Article
Chemistry, Multidisciplinary
Qimin Wu, Qi Zhang, Shuxin Yin, Aijun Lin, Shang Gao, Hequan Yao
Summary: A platinum-catalyzed atroposelective hydrosilylation of unactivated internal alkynes has been reported for the first time. By using L1 as a chiral ligand, various axially chiral styrenes were obtained with excellent enantioselectivities and high E-selectivities. Control experiments showed that NH-arylamide groups have significant effects on yields and enantioselectivities, and they can act as directing groups. The potential applications of the products were demonstrated through transformations of the amide motifs.
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
(2023)
Article
Chemistry, Inorganic & Nuclear
Malgorzata Bolt, Aleksandra Mermela, Patrycja Zak
Summary: This study describes the synthesis and characterization of a new bifunctional N-heterocyclic carbene precursor with sterically expanded substituents. The obtained NHC is used in the catalytic system for hydrosilylation of internal alkynes, providing a fully selective and efficient reaction under mild conditions in the presence of air. Comparative analysis with analogs based on monofunctional NHC ligands demonstrates that the presence of two metal atoms and the proper design of the steric environment around the metal center significantly enhance the catalytic activity in the hydrosilylation process.
EUROPEAN JOURNAL OF INORGANIC CHEMISTRY
(2023)
Article
Chemistry, Organic
Ying Yang, Ya-Nan Jiang, Zhi-Yi Lin, Jia-Hao Zeng, Zhi-Kai Liu, Zhuang-Ping Zhan
Summary: The use of a porous organic polymer as a heterogeneous ligand in 1,3-diyne hydrosilylation reaction can significantly increase the selectivity and efficiency, showing promising prospects for industrial applications.
ORGANIC CHEMISTRY FRONTIERS
(2021)
Article
Chemistry, Multidisciplinary
Zhaoyang Cheng, Jun Guo, Yufeng Sun, Yushan Zheng, Zhehong Zhou, Zhan Lu
Summary: This study presents a controllable cobalt-catalyzed sequential hydrosilylation/hydroboration reaction of arylacetylenes, achieving high regioselectivities for all possible regio-outcomes. Adjusting the ligands of cobalt catalysts combined with dual catalysis relay strategy is crucial for achieving regio-chemistry control, which may inspire further exploration in diversity-oriented synthesis involving multiple additions.
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
(2021)
Article
Chemistry, Physical
Irina K. Goncharova, Roman A. Novikov, Irina P. Beletskaya, Ashot V. Arzumanyan
Summary: This study presents a highly efficient and simple recyclable catalytic system for heterophase hydrosilylation. The catalytic system consists of a commercially available platinum precatalyst, K2PtCl4, and a cheap green solvent, ethylene glycol (EG). The single-atom Pt0-complex generated in the catalytic system enables 36 recycles with quantitative yield in air at room temperature. The method is applicable to a wide range of unsaturated compounds and suitable for the synthesis of linear and cross-linked polyorganosiloxanes.
JOURNAL OF CATALYSIS
(2023)
Article
Chemistry, Inorganic & Nuclear
Konstantin V. Deriabin, Ekaterina A. Golovenko, Nikita S. Antonov, Sergey V. Baykov, Vadim P. Boyarskiy, Regina M. Islamova
Summary: A platinum polymer catalyst (Pt-PDMS) was synthesized by immobilizing a platinum catalytic complex in a polysiloxane chain using an azide-alkyne CuAAC cycloaddition. Insoluble Pt-PDMS can be used as an effective heterogeneous macrocatalyst for Si-O dehydrocoupling. Pt-PDMS is easy to recover, purify, and reuse again for heterogeneous catalysis.
DALTON TRANSACTIONS
(2023)
Article
Chemistry, Applied
Nikita V. V. Shvydkiy, Klimentiy V. V. Rimskiy, Dmitry S. S. Perekalin
Summary: The readily available cyclobutadiene platinum complex [(C4Et4)PtCl2] can catalyze the hydrosilylation of alkenes and alkynes. The reaction occurs at room temperature and does not require any solvent. The products obtained include terminal and internal alkynes, as well as terminal alkenes, with yields ranging from 43% to 99%. Various tertiary silanes (Et3SiH, (EtO)(3)SiH, Ph3SiH) and the disubstituted silane Ph2SiH2 are suitable substrates for this reaction. The hydrosilylation reaction exhibits typical anti-Markovnikov regioselectivity, yielding mainly beta(E)-vinylsilanes from alkynes and linear alkyl silanes from alkenes.
