期刊
JOURNAL OF ORGANIC CHEMISTRY
卷 79, 期 23, 页码 11729-11734出版社
AMER CHEMICAL SOC
DOI: 10.1021/jo501684k
关键词
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资金
- National Natural Science Foundation of China [21172169]
- Open Fund of Zhejiang Provincial Top Key Discipline of Biology
- National Basic Research Project [2014CB932201]
A concise, stereoselective, and protecting-group-free total synthesis of aplykurodinone-1 from HajosParrish ketone was described. The synthetic approach features a sequence of aerobic allylic oxidation and elimination of alcohol 9. The key intermediate for this synthesis was formed by a stereoselective intramolecular radical cyclization.
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