期刊
JOURNAL OF ORGANOMETALLIC CHEMISTRY
卷 693, 期 13, 页码 2231-2236出版社
ELSEVIER SCIENCE SA
DOI: 10.1016/j.jorganchem.2008.03.016
关键词
C-N coupling; carbenes; carbocycles; homogeneous catalysis; palladium
Palladium complexes bearing a cycloheptatrienylidene ligand are powerful precatalysts for C-N coupling reactions. Their catalytic performance is directly compared to analogous 2,3-diphenylcyclopropenylidene complexes. The crystal structure of cis-dibromo( cycloheptatrienylidene)( triphenylphosphane) palladium( II) is presented. (C) 2008 Elsevier B. V. All rights reserved.
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