APPLIED ORGANOMETALLIC CHEMISTRY
(2023)
Article
Chemistry, Inorganic & Nuclear
Lu Dong, Linke Yu, Xueli Sun, Xiongkai Tang, Xuexin You, Jiaqi Tang, Zi-Ang Nan, Dongxu Cao, Yanyuan Jia, Simin Li, Fengyu Li, Shuo Guo, Hui Shen
Summary: We report a stable gold-copper alloy nanocluster with high catalytic performance. The nanocluster exhibits high thermal stability and contains rich uncoordinated copper sites, which contribute to its extremely high catalytic activity in C-O coupling reactions. This finding is of great significance for understanding the underlying rationale of ligand-functionalized metal nanocatalysts.
INORGANIC CHEMISTRY FRONTIERS
(2023)
Review
Chemistry, Multidisciplinary
Leandro Duarte de Almeida, Hongli Wang, Kathrin Junge, Xinjiang Cui, Matthias Beller
Summary: This minireview discusses the use of homogeneous noble metal catalysts and earth-abundant transition metals/heterogeneous catalysts in hydrosilylation reactions, highlighting the growing interest in more sustainable and economic catalysts.
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
(2021)
Review
Chemistry, Multidisciplinary
Ria Ayu Pramudita, Ken Motokura
Summary: This article presents the current development of utilizing hydrosilanes in the chemical reduction of CO2, with a focus on organic catalysts. The use of heterogeneous organocatalysts with precisely designed active sites is emphasized for their recyclability and higher efficiency in these transformations.
Article
Chemistry, Multidisciplinary
Tahani A. C. A. Bayrakdar, Benon P. Maliszewski, Fady Nahra, Dominic Ormerod, Steven P. Nolan
Summary: The integration of a membrane separation protocol with platinum-catalyzed hydrosilylation of olefins was studied, resulting in efficient separation of the platinum catalyst under solvent-free conditions. The intact catalyst was recovered at the end of the process in high yield without further purification.
Article
Chemistry, Organic
Xinyu Chen, Yi-Guo Huang, Wei-Qiang Zhong, Jing-Mei Huang
Summary: An electrochemical method for the decarboxylative silylation of alpha,beta-unsaturated carboxylic acids has been developed with satisfactory yields and excellent selectivities. Mechanistic studies reveal that NHPI mediates the formation of silyl radicals by generating the HAT reagent PINO via MS-CPET.
Article
Chemistry, Inorganic & Nuclear
Chunying Chen, Qijie Mo, Yufei Wang, Li Zhang
Summary: Vinylsilanes are important structural units in organic chemistry. This study reports a catalytic alkyne hydrosilylation method using a porphyrin metal-organic framework with incorporated Pd nanoparticles. The catalytic results show that the catalyst has high efficiency and selective production of E isomer vinylsilane. Mechanistic studies reveal that the cooperation between iridium porphyrin and Pd nanoparticles is the key to the high catalytic activity.
INORGANIC CHEMISTRY
(2023)
Article
Materials Science, Multidisciplinary
Mikhail Dobrynin, Elina Sokolova, Mikhail A. Kinzhalov, Andrey S. Smirnov, Galina L. Starova, Vadim Yu Kukushkin, Regina M. Islamova
Summary: In this study, a family of platinum complexes were synthesized and used as hydrosilylation catalysts to prepare luminescent silicone rubbers. The silicone rubbers and the complexes exhibited similar emission spectra in the green region and strong phosphorescence, with potential applications in protective coatings and phosphor-converted white light-emitting diodes.
ACS APPLIED POLYMER MATERIALS
(2021)
Article
Chemistry, Physical
Jiaojiao Song, Yixuan Yang, Shoujie Liu, Lei Li, Nan Yu, Yuteng Fan, Zhiming Chen, Long Kuai, Baoyou Geng
Summary: This study investigates the impact of dispersion and support on the activity of Pt in CO oxidation reaction, revealing that reducible TiO2 significantly influences Pt activity with lower apparent activation barriers, and that single-atom dispersion of Pt maximizes active sites.
