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An effective route for the synthesis of cationic palladium complexes of general formula [(Acac)(PdLL2)-L-1](+)A(-)

JOURNAL OF ORGANOMETALLIC CHEMISTRY (2008)

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JOURNAL OF ORGANOMETALLIC CHEMISTRY
卷 693, 期 12, 页码 2069-2073

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ELSEVIER SCIENCE SA
DOI: 10.1016/j.jorganchem.2007.12.019

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boron trifluoride; dimerization; palladium; styrene; norbornene; polymerization

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Chemistry, Inorganic & Nuclear Chemistry, Organic

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A series of palladium complexes of general formula [(Acac)(PdLL2)-L-1](+)A(-), where L-1, L-2 = phosphines and A = BF4, CF3SO3, were synthesized. Preliminary studies show that the complexes are active in selective dimerization of styrene and addition polymerization of norbornene. (C) 2008 Published by Elsevier B.V.

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