期刊
JOURNAL OF ORGANIC CHEMISTRY
卷 79, 期 3, 页码 1111-1119出版社
AMER CHEMICAL SOC
DOI: 10.1021/jo4025539
关键词
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资金
- National Natural Science Foundation of China [21072148]
- Foundation (B) for Peiyang Scholar-Young Core Faculty of Tianjin University [2013XR-0144]
- Innovation Foundation of Tianjin University [2013XJ-0005]
- National Basic Research Project of the MOST [2014CB932200]
The series of 3-monofunctionalized 2-oxindoles 2 were conveniently synthesized from reactions between anilide 1 and phenyliodine(III) diacetate (PIDA) through hypervalent iodine mediated C(sp(2))-C(sp(2)) bond formation followed by a subsequent deacylation reaction. This metal-free method, shown to provide direct access to an important oxindole intermediate, could be applied to the total synthesis of naturally occurring horsfiline.
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