Article
Chemistry, Physical
Il Son Khan, Luis Garzon-Tovar, Toni Grell, Genrikh Shterk, Jose Cerrillo, Tuiana Shoinkhorova, Juan C. Navarro, Faisal Alahmadi, Angel Sousa, Anastasiya Bavykina, Daria Poloneeva, Mustafa Caglayan, Stephanie Terruzzi, Javier Ruiz-Martinez, Nikolay Kosinov, Valentina Colombo, Jorge Gascon
Summary: The use of metal-organic frameworks (MOFs) as precursors for heterogeneous catalysts has attracted much attention. Steaming during the controlled decomposition of MOFs leads to the formation of smaller, well-dispersed metal nanoparticles, resulting in more efficient catalysts. This study demonstrates the benefits of steam addition, including improved phase composition control and catalyst activity, for CO2 hydrogenation.
Review
Chemistry, Multidisciplinary
V Hernandez-Montes, R. Buitrago-Sierra, Monica Echeverry-Rendon, J. F. Santa-Marin
Summary: In order to overcome the limitations of magnesium alloys in temporary orthopedic implants, various surface coatings have been used to improve their biological, physico-chemical, and biodegradation properties. Ceria-based materials are considered as one of the most promising coatings due to their good self-healing properties and interesting biological properties. However, there are still some problems and challenges related to the biocompatibility and application of these materials.
Article
Chemistry, Physical
Pierfrancesco Ticali, Sara Morandi, Genrikh Shterk, Samy Ould-Chikh, Adrian Ramirez, Jorge Gascon, Sang-Ho Chung, Javier Ruiz-Martinez, Silvia Bordiga
Summary: The present work investigates the application of a previously studied PdZn/ZrO2+SAPO-34 bifunctional catalyst for CO2 conversion. High activity and selectivity for propane were observed. The results obtained from NAP-XPS measurements and CO adsorption at liquid-nitrogen temperature (LNT) followed by FT-IR spectroscopy provide insights into the behavior of the catalyst. Fresh, used, and regenerated states of the catalyst were characterized, revealing interactions between different components and the formation of new species in the catalyst framework.
APPLIED CATALYSIS A-GENERAL
(2023)
Article
Chemistry, Physical
Mauricio Perez, Robison Buitrago-Sierra, Karen Cacua, Juan Santa
Summary: In this study, nanolubricants containing graphene and copper oxide were prepared and their physicochemical and tribological properties were evaluated. The nanolubricants exhibited Newtonian behavior and the viscosity was not significantly affected by the additives. The addition of graphene and copper oxide reduced the size of wear scars, with graphene showing higher wear protection. A synergistic effect was observed when both additives were present. The SEM analysis revealed two protection mechanisms: the rolling bearing/ball effect (CuO) and the deposition of graphene in surface roughness valleys and peaks.
JOURNAL OF DISPERSION SCIENCE AND TECHNOLOGY
(2023)
Article
Chemistry, Multidisciplinary
Qingpeng Cheng, Guanna Li, Xueli Yao, Lirong Zheng, Junhu Wang, Abdul-Hamid Emwas, Pedro Castano, Javier Ruiz-Martinez, Yu Han
Summary: This study presents a facile synthesis strategy for incorporating more Fe into the zeolite framework. The Fe-ZSM-5 catalyst prepared using this method has three times as many active sites as conventional Fe-ZSM-5, leading to a record-high C-1 oxygenate yield in the selective oxidation of CH4.
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
(2023)
Article
Materials Science, Multidisciplinary
Luisa Carvajal, Sebastian Perez, Robison Buitrago-Sierra, Alexander Santamaria, Andres Moreno, Hartmut Wiggers, Jaime Gallego
Summary: The study focused on the effect of different metal precursors on the synthesis of iron oxide nanoparticles in a spray flame reactor. Iron nitrate, iron acetylacetonate, and ferrocene were tested at two different concentrations. The choice of metal precursor significantly influenced the crystallinity, crystallite size, and iron oxide content of the nanoparticles. The findings also revealed that the concentration of the precursor played a crucial role in determining the particle characteristics, with the catalytic effect of iron positively influencing the flame energy.
