期刊
JOURNAL OF ORGANOMETALLIC CHEMISTRY
卷 693, 期 25, 页码 3689-3691出版社
ELSEVIER SCIENCE SA
DOI: 10.1016/j.jorganchem.2008.09.032
关键词
Thiophosphite ligands; Carboranes; Asymmetric hydrogenation; Rhodium
资金
- INTAS [05-1000008-8064]
A new class of chiral monodentate ligands - carborane-containing thiophosphites have been synthesized and tested in the Rh-catalyzed asymmetric hydrogenation of prochiral olefins with the result of up to 99% ee. The dependence of the enantioselectivity on the electronic properties of the carboranyl substituent has been studied. (C) 2008 Elsevier B. V. All rights reserved.
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