期刊
JOURNAL OF ORGANIC CHEMISTRY
卷 83, 期 17, 页码 10619-10626出版社
AMER CHEMICAL SOC
DOI: 10.1021/acs.joc.8b01433
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资金
- CSIR, New Delhi [02(0307)/17/EMR-II]
A metal-free visible-light-promoted C(sp(3))-C(sp(2)) cross-dehydrogenative coupling between tetrahydroisoquinoline and imidazo[1,2-a]pyridine has been developed to afford 3-substituted imidazopyridines using a catalytic amount of rose bengal as photosensitizer under aerobic conditions. The present methodology is also applicable to imidazo[1,2-a]pyrimidine, indolizine, indole, and pyrrole as well as N,N-dimethyl aniline. Wide substrates scope, use of organo photocatalyst, metal-free, and mild reaction conditions are the attractive features of this methodology.
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