Article
Chemistry, Multidisciplinary
Rushana Khairova, Sarah Komaty, Alla Dikhtiarenko, Jose Luis Cerrillo, Sudheesh Kumar Veeranmaril, Selvedin Telalovic, Antonio Aguilar Tapia, Jean-Louis Hazemann, Javier Ruiz-Martinez, Jorge Gascon
Summary: Metal encapsulation in zeolitic materials through one-pot hydrothermal synthesis is an attractive technique to prepare zeolites with high metal dispersion. Metallosiloxanes are used as an alternative metal precursor, leading to quantitative metal loading and high dispersion. Fe-MFI zeolites synthesized using this method exhibit high catalytic activity in NH3-mediated selective catalytic reduction (SCR) of NOx.
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
(2023)
Article
Engineering, Mechanical
Jose Wilmar Calderon-Hernandez, Mauricio Perez-Giraldo, Robison Buitrago-Sierra, Juan Felipe Santa-Marin
Summary: This paper presents the failure analysis results of several crankshafts from synthetic canvas looms. The fractured components were analyzed based on material characterization methods, hardness measurements, stress calculations and finite element modeling to determine if the crankshafts were suitable for fatigue applications. The failure occurred due to fatigue initiated by fretting induced by inadequate heat treatment, material selection problems, and inadequate bushing adjustment.
ENGINEERING FAILURE ANALYSIS
(2023)
Article
Chemistry, Physical
Stefan Adrian F. Nastase, Yiru Ye, Teng Li, Sang -Ho Chung, Javier Ruiz-Martinez, Abhishek Dutta Chowdhury, Luigi Cavallo
Summary: Zeolites are widely used and researched in various reaction processes. Understanding the reaction mechanisms involved has been a long-term challenge, but computational simulations analyzing 13C chemical shifts of different compounds have proven useful.
JOURNAL OF CATALYSIS
(2023)
Article
Green & Sustainable Science & Technology
Wei Jin, Jesus Gandara-Loe, Laura Pastor-Perez, Juan J. Villora-Pico, Antonio Sepulveda-Escribano, Roberto Rinaldi, Tomas Ramirez Reina
Summary: This study proposes an integrated approach combining aqueous phase reforming (APR) and hydrodeoxygenation (HDO) for the hydrotreatment of guaiacol, a model compound representing lignin-derived phenols in pyrolysis bio-oils. The study explores the effect of metal species, Pt-promoting effect on Ni-Pt catalyst supported on activated carbon (AC), and the choice of hydrogen source (methanol or glycerol) on the conversion of guaiacol. The findings highlight the significant improvement in guaiacol conversion with bimetallic Ni-Pt/AC catalysts using methanol as the hydrogen source, and the importance of hydrogen source selection for catalyst performance and stability.
Article
Chemistry, Physical
Teng Li, Sang-Ho Chung, Stefan Nastase, Adrian Galilea, Yan Wang, Ildar Mukhambetov, Moussa Zaarour, Juan Carlos Navarro de Miguel, Jurjen Cazemier, Abhay Dokania, Liliana Panarone, Jorge Gascon, Luigi Cavallo, Javier Ruiz-Martinez
Summary: In this study, two H-ZSM-5 zeolites with different aluminum distributions were compared, and it was found that aluminum enrichment closer to the surface leads to more paired acid sites and enhanced catalytic activity. Furthermore, this aluminum distribution accelerates cascade reactions to produce aromatics and improves their diffusion out of the zeolite. By exploiting this feature, hollow zeolites were successfully fabricated, combining optimized active sites and improved diffusion and confinement properties to achieve the highest capacity for aromatic production.
Article
Engineering, Biomedical
Angie Tatiana Toro Martinez, Robison Buitrago-Sierra, Alvaro Guzman Aponte
Summary: Collagen is widely used in biomedical applications for cell scaffolds and in cosmetics and pharmaceutics. However, its use is limited due to ethical concerns. Extracting collagen from fishing industry waste has been suggested as an environmentally friendly alternative with promising results. Further research is needed on the characteristics and sources of this biomaterial.
JOURNAL OF BIOMIMETICS BIOMATERIALS AND BIOMEDICAL ENGINEERING
(2023)
Article
Chemistry, Physical
Mustafa Caglayan, Abdallah Nassereddine, Stefan-Adrian F. Nastase, Antonio Aguilar-Tapia, Alla Dikhtiarenko, Sang-Ho Chung, Genrikh Shterk, Tuiana Shoinkhorova, Jean-Louis Hazemann, Javier Ruiz-Martinez, Luigi Cavallo, Samy Ould-Chikh, Jorge Gascon
Summary: Tungsten is a promising metal with higher thermal stability for replacing molybdenum in methane dehydroaromatization (MDA) catalysis. However, the MDA activity of W-ZSM-5 catalysts is lower than their Mo counterpart. In order to understand the differences in catalytic activity, thorough investigations are conducted on the dispersion and distribution of W sites on the zeolite.
