their application as catalysts for the intramolecular hydroamination, in which good activity, particularly high functional group tolerance and a relatively high stability towards moisture and air were observed. In addition, a heterogeneous zinc catalyst was reported in order to increase the stability and the recyclability of the catalytic system. (C) 2010 Elsevier B.V. All rights reserved.
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