期刊
JOURNAL OF ORGANOMETALLIC CHEMISTRY
卷 693, 期 14, 页码 2465-2467出版社
ELSEVIER SCIENCE SA
DOI: 10.1016/j.jorganchem.2008.04.025
关键词
alkoxides; aluminum; silver; sodium; weakly coordinating anions
Acetonitrile ligated silver perfluoroalkoxy aluminate can be applied as versatile anion transfer reagent for several complexes with weakly coordinating counter anions. Its synthesis, however, is not as inexpensive and easy as it would be desirable. Accordingly, a new and straightforward synthesis for this useful compound, avoiding the use of expensive AgF and an ultrasonic bath has been developed, affording 90% yield. (C) 2008 Elsevier B.V. All rights reserved.
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