CATALYSIS SCIENCE & TECHNOLOGY
(2023)
Article
Chemistry, Multidisciplinary
Rushana Khairova, Sarah Komaty, Alla Dikhtiarenko, Jose Luis Cerrillo, Sudheesh Kumar Veeranmaril, Selvedin Telalovic, Antonio Aguilar Tapia, Jean-Louis Hazemann, Javier Ruiz-Martinez, Jorge Gascon
Summary: Encapsulating metal in zeolitic materials through one-pot hydrothermal synthesis is an attractive technique to prepare zeolites with high metal dispersion. This study introduces the use of metallosiloxanes as an alternative metal precursor and demonstrates their effectiveness in achieving quantitative metal loading and high dispersion. Fe-MFI zeolites obtained through this method exhibit high catalytic activity and good tolerance in the NH3-mediated SCR of NOx.
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
(2023)
Article
Electrochemistry
Jennifer Laverde, Nataly C. Rosero-Navarro, Akira Miura, Robison Buitrago-Sierra, Kiyoharu Tadanaga, Diana Lopez
Summary: In this study, nitrogen doped mesoporous carbon was used as a host for sulfur and S/C composite electrodes were prepared by sulfur melting-diffusion process. The results showed that a composite electrode with homogeneous sulfur distribution could be obtained with 6 hours of sulfur melting-diffusion and 10 wt.% of sulfur content, achieving high sulfur utilization and good electronic conductivity in Li-S cells.
Article
Chemistry, Inorganic & Nuclear
Guojun Hu, Ziyue Deng, Yanwei Wang, Dan Yuan, Yong Zhang, Yingming Yao
Summary: A series of rare-earth metal complexes were synthesized and used as efficient initiators for the polymerization of trimethylene carbonate (TMC) and (L)-lactide ((L)-LA).
JOURNAL OF ORGANOMETALLIC CHEMISTRY
(2024)
Article
Chemistry, Inorganic & Nuclear
Van Ha Nguyen, John H. K. Yip
Summary: In this study, eight PtII-azulene complexes were synthesized to investigate the effect of metalation on the electronic structures, spectroscopy, and luminescence of organic chromophores. The results showed that the attachment of Pt substituents to azulene affected the HOMOs, LUMOs, and luminescence properties. The study provides insights into the role of metalation in modifying the properties of organic chromophores.
JOURNAL OF ORGANOMETALLIC CHEMISTRY
(2024)
Article
Chemistry, Inorganic & Nuclear
Moon Kedia, Virender Singh, Bhaskaran Shankar, Malaichamy Sathiyendiran
Summary: This study synthesized two types of neutral binuclear metallocycles using a one-pot solvothermal method and characterized their structures. The analysis revealed that these complexes adopt a binuclear heteroleptic cyclic architecture and belong to phosphine oxide donor (P=O)-based supramolecular coordination cyclic complexes.
JOURNAL OF ORGANOMETALLIC CHEMISTRY
(2024)
Article
Chemistry, Inorganic & Nuclear
Radhey S. Srivastava
Summary: This study demonstrates the effectiveness of zero-valent elements as reductants for the deoxydehydration reaction of polyols catalyzed by ONO-pincer ligated molybdenum dioxo. The insolubility and easy separability of the reductants and their oxidized products during the reaction are emphasized. Additionally, the choice of ligand has an impact on the catalytic performance of the reaction.
JOURNAL OF ORGANOMETALLIC CHEMISTRY
(2024)
Article
Chemistry, Inorganic & Nuclear
Hao Zhou, Yajun Sun, Li Deng, Weiran Yang, Yuehui Li
Summary: Efficient Ru-catalyzed hydrogenation of aldehydes was achieved using carbazole-derived phosphine ligands, with the crucial role of N-H moiety in promoting the catalytic reaction. The method was successfully applied in the Co/Ru-catalyzed hydroformylation process, resulting in the production of long-chain alcohols with excellent yields.
