期刊
JOURNAL OF ORGANIC CHEMISTRY
卷 79, 期 23, 页码 11780-11786出版社
AMER CHEMICAL SOC
DOI: 10.1021/jo502283h
关键词
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A transition-metal-free synthetic approach for constructing alkylated aryl tetrazoles has been developed using n-Bu4NI as the catalyst and t-BuOOH as the oxidant. It involves the direct C-N bond formation through sp(3) C-H activation. A wide range of benzylic C-H substrates (or alkyl ethers) and aryl tetrazoles undergo this reaction smoothly to deliver the corresponding products in good yields.
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