JOURNAL OF ORGANOMETALLIC CHEMISTRY
(2024)
Article
Chemistry, Inorganic & Nuclear
Theodor Danescu, Alexandru Lupan, Radu Silaghi-Dumitrescu, R. Bruce King
Summary: The structures and energies of complexes containing (Me2C2N2P)2Ru2(CO)n and (Me2C2N2P)2Fe2(CO)n have been studied. Low-energy structures are characterized by the presence of bridging diazaphospholyl rings, while higher-energy structures involve different ligand structures.
JOURNAL OF ORGANOMETALLIC CHEMISTRY
(2024)
Article
Chemistry, Inorganic & Nuclear
Savannah C. Kapper, Aamani Ponnekanti, Jonas Schaab, Tian-yi Li, Christine L. Chung, Gael Ung, Peter I. Djurovich, Mark E. Thompson
Summary: Organometallic iridium complexes with two cyclometalated ligands and one bis-oxazoline derived ancillary ligand were studied. These complexes have emission spanning across the visible and near-ultraviolet region, with moderate to high photoluminescence quantum yields. The (ppy)2Ir(BOX-CN) complexes were resolved into Delta- and Lambda-diastereomers based on solubility differences.
JOURNAL OF ORGANOMETALLIC CHEMISTRY
(2024)
Article
Chemistry, Inorganic & Nuclear
Zahra Karimi Sangari, Hossein Naeimi
Summary: In this research, a nanostructured CoCuFe2O4 catalyst was prepared using a brief and useful synthetic strategy. This catalyst was used for synthesizing 1,2,4,5-tetrasubstituted imidazole derivatives under ultrasonic irradiation. The approach offers advantages such as high efficiency, short reaction times, simplicity of the reaction medium, accelerated reaction rates, and easier separation and purification of products.
JOURNAL OF ORGANOMETALLIC CHEMISTRY
(2024)
Article
Chemistry, Inorganic & Nuclear
Rukhsana Gul, Wajid Munir, Ebraheem Abdu Musad Saleh, Shaukat Shujah, Muhammad Sirajuddin, Saira Tabassum, Khalil Ur Rehman, Dilfaraz Khan, Sameerah I. Al-Saeedi, Ehab A. Abdelrahman
Summary: Two new Schiff base ligands were synthesized and used to form copper, nickel, and cobalt complexes. The synthesized compounds were characterized and screened for various biological activities. The metal complexes showed better activities in antibacterial, antifungal, antidiabetic, and antioxidant assays.
JOURNAL OF ORGANOMETALLIC CHEMISTRY
(2024)
Review
Chemistry, Inorganic & Nuclear
Ahsan Nazir, Pengwei Huo, Ameena Tur Rasool
Summary: This review explores the potential of g-C3N4-based S-scheme heterojunctions in addressing environmental issues. It summarizes the mechanism and preparation techniques of S-scheme heterojunctions based on g-C3N4, and presents recent studies on their applications in pollutant removal, CO2 reduction, hydrogen production, and bacterial disinfection. The review concludes with an outlook on future challenges for g-C3N4-based S-scheme heterojunctions.
JOURNAL OF ORGANOMETALLIC CHEMISTRY
(2024)
Article
Chemistry, Inorganic & Nuclear
Francois Mazars, Koffi Senam Etse, Guillermo Zaragoza, Lionel Delaude
Summary: The activity of three Pd-PEPPSI catalyst precursors with N-heterocyclic carbene (NHC) ligands derived from caffeine and theophylline in Mizoroki-Heck reactions was tested. The results showed that the catalysts achieved high conversions and yields, especially in the presence of electron-withdrawing substituents.
JOURNAL OF ORGANOMETALLIC CHEMISTRY
(2024)
Article
Chemistry, Inorganic & Nuclear
Bo-Han Wu, Xue Zhou, Lin Liu, Zheng-Bo Han
Summary: Researching carbon dioxide removal from flue gas and natural gas is crucial. Metal-organic frameworks (MOFs) are commonly used in adsorption due to their high surface area, porosity, and chemical properties. An ultra-microporous MOF CPM-20(Co) with mixed ligand was synthesized using inexpensive ligands. The material exhibited high selectivities and low regenerative energy, making it a promising option for CO2 separation in industries.
JOURNAL OF ORGANOMETALLIC CHEMISTRY
(2024)
